{"id":4627,"date":"2009-06-19T14:02:28","date_gmt":"2009-06-19T06:02:28","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=4627"},"modified":"2021-10-06T16:49:37","modified_gmt":"2021-10-06T08:49:37","slug":"%e4%b8%89%e8%81%9a%e6%b0%b0%e8%83%ba%ef%bc%88melamine%e6%88%96135-triazine-246-triamine%ef%bc%89","status":"publish","type":"post","link":"http:\/\/localhost\/%e4%b8%89%e8%81%9a%e6%b0%b0%e8%83%ba%ef%bc%88melamine%e6%88%96135-triazine-246-triamine%ef%bc%89\/","title":{"rendered":"\u4e09\u805a\u6c30\u80fa\uff08Melamine\u62161,3,5-Triazine-2,4,6-Triamine\uff09"},"content":{"rendered":"

\u4e09\u805a\u6c30\u80fa\uff08Melamine\u62161,3,5-Triazine-2,4,6-Triamine\uff09<\/span>
\n\u570b\u7acb\u53f0\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u78a9\u58eb\u751f\u856d\u5168\u4f51\/\u570b\u7acb\u53f0\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u8449\u540d\u5009\u6559\u6388\u8cac\u4efb\u7de8\u8f2f<\/span><\/strong><\/p>\n

\"\"<\/a><\/p>\n

\u6027\u8cea<\/strong>
\n\u4e09\u805a\u6c30\u80fa\u7684\u5316\u5b78\u5f0f\u70baC3<\/sub>H6<\/sub>N6<\/sub>\uff0c\u5206\u5b50\u91cf126.12 g mol-1<\/sup>\uff0cIUPAC\u547d\u540d\uff1a1,3,5-Triazine-2,4,6-Triamine\uff0c\u4fd7\u7a31\u5bc6\u80fa\u3001\u6c30\u5c3f\u91af\u80fa\u3001\u4e09\u805a\u91af\u80fa\u3001\u86cb\u767d\u7cbe\uff0c\u662f\u4e00\u7a2e\u767d\u8272\u55ae\u659c\u6676\u9ad4\uff0c\u5e7e\u4e4e\u7121\u5473\u7684\u4e09\u55ea\u985e\uff08Triazine\uff09\u542b\u6c2e\u96dc\u74b0\u6709\u6a5f\u5316\u5408\u7269\u3002\u5bc6\u5ea61.574 g\/cm3<\/sup>\uff0c\u7194\u9ede250 \u00b0C\uff0c\u53ef\u5fae\u6eb6\u65bc\u6c34\uff083.1g\/L\uff0c20\u00b0C\uff09\uff0c\u53ef\u6eb6\u65bc\u7532\u9187\u3001\u7532\u919b\u3001\u4e59\u9178\u3001\u71b1\u4e59\u4e8c\u9187\u3001\u7518\u6cb9\u3001\u5421\u5576\u7b49\uff0c\u4e0d\u6eb6\u65bc\u4e19\u916e\u3001\u919a\u985e\u3002\u4e09\u805a\u6c30\u80fa\u9047\u5f37\u9178\u6216\u5f37\u9e7c\u6c34\u6eb6\u6db2\u53ef\u88ab\u6c34\u89e3\uff0c\u6c28\u57fa\u6703\u9010\u6b65\u88ab\u7fa5\u57fa\u53d6\u4ee3\uff0c\u9996\u5148\u751f\u6210\u4e09\u805a\u6c30\u9178\u4e8c\u91af\u80fa\uff0c\u9032\u4e00\u6b65\u6c34\u89e3\u751f\u6210\u4e09\u805a\u6c30\u9178\u4e00\u91af\u80fa\uff0c\u6700\u5f8c\u751f\u6210\u4e09\u805a\u6c30\u9178\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u5408\u6210<\/strong>
\n\u4e09\u805a\u6c30\u80fa\u6700\u65e9\u65bc1834\u5e74\u7531\u5fb7\u570b\u5316\u5b78\u5bb6Justus von Liebig\u6240\u5408\u6210\u7684\uff0c\u7576\u521d\u65e9\u671f\u5408\u6210\u65b9\u6cd5\u4fc2\u5148\u5c07\u96fb\u77f3\uff08CaC2<\/sub>\uff09\u88fd\u5099\u6210\u6c30\u80fa\u5316\u9223\uff08Ca(CN)2<\/sub>\uff09\uff0c\u6c30\u80fa\u5316\u9223\u6c34\u89e3\u5f8c\u4e8c\u805a\u751f\u6210\u96d9\u6c30\u80fa\uff08dicyandiamide\uff09\uff0c\u518d\u52a0\u71b1\u8d85\u904e\u5176\u7194\u9ede\u800c\u88fd\u5099\u5f97\u5230\u4e09\u805a\u6c30\u80fa\u3002<\/p>\n

\u76ee\u524d\u5de5\u696d\u4e0a\u5247\u4e3b\u8981\u4f7f\u7528\u5c3f\u7d20\uff08urea\uff09\u70ba\u539f\u6599\uff0c\u4ee5\u6c28\u6c23\u70ba\u8f09\u9ad4\uff0c\u77fd\u81a0\u70ba\u50ac\u5316\u5291\uff0c\u5728380-400\u2103\u6eab\u5ea6\u4e0b\u6cb8\u9a30\u53cd\u61c9\uff0c\u5148\u5206\u89e3\u751f\u6210\u6c30\u9178\uff0c\u4e26\u9032\u4e00\u6b65\u7e2e\u5408\u751f\u6210\u4e09\u805a\u6c30\u80fa\uff0c\u6b64\u53cd\u61c9\u70ba\u5438\u71b1\u53cd\u61c9\u3002
\n6 (NH2<\/sub>)2<\/sub>CO \u2192 C3<\/sub>H6<\/sub>N6<\/sub> + 6 NH3<\/sub> + 3 CO2<\/sub>, \u0394H > 0
\n\u76ee\u524d\u5df2\u77e5\u4e3b\u8981\u7d93\u7531\u5169\u6b65\u9a5f\u53cd\u61c9\u5b8c\u6210\u3002\u9996\u5148\u5c3f\u7d20\u5206\u89e3\u751f\u6210\u6c30\u9178\uff08cyanic acid\uff09\u53ca\u6c28\uff08amine\uff09\uff0c\u6b64\u53cd\u61c9\u70ba\u5438\u71b1\u53cd\u61c9\uff08endothermic reaction\uff09\u3002
\n(NH2<\/sub>)2<\/sub>CO \u2192 HOCN + NH3<\/sub>, \u0394H > 0
\n\u6c30\u9178\u805a\u5408\u5f62\u6210\u4e09\u805a\u6c30\u80fa\u4e26\u91cb\u653e\u51fa\u4e8c\u6c27\u5316\u78b3\uff0c\u6b64\u53cd\u61c9\u70ba\u653e\u71b1\u53cd\u61c9\uff08exothermic reaction\uff09\u3002
\n6 HOCN \u2192 C3<\/sub>H6<\/sub>N6<\/sub> + 3 CO2<\/sub>, \u0394H < 0<\/p>\n

\u7528\u9014<\/strong>
\n\u4e09\u805a\u6c30\u80fa\u662f\u4e00\u7a2e\u7528\u9014\u5ee3\u6cdb\u7684\u57fa\u672c\u6709\u6a5f\u5316\u5de5\u4e2d\u9593\u7522\u54c1\uff0c\u6700\u4e3b\u8981\u7684\u7528\u9014\u662f\u4f5c\u70ba\u751f\u7522\u4e09\u805a\u6c30\u80fa\u7532\u919b\u6a39\u8102\uff08melamine formaldehyde resin, MF\uff09\u7684\u539f\u6599\uff0c\u53c8\u7a31\u70ba\u7f8e\u8010\u76bf\uff08Melamine\uff09\u3002\u8a72\u6a39\u8102\u786c\u5ea6\u6bd4\u5c3f\u7d20\u7532\u919b\u6a39\u8102\uff08urea formaldehyde resin, UF\uff09\u9ad8\uff0c\u4e0d\u6613\u71c3\uff0c\u8010\u6c34\u3001\u8010\u71b1\u3001\u8010\u8001\u5316\u3001\u8010\u96fb\u5f27\u3001\u8010\u5316\u5b78\u8150\u8755\u3001\u6709\u826f\u597d\u7684\u7d55\u7de3\u6027\u80fd\u3001\u5149\u6fa4\u5ea6\u548c\u6a5f\u68b0\u5f37\u5ea6\uff0c\u5ee3\u6cdb\u904b\u7528\u65bc\u6728\u6750\u3001\u5851\u81a0\u3001\u5857\u6599\u3001\u9020\u7d19\u3001\u7d21\u7e54\u3001\u76ae\u9769\u3001\u96fb\u6c23\u3001\u91ab\u85e5\u7b49\u884c\u696d\u3002\u5176\u4e3b\u8981\u7528\u9014\u6709\u4ee5\u4e0b\u5e7e\u65b9\u9762\uff1a
\n\uff081\uff09\u88dd\u98fe\u9762\u677f\uff1a\u53ef\u88fd\u6210\u9632\u706b\u3001\u6297\u9707\u3001\u8010\u71b1\u7684\u5c64\u58d3\u677f\uff0c\u8272\u6fa4\u9bae\u8c54\u3001\u5805\u56fa\u8010\u71b1\u7684\u88dd\u98fe\u677f\uff0c\u4f5c\u98db\u6a5f\u3001\u8239\u8236\u548c\u50a2\u4ff1\u7684\u8cbc\u9762\u677f\u53ca\u9632\u706b\u3001\u6297\u9707\u3001\u8010\u71b1\u7684\u623f\u5c4b\u88dd\u98fe\u6750\u6599\u3002
\n\uff082\uff09\u5857\u6599\uff1a\u7528\u4e01\u9187\u3001\u7532\u9187\u919a\u5316\u5f8c\uff0c\u4f5c\u70ba\u9ad8\u7d1a\u71b1\u56fa\u6027\u5857\u6599\u3001\u56fa\u9ad4\u7c89\u672b\u5857\u6599\u7684\u81a0\u806f\u5291\u3001\u53ef\u88fd\u4f5c\u91d1\u5c6c\u5857\u6599\u548c\u8eca\u8f1b\u3001\u96fb\u5668\u7528\u9ad8\u6a94\u6c28\u57fa\u6a39\u8102\u88dd\u98fe\u6f06\u3002
\n\uff083\uff09\u6a21\u5851\u7c89\uff1a\u7d93\u6df7\u7149\u3001\u9020\u7c92\u7b49\u5de5\u5e8f\u53ef\u88fd\u6210\u871c\u80fa\u6a39\u8102\uff08melamine resin\uff09\uff0c\u7121\u6bd2\u3001\u6297\u6c59\uff0c\u6f6e\u6fd5\u6642\u4ecd\u80fd\u4fdd\u6301\u826f\u597d\u7684\u96fb\u6c23\u6027\u80fd\uff0c\u53ef\u88fd\u6210\u6f54\u767d\u3001\u8010\u6454\u6253\u7684\u65e5\u7528\u5668\u76bf\u3001\u885b\u751f\u6f54\u5177\u548c\u4eff\u74f7\u9910\u5177\uff0c\u96fb\u5668\u8a2d\u5099\u7b49\u9ad8\u7d1a\u7d55\u7de3\u6750\u6599\u3002
\n\uff084\uff09\u7d19\u5f35\uff1a\u7528\u4e59\u919a\u919a\u5316\u5f8c\u53ef\u7528\u4f5c\u7d19\u5f35\u8655\u7406\u5291\uff0c\u751f\u7522\u6297\u76ba\u3001\u6297\u7e2e\u3001\u4e0d\u8150\u721b\u7684\u9214\u7968\u548c\u8ecd\u7528\u5730\u5716\u7b49\u9ad8\u7d1a\u7d19\u3002
\n\uff085\uff09\u4e09\u805a\u6c30\u80fa\u7532\u919b\u6a39\u8102\u8207\u5176\u4ed6\u539f\u6599\u6df7\u914d\uff0c\u9084\u53ef\u4ee5\u751f\u7522\u51fa\u7e54\u7269\u6574\u7406\u5291\u3001\u76ae\u9769\u97a3\u6f64\u5291\u3001\u4e0a\u5149\u5291\u548c\u6297\u6c34\u5291\u3001\u6a61\u81a0\u7c98\u5408\u5291\u3001\u52a9\u71c3\u5291\u3001\u9ad8\u6548\u6c34\u6ce5\u6e1b\u6c34\u5291\u3001\u92fc\u6750\u6de1\u5316\u5291\u7b49\u3002<\/p>\n

\u6bd2\u6027<\/strong>
\n\u76ee\u524d\u4e09\u805a\u6c30\u80fa\u88ab\u8a8d\u70ba\u6bd2\u6027\u8f15\u5fae\uff0c\u4e00\u822c\u6210\u5e74\u4eba\u8eab\u9ad4\u6703\u6392\u51fa\u5927\u90e8\u5206\u7684\u4e09\u805a\u6c30\u80fa\uff0c\u4e0d\u904e\u5982\u679c\u82e5\u8207\u4e09\u805a\u6c30\u9178\u4e26\u7528\uff0c\u6703\u5f62\u6210\u7121\u6cd5\u6eb6\u89e3\u7684\u6c30\u5c3f\u9178\u4e09\u805a\u6c30\u80fa\uff0c\u9020\u6210\u56b4\u91cd\u7684\u814e\u7d50\u77f3\u3002\u56e0\u6b64\u70ba\u4e86\u5b89\u5168\u8d77\u898b\uff0c\u4e00\u822c\u63a1\u7528\u4e09\u805a\u6c30\u80fa\u88fd\u9020\u7684\u98df\u5177\uff08\u5982\uff1a\u7f8e\u8010\u76bf\uff09\u90fd\u61c9\u6a19\u660e\u201c\u4e0d\u53ef\u653e\u9032\u5fae\u6ce2\u7210\u4f7f\u7528\u201d\u3002
\n\u5927\u9f20\u53e3\u670d\u7684\u534a\u6578\u81f4\u6b7b\u91cf\u70ba\u6bcf\u516c\u65a43248\u6beb\u514b\uff1b\u5c0d\u65bc\u5154\u5b50\u534a\u6578\u81f4\u6b7b\u91cf\u5247\u8d85\u904e\u6bcf\u516c\u65a41000\u6beb\u514b\u3002\u64da1945\u5e74\u7684\u4e00\u500b\u5be6\u9a57\u5831\u5c0e\uff1a\u5c07\u5927\u5291\u91cf\u7684\u4e09\u805a\u6c30\u80fa\u98fc\u5582\u7d66\u5927\u9f20\u3001\u5154\u548c\u72d7\u5f8c\u6c92\u6709\u89c0\u5bdf\u5230\u660e\u986f\u7684\u6025\u6027\u4e2d\u6bd2\u73fe\u8c61\u3002
\n\u800c\u9577\u671f\u651d\u53d6\u4e09\u805a\u6c30\u80fa\u53ef\u80fd\u9020\u6210\u751f\u6b96\u80fd\u529b\u640d\u5bb3\u3001\u8180\u80f1\u6216\u814e\u7d50\u77f3\u3001\u8180\u80f1\u764c\u7b49\u30021983\u5e74\u7f8e\u570b\u91dd\u5c0d\u4e09\u805a\u6c30\u80fa\u9032\u884c\u52d5\u7269\u5be6\u9a57\u7814\u7a76\uff0c\u767c\u73fe\u7528\u4e09\u805a\u6c30\u80fa\u9ad8\u5291\u91cf\uff084500 ppm or 263 mg\/kg bw\/day\uff09\u548c\u6301\u7e8c\uff08\u5169\u5e74\uff09\u5730\u9935\u98df\u96c4\u9f20\u6703\u9020\u6210\u5176\u8180\u80f1\u7d50\u77f3\uff0c\u4e26\u589e\u52a0\u5176\u8180\u80f1\u3001\u5c3f\u9053\u51fa\u73fe\u60e1\u6027\u816b\u7624\u7684\u98a8\u96aa\u3002
\n\u76ee\u524d\u5c0d\u65bc\u4e09\u805a\u6c30\u80fa\u5f62\u6210\u814e\u7d50\u77f3\u7684\u6a5f\u5236\u4e26\u4e0d\u662f\u5f88\u6e05\u695a\uff0c\u800c\u904e\u53bb\u91ab\u5b78\u7814\u7a76\u767c\u73fe\u5728\u98df\u54c1\u4e2d\u53ea\u6709\u540c\u6642\u542b\u6709\u4e09\u805a\u6c30\u80fa\u548c\u4e09\u805a\u6c30\u9178\u9019\u5169\u7a2e\u5316\u5b78\u6210\u5206\u6642\u624d\u5c0d\u5b30\u5152\u5065\u5eb7\u69cb\u6210\u5a01\u8105\u3002\u96d6\u7136\u9019\u770b\u8d77\u4f86\u597d\u50cf\u5169\u7a2e\u5316\u5408\u7269\u5171\u540c\u4f5c\u7528\u4e0b\u624d\u6703\u5c0e\u81f4\u814e\u7d50\u77f3\uff0c\u4f46\u6709\u7814\u7a76\u8a8d\u70ba\uff0c\u4e09\u805a\u6c30\u80fa\u9032\u5165\u4eba\u9ad4\u5f8c\uff0c\u5728\u80c3\u7684\u5f37\u9178\u6027\u74b0\u5883\u4e2d\u6703\u6709\u90e8\u5206\u6c34\u89e3\u6210\u70ba\u4e09\u805a\u6c30\u9178\uff0c\u4e4b\u5f8c\u9032\u5165\u814e\u7d30\u80de\u5f8c\uff0c\u4e09\u805a\u6c30\u80fa\u8207\u4e09\u805a\u6c30\u9178\u5f62\u6210\u5927\u7684\u7db2\u72c0\u7d50\u6676\u7d50\u69cb\u6c89\u6fb1\uff0c\u9020\u6210\u814e\u7d50\u77f3\u4e26\u5835\u585e\u814e\u5c0f\u7ba1\uff0c\u4e26\u6709\u53ef\u80fd\u6700\u7d42\u5c0e\u81f4\u814e\u8870\u7aed\u3002
\n\u7531\u65bc\u4e09\u805a\u6c30\u80fa\u5fae\u6eb6\u65bc\u6c34\uff0c\u7d93\u5e38\u98f2\u6c34\u7684\u6210\u5e74\u4eba\u9ad4\u5167\u4e0d\u6613\u5f62\u6210\u4e09\u805a\u6c30\u80fa\u7d50\u77f3\uff0c\u4f46\u98f2\u6c34\u8f03\u5c11\u4e14\u814e\u81df\u72f9\u5c0f\u7684\u54fa\u4e73\u671f\u5b30\u5152\u9ad4\u5167\uff0c\u5247\u8f03\u6613\u5f62\u6210\u7d50\u77f3\uff0c\u9019\u4e5f\u5c31\u662f\u8fd1\u671f\u7206\u767c\u5927\u9678\u4e09\u9e7f\u5976\u7c89\u6c61\u67d3\u4e8b\u4ef6\u4e2d\u4e3b\u8981\u53d7\u5bb3\u8005\u90fd\u662f\u5b30\u5e7c\u5152\u7684\u4e3b\u56e0\u3002<\/p>\n

\u53c3\u8003\u8cc7\u6599\uff1a<\/strong>
\n1. \u4e09\u805a\u6c30\u80fa\u3002http:\/\/baike.baidu.com\/view\/298398.htm?func=retitle<\/a>
\n2. \u4e09\u805a\u6c30\u80fa\u3002http:\/\/zh.wikipedia.org\/wiki\/%E4%B8%89% \u2026 0%E8%83%BA<\/a><\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"

\u4e09\u805a\u6c30\u80fa\uff08Melamine\u62161,3,5-Triazine-2,4,6-Triamine\uff09 \u570b\u7acb\u53f0\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78…<\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[108,50,48],"tags":[459,458,1246],"class_list":["post-4627","post","type-post","status-publish","format-standard","hentry","category-chemistry00","category-chemistry01-02","category-chemistry01","tag-melamine","tag-458","tag-1246","loop-entry","cat-108","cat-50","cat-48","no-thumbnail"],"views":12920,"_links":{"self":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4627","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/comments?post=4627"}],"version-history":[{"count":1,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4627\/revisions"}],"predecessor-version":[{"id":91048,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4627\/revisions\/91048"}],"wp:attachment":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/media?parent=4627"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/categories?post=4627"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/tags?post=4627"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}