{"id":4863,"date":"2009-09-21T06:34:54","date_gmt":"2009-09-20T22:34:54","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=4863"},"modified":"2021-10-06T16:46:55","modified_gmt":"2021-10-06T08:46:55","slug":"%e9%85%b8%e9%b9%bc%e6%8c%87%e7%a4%ba%e5%8a%91%ef%bc%88acid-base-indicator%ef%bc%89%e7%9a%84%e8%ae%8a%e8%89%b2%e5%8e%9f%e7%90%86","status":"publish","type":"post","link":"http:\/\/localhost\/%e9%85%b8%e9%b9%bc%e6%8c%87%e7%a4%ba%e5%8a%91%ef%bc%88acid-base-indicator%ef%bc%89%e7%9a%84%e8%ae%8a%e8%89%b2%e5%8e%9f%e7%90%86\/","title":{"rendered":"\u9178\u9e7c\u6307\u793a\u5291\uff08Acid-Base Indicator\uff09\u7684\u8b8a\u8272\u539f\u7406"},"content":{"rendered":"<div class=\"pf-content\"><p><span style=\"color: #ff6600;\"><strong>\u9178\u9e7c\u6307\u793a\u5291\uff08Acid-Base Indicator\uff09\u7684\u8b8a\u8272\u539f\u7406<\/strong><\/span><br \/>\n<span style=\"color: #008000;\">\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u6797\u96c5\u51e1\u535a\u58eb\/\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u674e\u4fca\u6bc5\u8cac\u4efb\u7de8\u8f2f<\/span><\/p>\n<p>\u9178\u9e7c\u6307\u793a\u5291\u7121\u8ad6\u5c0d\u65bc\u5224\u5b9a\u7269\u8cea\u7684 pH\u503c\uff0c\u6216\u662f\u61c9\u7528\u65bc\u9178\u9e7c\u6ef4\u5b9a\u4e0a\uff0c\u90fd\u626e\u6f14\u8457\u91cd\u8981\u7684\u89d2\u8272\u3002\u65e9\u5728\u5341\u4e03\u4e16\u7d00\uff0c\u4eba\u5011\u5c31\u958b\u59cb\u5728\u5404\u6a23\u7684\u7814\u7a76\u4e0a\u5229\u7528\u6307\u793a\u5291\uff0c\u7136\u800c\u537b\u9072\u81f3\u5341\u4e5d\u4e16\u7d00\u672b\uff0c\u79d1\u5b78\u5bb6\u624d\u958b\u59cb\u5c0d\u300c\u70ba\u4ec0\u9ebc\u9178\u9e7c\u6307\u793a\u5291\u5728\u4e0d\u540c\u7684pH\u503c\u4e4b\u4e0b\u6703\u5448\u4e0d\u540c\u984f\u8272\uff1f\u300d\u9019\u6a23\u7684\u554f\u984c\u6709\u8f03\u6df1\u5165\u5730\u63a2\u8a0e\u3002\u6700\u5148\u5c0d\u9019\u73fe\u8c61\u63d0\u51fa\u89e3\u91cb\u7684\uff0c\u662f\u5fb7\u570b\u5316\u5b78\u5bb6\u5a01\u5ec9\u2022\u5967\u58eb\u83ef\uff08Wilhelm Ostwald\uff09\uff0c\u5f8c\u4f86\u7d93\u904e\u6f22\u8332\u8a31\uff08A. Hantzsch\uff09\u3001\u79d1\u723e\u7d22\u592b\uff08I. M. Kolthoff\uff09\u4ee5\u53ca\u53f2\u7b2c\u683c\u7acb\u8332\uff08Julius Stiegliez, 1867-1937\uff09\u7b49\u4eba\u7684\u7814\u7a76\u3001\u4fee\u6b63\u8207\u6b78\u7d0d\u5f8c\uff0c\u63d0\u51fa\u73fe\u4eca\u6211\u5011\u6240\u8a8d\u540c\u7684\u9178\u9e7c\u6307\u793a\u5291\u8b8a\u8272\u7406\u8ad6\u3002<\/p>\n<p>\u300c\u6c7a\u5b9a\u6307\u793a\u5291\u8b8a\u8272\u7684\u56e0\u7d20\u662f\u4ec0\u9ebc\uff1f\u300d\u8a00\u7c21\u610f\u8cc5\u7684\u8aaa\uff0c\u5c31\u662f\u300c\u5e73\u8861\u300d\u3002\u4e00\u822c\u5e38\u7528\u7684\u6307\u793a\u5291\u672c\u8eab\u5373\u662f\u4e00\u7a2e\u5f31\u9178\u6216\u5f31\u9e7c\uff0c\u6240\u4ee5\u7f6e\u65bc\u6eb6\u6db2\u4e2d\uff0c\u81ea\u7136\u6709\u5fae\u5f31\u7684\u89e3\u96e2\u73fe\u8c61\u7522\u751f\uff0c\u800c\u80fd\u5beb\u6210\u5982\u5f0f\u4e00\u7684\u5e73\u8861\u5f0f\u3002<\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/09\/Acid-Base-Indicator-1.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-13268\" title=\"Acid-Base Indicator-1\" alt=\"\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/09\/Acid-Base-Indicator-1.png\" width=\"500\" height=\"51\" \/><\/a><!--more--><\/p>\n<p>\u5728\u9054\u5230\u5e73\u8861\u7684\u6642\u5019\uff0c\u6b64\u5f31\u9178\u6307\u793a\u5291\uff08\u5728\u6b64\u4ee5\u5f31\u9178\u5f62\u5f0f\u7684\u6307\u793a\u5291\u70ba\u4f8b\uff09\u7684\u5e73\u8861\u5e38\u6578K<sub>AI<\/sub>\u53ef\u8868\u9054\u6210\u5982\u5f0f\u4e8c\u3002<\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/09\/Acid-Base-Indicator-2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-13270\" title=\"Acid-Base Indicator-2\" alt=\"\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/09\/Acid-Base-Indicator-2.png\" width=\"300\" height=\"85\" \/><\/a><br \/>\n\u82e5\u5c07\u5f0f\u4e8c\u9032\u4e00\u6b65\u6539\u5beb\uff0c\u53ef\u4ee5\u5f97\u5230\u5982\u5f0f\u4e09\u7684\u7b49\u5f0f\u3002<\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/09\/Acid-Base-Indicator-3.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-13271\" title=\"Acid-Base Indicator-3\" alt=\"\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/09\/Acid-Base-Indicator-3.png\" width=\"350\" height=\"97\" \/><\/a><br \/>\n\u800c\u53ef\u4ee5\u4f5c\u70ba\u6307\u793a\u5291\u5206\u5b50\u7684\uff0c\u901a\u5e38\u5177\u5099\u4e00\u500b\u57fa\u672c\u7279\u6027\uff0c\u90a3\u5c31\u662f\u5f31\u9178\uff08\u9e7c\uff09\u6027\u6307\u793a\u5291\u5206\u5b50\uff08HIn\uff09\u8207\u5176\u89e3\u96e2\u5f8c\u7684\u5171\u8edb\u7d50\u69cb\uff08In<sup>&#8211;<\/sup>\uff09\u6240\u5448\u73fe\u7684\u984f\u8272\u662f\u4e0d\u540c\u7684\u3002\u5982\u6b64\u4e00\u4f86\uff0c\u7576[H<sub>3<\/sub>O<sup>+<\/sup>\u201c&gt; &gt; 10 K<sub>AI<\/sub>\u6642\uff0c\u6eb6\u6db2\u8f03\u6613\u8868\u73fe\u51faHIn\u7684\u984f\u8272\uff1b\u76f8\u53cd\u5730\uff0c\u5982\u679c[H<sub>3<\/sub>O <sup>+<\/sup>\u201c&gt; &lt; K<sub>AI<\/sub>\/10\uff0c\u6eb6\u6db2\u5448\u8272\u5c31\u6703\u53d7In<sup>&#8211;<\/sup>\u7684\u984f\u8272\u4e3b\u5c0e\u3002<\/p>\n<p>\u6240\u4ee5\u7406\u8ad6\u4e0a\uff0c\u82e5\u8981\u4ee5\u6307\u793a\u5291\u6e2c\u6eb6\u6db2\u4e2d\u7684pH\u503c\uff0c\u7531\u5f0f\u4e09\uff0c\u7576[H<sub>3<\/sub>O <sup>+<\/sup>\u201c&gt;=K<sub>AI<\/sub>\u6642\uff0c\u80fd\u6e2c\u5f97\u6700\u6e96\u78ba\u7684\u7d50\u679c\uff0c\u56e0\u70ba\u5728\u6b64\u6642\uff0c[HIn\u201d&gt;=[In<sup>&#8211;<\/sup>\u201c&gt;\uff0c\u6eb6\u6db2\u5448\u8272\u61c9\u662f\u5169\u7a2e\u5f62\u5f0f\u6307\u793a\u5291\u984f\u8272\u6df7\u5408\u7684\u7d50\u679c\u3002\u7136\u800c\u5be6\u969b\u4e0a\uff0c\u6307\u793a\u5291\u7684\u8b8a\u8272\u4e26\u975e\u5728[H<sub>3<\/sub>O <sup>+<\/sup>\u201c&gt;=K<sub>AI<\/sub>\u7684\u77ac\u9593\uff0c\u6eb6\u6db2\u7acb\u523b\u7531HIn\u6216In\u7684\u984f\u8272\uff0c\u8b8a\u70ba\u5169\u8005\u6df7\u5408\u7684\u984f\u8272\uff0c\u4e43\u662f\u5b58\u5728\u4e00\u8b8a\u8272\u7bc4\u570d\uff0c\u5728\u6b64\u7bc4\u570d\u4e4b\u5167\uff0c\u6eb6\u6db2\u90fd\u6703\u5448\u73fe\u6df7\u5408\u984f\u8272\uff0c\u800c\u4e0d\u6613\u5340\u5206\u54ea\u7a2e\u984f\u8272\u4e3b\u5c0e\u8f03\u591a\u3002\u800c\u6df7\u5408\u8272\u7bc4\u570d\u7684\u5927\u5c0f\uff0c\u5247\u6703\u56e0\u6307\u793a\u5291\u5206\u5b50\u7684\u7279\u6027\u800c\u6709\u6240\u4e0d\u540c\uff0c\u7bc4\u570d\u8f03\u7a84\u8005\uff0c\u5224\u8b80\u51fa\u4f86\u7684pH\u503c\u8d8a\u6e96\u78ba\u3002<\/p>\n<p>\u6839\u64da\u9019\u6a23\u7684\u539f\u7406\uff0c\u4e0d\u8ad6\u662f\u5229\u7528\u6307\u793a\u5291\u4f86\u5224\u65b7pH\u503c\uff0c\u6216\u662f\u7528\u5176\u4f5c\u70ba\u9178\u9e7c\u53cd\u61c9\u6ef4\u5b9a\u7d42\u9ede\u7684\u5224\u65b7\uff0c\u300c\u9078\u64c7\u9069\u7528\u7684\u6307\u793a\u5291\u300d\u5c31\u662f\u4e00\u9580\u4e0d\u53ef\u6216\u7f3a\u7684\u529f\u8ab2\u3002\u4e00\u822c\u800c\u8a00\uff0c\u6211\u5011\u6703\u9078\u64c7\u7528\u5e73\u8861\u5e38\u6578\u70baK<sub>AI<\/sub>\u7684\u6307\u793a\u5291\uff0c\u6307\u793a\u5728pK<sub>AI<\/sub>-1\u5230pK<sub>AI<\/sub>+1\u5340\u9593\u7684pH\u503c\u3002<\/p>\n<p>\u6545\u6b64\uff0c\u4e86\u89e3\u9178\u9e7c\u6307\u793a\u5291\u7684\u8b8a\u8272\u7bc4\u570d\u5c31\u975e\u5e38\u91cd\u8981\u3002\u8868\u4e00\u5217\u51fa\u4e00\u4e9b\u5be6\u9a57\u5ba4\u5e38\u898b\u7684\u6307\u793a\u5291\u53ca\u5176\u8b8a\u8272\u7bc4\u570d\u3002<\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/09\/Acid-Base-Indicator-41.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone  wp-image-13276\" title=\"Acid-Base Indicator-4\" alt=\"\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/09\/Acid-Base-Indicator-41.png\" width=\"489\" height=\"359\" \/><\/a><br \/>\n1920\u5e74\u5f8c\uff0c\u79d1\u5b78\u5bb6\u5229\u7528\u4e0d\u540c\u6fc3\u5ea6\u6bd4\u4f8b\u7684\u591a\u7a2e\u6307\u793a\u5291\u6df7\u5408\uff0c\u4f01\u5716\u958b\u59cb\u81f4\u529b\u65bc\u767c\u5c55\u51fa\u65e2\u80fd\u7cbe\u78ba\u6e2c\u51fapH\u503c\uff0c\u53c8\u9069\u7528\u65bc\u8f03\u5bec\u5ee3\u7bc4\u570d\u9178\u9e7c\u503c\u6e2c\u5b9a\u7684\u6307\u793a\u5291\u3002\u4f8b\u59821921 \u5e74\uff0c\u8cbb\u52d2\u9813\uff08Lloyd. D. Felton\uff09\u5c07\u7532\u57fa\u7d05\uff08methyl red\uff09\/\u6eb4\u745e\u9999\u8349\u915a\u85cd\uff08bromthymol blue\uff09\u9ad4\u7a4d\u83ab\u8033\u6fc3\u5ea6=1:1\u6bd4\u4f8b\u6df7\u5408\u5728\u4e00\u8d77\uff0c\u80fd\u6210\u529f\u6e2c\u5f97pH=4.6~7.6\u7bc4\u570d\u7684\u7269\u8cea\u9178\u9e7c\u503c\uff1b\u5c07\u7532\u57fa\u7d05\/\u6eb4\u7532\u915a\u7d2b\uff08bromcresol purple\uff09=1:1\u6bd4\u4f8b\u6df7\u5408\u5728\u4e00\u8d77\uff0c\u53ef\u6e2c\u5f97pH\u503c\u7bc4\u570d\u5247\u70ba4.6~7.0\uff1b\u7532\u57fa\u7570\u4e19\u915a\u85cd\uff08thymol blue\uff09\/\u6eb4\u915a\u85cd\uff08bromphenol blue\uff09=1:1\uff0c\u53ef\u6e2c\u5f97pH\u7bc4\u570d\u70ba1.2~4.6\uff1b\u7532\u57fa\u7d05\/\u7532\u57fa\u7570\u4e19\u915a\u85cd=1:1\u5247\u70ba4.6~9.0\uff1b\u897f\u51431922\u5e74\uff0c\u674e\u5409\u4fc4\u65af\uff08J. L. Lizius\uff09\u8207\u827e\u7dad\u723e\u65af\uff08Norman, Evers\uff09\u5171\u540c\u63d0\u51fa\uff0c\u5c07\u7532\u57fa\u7d05\/\u7532\u57fa\u7570\u4e19\u915a\u85cd\u9ad4\u7a4d\u83ab\u8033\u6fc3\u5ea6=1:3\u6bd4\u4f8b\u6df7\u5408\u5728\u4e00\u8d77\uff0c\u53ef\u6e2c\u5f97pH\u503c\u7bc4\u570d\u70ba4.0~10.0\uff1b\u915a\u915e\uff08phenolphthalein\uff09\/\u7532\u57fa\u7570\u4e19\u915a\u85cd=1:6\uff0c\u53ef\u6e2c\u5f97pH\u503c\u7bc4\u570d\u70ba8.0~10.0\u3002\u800c\u6700\u7d42\uff0c\u79d1\u5b78\u5bb6\u628a\u7532\u57fa\u7d05\u3001\u915a\u915e\u3001\u6eb4\u745e\u9999\u8349\u915a\u85cd\u3001\u7532\u57fa\u7570\u4e19\u915a\u85cd\u3001\u9e9d\u9999\u8349\u915a\u915e\uff08thymolphthalein\uff09\u30011-\u8418\u915a\u915e\uff08\u03b1-naphtholphthalein\uff09\u7b49\u4e94\u7a2e\u8a66\u5291\u6df7\u5408\uff0c\u5f62\u6210\u73fe\u4eca\u5ee3\u70ba\u4eba\u4f7f\u7528\u7684\u5ee3\u7528\u6307\u793a\u5291\uff08universal indicator\uff09\u3002\u8981\u63d0\u51fa\u4f86\u8aaa\u660e\u7684\uff0c\u662f\u76f4\u81f3\u4e8c\u5341\u4e16\u7d00\u4e2d\uff0c\u79d1\u5b78\u5bb6\u4ecd\u6301\u7e8c\u6539\u826f\u5ee3\u7528\u6307\u793a\u5291\u7684\u6210\u5206\uff0c\u6240\u4ee5\u82e5\u67e5\u95b1\u5176\u4ed6\u8cc7\u6599\uff0c\u5c0d\u5ee3\u7528\u6307\u793a\u5291\u7684\u6210\u5206\u8aaa\u660e\uff0c\u6216\u591a\u6216\u5c11\u6703\u6709\u4e9b\u8a31\u4e0d\u540c\uff0c\u4f46\u6700\u4e3b\u8981\u7684\u5e7e\u7a2e\u6210\u5206\u5247\u4e0d\u6703\u6709\u592a\u5927\u5dee\u7570\uff0c\u53ef\u53c3\u95b1\u53c3\u8003\u6587\u737b4\u3002<\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/09\/Acid-Base-Indicator-5.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-13275\" title=\"Acid-Base Indicator-5\" alt=\"\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/09\/Acid-Base-Indicator-5.png\" width=\"300\" height=\"335\" \/><\/a><br \/>\n<strong>\u53c3\u8003\u6587\u737b\uff1a<\/strong><br \/>\n1. Kolthoff, I. M. \u201cAcid Base Indicator\u201d <em>Lightning Source Inc.<\/em> <strong>2007<\/strong>.<br \/>\n2. Stiegilez, J. <em>J. Am. Soc. Chem.<\/em> <strong>1903<\/strong>, 539, 1112.<br \/>\n3. Felton, L. D. <em>J. Biol. Chem.<\/em> <strong>1921<\/strong>, 299.<br \/>\n4. Foster, S.F. ; Gruntfest, I. J.<em> J. Chem. Edu.<\/em>, <strong>1937<\/strong>, 14, 274.<\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"<p>\u9178\u9e7c\u6307\u793a\u5291\uff08Acid-Base Indicator\uff09\u7684\u8b8a\u8272\u539f\u7406 \u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u6797\u96c5\u51e1\u535a\u58eb\/\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78&hellip;<\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[108,67,70],"tags":[2671,241],"class_list":["post-4863","post","type-post","status-publish","format-standard","hentry","category-chemistry00","category-chemistry05","category-chemistry05-03","tag-2671","tag-241","loop-entry","cat-108","cat-67","cat-70","no-thumbnail"],"views":58217,"_links":{"self":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4863","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/comments?post=4863"}],"version-history":[{"count":1,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4863\/revisions"}],"predecessor-version":[{"id":90280,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4863\/revisions\/90280"}],"wp:attachment":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/media?parent=4863"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/categories?post=4863"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/tags?post=4863"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}