{"id":40799,"date":"2011-11-11T15:28:37","date_gmt":"2011-11-11T07:28:37","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=40799"},"modified":"2021-10-06T16:22:42","modified_gmt":"2021-10-06T08:22:42","slug":"%e7%9f%b3%e6%b2%b9%e7%9a%84%e8%84%ab%e7%a1%ab%e5%8c%96desulfurization-of-petroleum","status":"publish","type":"post","link":"http:\/\/localhost\/%e7%9f%b3%e6%b2%b9%e7%9a%84%e8%84%ab%e7%a1%ab%e5%8c%96desulfurization-of-petroleum\/","title":{"rendered":"\u77f3\u6cb9\u7684\u812b\u786b\u5316(Desulfurization of Petroleum)"},"content":{"rendered":"

\u77f3\u6cb9\u7684\u812b\u786b\u5316(Desulfurization of Petroleum)<\/span>
\n\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u5b78\u58eb\u751f\u9673\u4f73\u7ff0\/\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u9673\u85f9\u7136\u535a\u58eb\u8cac\u4efb\u7de8\u8f2f<\/span><\/strong><\/p>\n

\u77f3\u6cb9\u7684\u812b\u786b\u5316\uff0c\u662f\u5728\u5929\u7136\u6c23\u3001\u6c7d\u6cb9\u3001\u71c3\u6cb9\u6216\u77f3\u5316\u539f\u6599\uff08\u4f8b\u5982\uff1a\u7570\u4e19\u82ef\uff09\u5df2\u5206\u993e\u51fa\u4e4b\u5f8c\u3001\u8981\u52a0\u5de5\u6216\u71c3\u71d2\u4e4b\u524d\uff0c\u5c07\u5176\u4e2d\u7684\u542b\u786b\u5316\u5408\u7269\u53bb\u9664\u4e4b\u7684\u524d\u8655\u7406\u3002<\/p>\n

\u77f3\u6cb9\u662f\u7531\u53e4\u751f\u7269\u52d5\u7269\u907a\u9ab8\uff0c\u5728\u9ad8\u6eab\u9ad8\u58d3\u4e0b\u9577\u6642\u9593\u8f49\u5316\u5f62\u6210\uff0c\u800c\u52d5\u7269\u9ad4\u7d44\u6210\u591a\u70ba\u86cb\u767d\u8cea\uff0c\u6545\u77f3\u6cb9\u542b\u786b\u91cf\u5927\uff0c\u5176\u91cd\u91cf\u767e\u5206\u6bd4\u67090.5~6%\u3002\u82e5\u672a\u7d93\u8655\u7406\u800c\u76f4\u63a5\u4f5c\u70ba\u71c3\u6599\u4f7f\u7528\uff0c\u5247\u6703\u6392\u653e\u51fa\u5927\u91cf\u9178\u6027\u6c23\u9ad4\uff0c\u5982\u4e8c\u6c27\u5316\u786b\u7b49\uff0c\u9020\u6210\u9178\u96e8\u5371\u5bb3\u74b0\u5883\u3002<\/p>\n

\"\"<\/a>

\u5716\u4e00\u3001\u542b\u786b\u71c3\u6cb9\u7684\u71c3\u71d2\u3002<\/p><\/div>\n

\u9664\u9020\u6210\u9178\u96e8\u5371\u5bb3\u4e4b\u5916\uff0c\u672a\u7d93\u812b\u786b\u8655\u7406\u7684\u77f3\u5316\u539f\u6599\uff0c\u5728\u5f8c\u7e8c\u7684\u52a0\u5de5\u904e\u7a0b\u4e2d\u6613\u4f7f\u50ac\u5316\u5291\u5931\u6d3b\u3001\u8b8a\u8cea\u3002\u4f8b\u5982\u4ee5\u6cb8\u77f3(zeolite)\u88c2\u89e3\u91cd\u6cb9\u6642\uff0c\u786b\u9187\u8207\u786b\u919a\u6703\u653e\u51fa\u786b\u5206\u5b50\uff1b\u786b\u5206\u5b50\u6703\u9644\u8457\u5728\u6cb8\u77f3\u8868\u9762\uff0c\u963b\u64cb\u53cd\u61c9\u7269\u8207\u50ac\u5316\u5291\u63a5\u89f8\uff0c\u9020\u6210\u6cb8\u77f3\u5931\u6d3b\u3001\u88c2\u89e3\u6548\u7387\u9a5f\u964d\u3002<\/p>\n

\"\"<\/a>

\u5716\u4e8c\u3001\u542b\u786b\u71c3\u6cb9\u7684\u88c2\u89e3\u3002<\/p><\/div>\n

\u53e6\u5916\uff0c\u82e5\u50ac\u5316\u5291\u662f\u70ba\u91d1\u5c6c\u6216\u91d1\u5c6c\u6c27\u5316\u7269\uff0c\u5247\u5728\u904e\u7a0b\u4e2d\uff0c\u4e5f\u6613\u8207\u786b\u53cd\u61c9\u5f62\u6210\u91d1\u5c6c\u786b\u5316\u7269\u800c\u8b8a\u8cea\u3002\u4ee5\u4e59\u82ef(ethyl benzene)\u812b\u6c2b\u5316\u88fd\u82ef\u4e59\u70ef(styrene)\u70ba\u4f8b\uff0c\u5176\u50ac\u5316\u5291\u70baFe2<\/sub>O3<\/sub>-Cr2<\/sub>O3<\/sub>\/KOH\uff1b\u82e5\u4e59\u82ef\u539f\u6599\u542b\u786b\u9187\u3001\u786b\u919a\u6216\u56fa\u614b\u786b\u904e\u591a\u6642\uff0c\u5247Fe2<\/sub>O3<\/sub>\u6703\u8207\u5176\u53cd\u61c9\u5f62\u6210Fe2<\/sub>S3<\/sub>\u3001FeS\u7b49\u800c\u88ab\u6bd2\u5316(poisoning)\u3002<\/p>\n

\u70ba\u4e86\u907f\u514d\u4e0a\u8ff0\u60c5\u5f62\u767c\u751f\uff0c\u79d1\u5b78\u5bb6\u7814\u7a76\u51fa\u4e00\u7cfb\u5217\u7684\u812b\u786b\u6280\u8853\uff0c\u5176\u4e2d\u767c\u5c55\u6700\u6210\u719f\u4e14\u5df2\u5de5\u696d\u5316\u61c9\u7528\u7684\u6709\u300c\u52a0\u6c2b\u812b\u786b\u6cd5\uff08hydro-desulfurization\uff0c\u7c21 \u7a31HDS\uff09\u300d\u8207\u300c\u6c27\u5316\u812b\u786b\u6cd5\uff08oxo-desulfurization\uff0c\u53c8\u7a31oxidation desulfurization\uff0c\u7c21\u7a31ODS\uff09\u300d\u5169\u7a2e\u3002\u52a0\u6c2b\u812b\u786b\u6cd5\u662f\u4ee5\u647b\u96dc\u5fae\u91cfCo\u3001Ni\u3001W\u91d1\u5c6c\u7684MoS2<\/sub>\u6216RuS2<\/sub>\u4f5c\u70ba\u50ac\u5316\u5291\uff0c\u4f7f\u786b\u9187\u8207\u786b\u919a\u5206\u5b50\u88ab\u5916\u52a0\u7684\u6c2b\u6c23\u9084\u539f\u6210\u70f7\u985e\u8207\u786b\u5316\u6c2b\uff0c\u53cd\u61c9\u7522\u751f\u51fa\u7684\u6c23\u9ad4\u518d\u901a\u904e\u6709\u6a5f\u80fa\uff0c\u4ee5\u4e2d\u548c\u7684\u65b9\u5f0f\u9664\u53bb\u786b\u5316\u6c2b\u3002\u6b64\u6cd5\u7684\u7f3a\u9ede\u5728\u65bc\u9700\u5916\u52a0\u5927\u91cf\u6c2b\u6c23\uff0c\u6210\u672c\u8f03\u9ad8\uff1b\u800c\u5de5\u696d\u754c\u6240\u4f7f\u7528\u7684\u6c2b\u6c23\u591a\u4ee5\u6c34\u84b8\u6c23\u91cd\u7d44\u6cd5(steam reforming)\u88fd\u5099\uff0c\u6545\u4f7f\u7528\u6b64\u6cd5\u6703\u4f34\u96a8\u8457\u5927\u91cfCO2<\/sub>\u7684\u7522\u751f\uff0c\u76f8\u7576\u4e0d\u74b0\u4fdd\u3002<\/p>\n

\"\"<\/a>

\u5716\u4e09\u3001\u52a0\u6c2b\u812b\u786b\u6cd5\u3002<\/p><\/div>\n

\u76f8\u8f03\u65bc\u52a0\u6c2b\u812b\u786b\u6cd5\uff0c\u6c27\u5316\u812b\u786b\u6cd5\u662f\u4ee5\u542bNi2+<\/sup>\u6216Cu2+<\/sup>\u7684TiO2<\/sub>\u6216\u662f\u542bAg\u7684SiO2<\/sub>\u4f5c\u70ba\u89f8\u5a92\uff0c\u4ee5\u5149\u50ac\u5316\u6216\u52a0\u71b1 (70~150\u2103) \u65b9\u5f0f\u4f7f\u786b\u919a\u5206\u5b50\u88ab\u7a7a\u6c23\u6c27\u5316\u6210\u78b8(sulfone,\"\"<\/a>)\uff0c\u4e4b\u5f8c\u518d\u52a0\u71b1\u4f7f\u5f97\u78b8\u65b7\u9375\u91cd\u6392\u5f62\u6210\u70f7\u985e\u8207\u4e8c\u6c27\u5316\u786b\uff0c\u53cd\u61c9\u7522\u751f\u51fa\u7684\u6c23\u9ad4\u518d\u901a\u904e\u751f\u77f3\u7070\uff0c\u4ee5\u4e2d\u548c\u5438\u9644\u7684\u65b9\u5f0f\u9664\u53bb\u4e8c\u6c27\u5316\u786b\u3002\u6b64\u65b9\u6cd5\u53ea\u9700\u5916\u52a0\u7a7a\u6c23\u800c\u975e\u6c2b\u6c23\uff0c\u5c31\u6210\u672c\u4e0a \u6bd4\u52a0\u6c2b\u812b\u786b\u6cd5\u4fbf\u5b9c\uff0c\u4f46\u7531\u65bc\u5728\u78b8\u65b7\u9375\u91cd\u6392\u4e00\u6b65\u9a5f\u4e2d\u6709\u5916\u52a0\u9ad8\u6eab(~500\u2103)\uff0c\u6703\u6709\u90e8\u5206\u70f7\u985e\u9032\u884c\u71b1\u88c2\u89e3(thermal cracking)\u800c\u5f62\u6210\u526f\u7522\u7269\u4e59\u70ef(ethylene, C2<\/sub>H4<\/sub>)\u7684\u7f3a\u9ede\u3002<\/p>\n

\"\"<\/a>

\u5716\u56db\u3001\u6c27\u5316\u812b\u786b\u6cd5\u3002<\/p><\/div>\n

\u53c3\u8003\u8cc7\u6599\uff1a<\/strong>
\n1. Zanniko, F.; Lois, E.; Stournas, S. Fuel Processing Technology 1995, 42, 35-45.
\n2. Yan, X. -M.; Su, G. -S.; Xiong, L. Journal of Fuel Chemistry and Technology 2009, 37, 318-323.
\n3. Duarte, F. A.; Bizzi, C. A.; Nunes, M. A. G.; Flores, E. M. M. Fuel 2011, 90, 2158\u20132164.
\n4. Deshpande, A.; Bassi, A.; Prakash, A. Energy and Fuels 2005, 19, 28-34.
\n5. Chianelli, R. R.; Berhault, G.; Raybaud, P.; Kasztelan, S.; Hafner, J.; Toulhoat, H. Applied Catalysis A 2002, 227, 83-96.
\n6. \u5716\u7247\u4f86\u6e90\uff1a\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u9673\u4f73\u7ff0\u3002<\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"

\u77f3\u6cb9\u7684\u812b\u786b\u5316(Desulfurization of Petroleum) \u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u5b78\u58eb\u751f\u9673\u4f73\u7ff0\/\u570b\u7acb…<\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[108,78,77,75,72],"tags":[1062,1394,4447],"class_list":["post-40799","post","type-post","status-publish","format-standard","hentry","category-chemistry00","category-chemistry08-01","category-chemistry08","category-chemistry06-03","category-chemistry06","tag-1062","tag-1394","tag-4447","avhec_catgroup-all","loop-entry","cat-108","cat-78","cat-77","cat-75","cat-72","no-thumbnail"],"views":12025,"_links":{"self":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/40799","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/comments?post=40799"}],"version-history":[{"count":1,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/40799\/revisions"}],"predecessor-version":[{"id":87782,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/40799\/revisions\/87782"}],"wp:attachment":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/media?parent=40799"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/categories?post=40799"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/tags?post=40799"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}