{"id":58324,"date":"2014-11-12T05:37:34","date_gmt":"2014-11-11T21:37:34","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=58324"},"modified":"2021-10-06T16:12:48","modified_gmt":"2021-10-06T08:12:48","slug":"%e5%b7%a5%e6%a5%ad%e9%a3%9f%e9%b9%bd%e6%b0%b4%e9%9b%bb%e8%a7%a3%e6%b3%95","status":"publish","type":"post","link":"http:\/\/localhost\/%e5%b7%a5%e6%a5%ad%e9%a3%9f%e9%b9%bd%e6%b0%b4%e9%9b%bb%e8%a7%a3%e6%b3%95\/","title":{"rendered":"\u5de5\u696d\u98df\u9e7d\u6c34\u96fb\u89e3\u6cd5"},"content":{"rendered":"

\u5de5\u696d\u98df\u9e7d\u6c34\u96fb\u89e3\u6cd5<\/strong><\/span>
\n\u570b\u7acb\u81fa\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u5b78\u58eb\u73ed\u4e09\u5e74\u7d1a \u4fde\u59ff\u5b87<\/strong><\/span><\/p>\n

\u5728\u6c2f\u9e7c\u5de5\u696d\u4e0a\uff0c\u96fb\u89e3\u98df\u9e7d\u6c34\u88fd\u9020\u6c2f\u6c23\u3001\u71d2\u9e7c\uff08\u6c2b\u6c27\u5316\u9209\uff09\uff0c\u5728\u967d\u6975\u751f\u6210\u6c2f\u6c23\uff0c\u9670\u6975\u751f\u6210\u6c2b\u6c23\u53ca\u6c2b\u6c27\u5316\u9209\uff0c\u5de5\u696d\u4e0a\u907f\u514d\uff081\uff09\u6c2b\u6c23\u548c\u6c2f\u6c23\u6df7\u548c\u5f62\u6210\u7206\u70b8\u6027\u7684\u6df7\u548c\u7269\uff082\uff09\u6c2b\u6c27\u5316\u9209\u5728\u96fb\u89e3\u69fd\u4e2d\u64f4\u6563\u5230\u967d\u6975\u8207\u6c2f\u6c23\u767c\u751f\u53cd\u61c9\u5f62\u6210\u6b21\u6c2f\u9178\u9209\uff0c\u964d\u4f4e\u6c2b\u6c27\u5316\u9209\u7522\u91cf\uff0c\u63a1\u7528\u9694\u819c\u6cd5\u3001\u6c5e\u6975\u6cd5\u6216\u8584\u819c\u6cd5\u3002<\/p>\n

\u9694\u819c\u6cd5\uff08Diaphragm cell process\uff09<\/strong><\/span><\/p>\n

\u5728\u967d\u6975\u8207\u9670\u6975\u4e4b\u9593\u8a2d\u7f6e\u77f3\u68c9\u9694\u819c\uff0c\u662f\u591a\u5b54\u6027\u6ef2\u900f\u9694\u5c64\uff0c\u5728\u967d\u6975\u7aef\u4e0d\u65b7\u5730\u6ce8\u5165\u98fd\u548c\u98df\u9e7d\u6c34\uff0c\u662f\u63a8\u52d5\u98df\u9e7d\u6c34\u6d41\u5411\u7684\u52d5\u529b\u4f86\u6e90\uff0c\u6c2f\u96e2\u5b50\u5728\u967d\u6975\u88ab\u6c27\u5316\u6210\u6c2f\u6c23\uff0c\u7531\u4e0a\u65b9\u6536\u96c6\u7ba1\u6536\u96c6\uff0c\u7d93\u904e\u51b7\u537b\u4e7e\u71e5\u5f8c\u6210\u70ba\u5316\u5de5\u539f\u6599\u3002\u6c92\u9032\u884c\u53cd\u61c9\u7684\u9209\u96e2\u5b50\u548c\u5269\u9918\u7684\u6c2f\u96e2\u5b50\uff0c\u901a\u904e\u77f3\u68c9\u9694\u819c\uff0c\u5230\u9054\u9670\u6975\u5ba4\uff0c\u9670\u6975\u96fb\u89e3\u6c34\u7522\u751f\u6c2b\u6c23\u548c\u6c2b\u6c27\u96e2\u5b50$$(\\mathrm{2H_2O+2e^-\\longrightarrow H_2+2OH^-})$$\uff0c\u7531\u4e0a\u65b9\u6536\u96c6\u7ba1\u6536\u96c6\u6c2b\u6c23\u3002\u6c2b\u6c27\u96e2\u5b50\u548c\u9209\u96e2\u5b50\u5f62\u6210\u6c2b\u6c27\u5316\u9209\uff0c\u8207\u7a00\u98df\u9e7d\u6c34\u5171\u540c\u6d41\u51fa\uff0c\u7d93\u84b8\u767c\u5668\u6fc3\u7e2e\u5206\u96e2\uff0c\u6b64\u6cd5\u7522\u51fa\u7684\u6c2b\u6c27\u5316\u9209\u542b\u67093%\u5de6\u53f3\u7684\u6c2f\u5316\u9209\uff0c\u4e0d\u80fd\u7528\u65bc\u4eba\u9020\u7d72\u8207\u5408\u6210\u7e96\u7dad\u7684\u751f\u7522\u3002<\/p>\n

\u6ef2\u6d41\u91cf\u7531\u967d\u6975\u5ba4\u8207\u9670\u6975\u5ba4\u7684\u6db2\u9762\u5dee\u6240\u9020\u6210\u7684\u58d3\u529b\u4f86\u7dad\u6301\u3002\u6d41\u901f\u6162\uff0c\u6c2b\u6c27\u5316\u9209\u6fc3\u5ea6\u9ad8\uff0c\u4f46\u56e0\u63a8\u52d5\u529b\u592a\u5f31\uff0c\u6709\u5c11\u91cf\u6c2b\u6c27\u6839\u96e2\u5b50\u6703\u53cd\u5411\u6d41\u56de\u967d\u6975\uff0c\u964d\u4f4e\u96fb\u89e3\u6548\u7387\u3002\u6d41\u901f\u592a\u5feb\uff0c\u5247\u6703\u964d\u4f4e\u9670\u6975\u5ba4\u7684\u9e7c\u6db2\u6fc3\u5ea6\uff0c\u9700\u8981\u8f03\u591a\u7684\u80fd\u91cf\u624d\u80fd\u7cbe\u5316\u3002<\/p>\n

\u9694\u819c\u6cd5\u4e2d\uff0c\u98fd\u548c\u98df\u9e7d\u6c34\u7684\u54c1\u8cea\u8981\u6c42\u9ad8\uff0c\u7531\u65bc\u77f3\u7dbf\u7e96\u7dad\u9694\u819c\u5c6c\u65bc\u7269\u7406\u6027\u7684\u963b\u7d55\uff0c\u9223\u3001\u9382\u96e2\u5b50\u5728\u9e7c\u6027\u74b0\u5883\u4e0b\u6703\u7522\u751f\u6c2b\u6c27\u5316\u9223\u3001\u6c2b\u6c27\u5316\u9382\u6c89\u6fb1\u5728\u9694\u819c\u4e0a\uff0c\u9694\u819c\u58fd\u547d\u7c21\u77ed\u3002\u82e5\u4eba\u9ad4\u4e0d\u614e\u5438\u5165\u77f3\u7dbf\u7c89\u5875\u6703\u5c0e\u81f4\u80ba\u90e8\u7e96\u7dad\u5316\u4e14\u81f4\u764c\u3002<\/p>\n

\"p1\"<\/a>

\u5716\u4e00$$~~~$$\u9694\u819c\u6cd5<\/p><\/div>\n

\u6c5e\u6975\u6cd5\uff08Mercury cell process\u6216Castner-Kellner process\uff09<\/strong><\/span><\/p>\n

\u6c5e\u6975\u6cd5\u662f\u4ee5\u6c5e\u91d1\u5c6c\u4f5c\u70ba\u96fb\u89e3\u7684\u9670\u6975\uff0c\u96fb\u89e3\u8cea\u6eb6\u6db2\u7684\u967d\u96e2\u5b50\u9084\u539f\u6790\u51fa\u7684\u91d1\u5c6c\u53ef\u8207\u6c5e\u5f62\u6210\u6c5e\u9f4a\uff08amalgam\uff09\uff0c\u9209\u91d1\u5c6c\u8207\u6c5e\u7d50\u5408\u5373\u5f62\u6210\u9209\u6c5e\u9f4a\uff0c\u7531\u65bc\u6c5e\u70ba\u5bc6\u5ea6\u5927\u4e4b\u6db2\u9ad4\uff0c\u53ef\u5e73\u8cbc\u5728\u96fb\u89e3\u69fd\u5e95\u90e8\u901a\u4e0a\u76f4\u6d41\u96fb\uff0c\u70ba\u9670\u6975\uff0c\u9670\u6975\u548c\u967d\u6975\u9593\u7684\u8ddd\u96e2\u61c9\u9069\u7576\u8abf\u7bc0\uff0c\u907f\u514d\u77ed\u8def\uff0c\u96fb\u89e3\u69fd\u5e95\u90e8\u8a2d\u8a08\u6210\u5c0f\u5e45\u5ea6\u50be\u659c\u7684\u539a\u92fc\u677f\uff0c\u4f7f\u9209\u6c5e\u9f4a\u80fd\u671d\u4f4e\u8655\u6d41\u52d5\uff0c\u9209\u6c5e\u9f4a\u5c07\u6d41\u5411\u89e3\u6c5e\u5668\uff0c\u7d93\u71b1\u6c34\u5206\u89e3\u6210\u6c5e\u3001\u6c2b\u6c23\u548c\u6c2b\u6c27\u5316\u9209\u6eb6\u6db2\u3002\u6c5e\u85c9\u7531\u5e6b\u6d66\u56de\u5230\u96fb\u89e3\u69fd\u5167\u91cd\u65b0\u4f7f\u7528\uff0c\u6b64\u70ba\u6c34\u9280\u5faa\u74b0\u7dda\u8def\u3002\u6c2b\u6c23\u7d93\u51b7\u537b\u5668\u51b7\u537b\u9664\u53bb\u6c5e\u84b8\u6c23\uff1b\u6c2b\u6c27\u5316\u9209\u6eb6\u6db2\u7d93\u904e\u6d3b\u6027\u78b3\u9664\u53bb\u6c5e\u5fae\u7c92\uff0c\u6b64\u6cd5\u751f\u7522\u7684\u6c2b\u6c27\u5316\u9209\u6fc3\u5ea6\u7279\u5225\u9ad8\uff0c\u53ef\u7528\u65bc\u4eba\u9020\u7d72\u7684\u88fd\u9020\u3002<\/p>\n

\u6c2f\u6c23\u5728\u77f3\u58a8\u967d\u6975\u4e0a\u7522\u751f\uff0c\u7a7f\u904e\u98df\u9e7d\u6c34\u5c64\u5192\u51fa\uff0c\u7531\u4e0a\u65b9\u51fa\u53e3\u7ba1\u6536\u96c6\uff0c\u6703\u647b\u96dc\u9670\u6975\u7522\u751f\u7684\u6c2b\u6c23\u3002\u96fb\u89e3\u5f8c\u5269\u9918\u7684\u7a00\u98df\u9e7d\u6c34\uff0c\u7d93\u6c2f\u5316\u6c2b\u9178\u5316\u3001\u5439\u5165\u7a7a\u6c23\u812b\u6c2f\uff0c\u518d\u52a0\u5165\u5927\u91cf\u7684\u6c2f\u5316\u9209\u56fa\u9ad4\uff0c\u4f7f\u5176\u98fd\u548c\uff0c\u4e26\u53bb\u9664\u9382\u3001\u9223\u7b49\u96dc\u8cea\uff0c\u91cd\u65b0\u56de\u5230\u96fb\u89e3\u69fd\u5167\u518d\u5229\u7528\uff0c\u6b64\u70ba\u98df\u9e7d\u6c34\u5faa\u74b0\u7dda\u8def\u3002<\/p>\n

\u6b64\u6cd5\u53ef\u751f\u7522\u9ad8\u7d14\u5ea6\u6c2b\u6c27\u5316\u9209\u3001\u6c2f\u6c23\u548c\u6c2b\u6c23\uff0c\u4f46\u662f\u7522\u51fa\u7684\u7522\u54c1\u53ca\u5ee2\u68c4\u7269\u5747\u542b\u6709\u5c11\u91cf\u6c34\u9280\uff1b\u4f4e\u6fc3\u5ea6\u7684\u96dc\u8cea\uff0c\u5982\u9382\u3001\u9223\u3001\u9435\uff0c\u6c89\u7a4d\u7522\u751f\u6c5e\u6c61\u6ce5\uff0c\u5bb9\u6613\u9020\u6210\u571f\u58e4\u6c61\u67d3\uff0c\u5f15\u8d77\u6c34\u4fc1\u75c5\uff0c\u81fa\u7063\u6c2f\u9e7c\u5de5\u696d\u5df2\u57281988\u5e74\u5e95\u5b8c\u5168\u7981\u6b62\u4f7f\u7528\u6c5e\u6975\u6cd5\u88fd\u6210\uff0c\u73fe\u5728\u5df2\u88ab\u8584\u819c\u6cd5\u53d6\u4ee3\u3002<\/p>\n

\"p2\"<\/a>

\u5716\u4e8c$$~~~$$\u6c5e\u6975\u6cd5<\/p><\/div>\n

\u8584\u819c\u6cd5\uff08Membrane cell process\uff09<\/strong><\/span><\/p>\n

\u8584\u819c\u6cd5\u662f1972\u958b\u59cb\u4f7f\u7528\u7684\u65b9\u6cd5\uff0c\u5229\u7528\u96e2\u5b50\u4ea4\u63db\u819c\u9694\u958b\u9670\u967d\u6975\uff0c\u967d\u6975\u5074\u6ce8\u5165\u7cbe\u9e7d\u6c34\uff0c\u6c27\u5316\u751f\u6210\u6c2f\u6c23\uff0c\u9670\u6975\u5074\u6ce8\u5165\u8d85\u7d14\u6c34\uff0c\u96fb\u89e3\u6c34\u7522\u751f\u6c2b\u6c23\u548c\u6c2b\u6c27\u6839\u96e2\u5b50\uff0c\u96e2\u5b50\u4ea4\u63db\u819c\u53ea\u5141\u8a31\u6b63\u96e2\u5b50\u901a\u904e\uff0c\u4ee5\u4fbf\u9209\u96e2\u5b50\u80fd\u548c\u6c2b\u6c27\u6839\u96e2\u5b50\u7d50\u5408\u751f\u6210\u6c2b\u6c27\u5316\u9209\uff0c\u540c\u6642\u907f\u514d\u6c2f\u6c23\u548c\u6c2b\u6c27\u6839\u96e2\u5b50\u767c\u751f\u53cd\u61c9\u751f\u6210\u6b21\u6c2f\u9178\u6839$$(\\mathrm{Cl_2+2OH^-\\longrightarrow Cl^-+ClO^-+H_2O})$$\u3002\u96e2\u5b50\u4ea4\u63db\u819c\u6cd5\u7684\u96fb\u89e3\u69fd\u7684\u8cbb\u7528\u6700\u4f4e\uff0c\u4e14\u5e7e\u4e4e\u6c92\u6709\u516c\u5bb3\u6c59\u67d3\u554f\u984c\uff0c\u662f\u76ee\u524d\u53f0\u7063\u6c2f\u9e7c\u5de5\u696d\u4e2d\u7684\u4e3b\u6d41\u751f\u7522\u65b9\u5f0f\u3002<\/p>\n

\"p3\"<\/a>

\u5716\u4e09$$~~~$$\u8584\u819c\u6cd5<\/p><\/div>\n

\n

\u53c3\u8003\u8cc7\u6599<\/strong><\/p>\n

    \n
  1. \u9694\u819c\u6cd5
    \n    http:\/\/www.twwiki.com\/wiki\/%E9%9A%94%E8%86%9C%E9%9B%BB%E8%A7%A3%E6%B3%95<\/a><\/li>\n
  2. \u6c5e\u6975\u6cd5
    \n    http:\/\/www.baike.com\/wiki\/%E6%B0%B4%E9%93%B6%E7%94%B5%E8%A7%A3%E6%B3%95<\/a><\/li>\n
  3. \u8584\u819c\u6cd5
    \n    http:\/\/dmt.zjlsedu.org\/longresgz\/300\/050\/130\/070\/L000000000097633.htm<\/a><\/li>\n
  4. \u5716\u7247\u4f86\u6e90
    \n\uff08\u5716\u4e00\uff09    http:\/\/www.eurochlor.org\/media\/7818\/diaphragm_300dpi2.pdf<\/a>
    \n\uff08\u5716\u4e8c\u3001\u4e09\uff09    http:\/\/www.ineris.fr\/ippc\/sites\/default\/interactive\/brefca\/bref_gb2.htm<\/a><\/li>\n<\/ol>\n<\/div>","protected":false},"excerpt":{"rendered":"

    \u5de5\u696d\u98df\u9e7d\u6c34\u96fb\u89e3\u6cd5 \u570b\u7acb\u81fa\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u5b78\u58eb\u73ed\u4e09\u5e74\u7d1a \u4fde\u59ff\u5b87 \u5728\u6c2f\u9e7c\u5de5\u696d\u4e0a\uff0c\u96fb\u89e3\u98df\u9e7d\u6c34\u88fd\u9020\u6c2f\u6c23\u3001\u71d2\u9e7c\uff08\u6c2b\u6c27\u5316\u9209…<\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[108,78,77],"tags":[7329,7330,7328],"class_list":["post-58324","post","type-post","status-publish","format-standard","hentry","category-chemistry00","category-chemistry08-01","category-chemistry08","tag-7329","tag-7330","tag-7328","loop-entry","cat-108","cat-78","cat-77","no-thumbnail"],"views":18454,"_links":{"self":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/58324","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/comments?post=58324"}],"version-history":[{"count":1,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/58324\/revisions"}],"predecessor-version":[{"id":86751,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/58324\/revisions\/86751"}],"wp:attachment":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/media?parent=58324"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/categories?post=58324"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/tags?post=58324"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}