{"id":56194,"date":"2014-09-10T00:13:21","date_gmt":"2014-09-09T16:13:21","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=56194"},"modified":"2021-10-06T16:15:16","modified_gmt":"2021-10-06T08:15:16","slug":"%e5%93%88%e8%92%99%e5%be%b7%e5%81%87%e8%aa%aahammond-postulate","status":"publish","type":"post","link":"http:\/\/localhost\/%e5%93%88%e8%92%99%e5%be%b7%e5%81%87%e8%aa%aahammond-postulate\/","title":{"rendered":"\u54c8\u8499\u5fb7\u5047\u8aaa"},"content":{"rendered":"

\u54c8\u8499\u5fb7\u5047\u8aaa (Hammond Postulate)<\/strong><\/span>
\n\u570b\u7acb\u81fa\u7063\u5e2b\u7bc4\u5927\u5b78\u78a9\u58eb\u751f\u4e8c\u5e74\u7d1a\u9673\u57f9\u6770<\/strong><\/span><\/p>\n

\u4e00\u3001\u7c21\u4ecb<\/strong><\/p>\n

\u5728\u767c\u751f\u5316\u5b78\u53cd\u61c9\u6642\uff0c\u7531\u53cd\u61c9\u7269\u8f49\u8b8a\u70ba\u7522\u7269\u7684\u9014\u4e2d\u6703\u7d93\u904e\u4e00\u500b\u904e\u6e21\u72c0\u614b\uff0c\u70ba\u53cd\u61c9\u904e\u7a0b\u4e2d\u80fd\u91cf\u7684\u6700\u5927\u503c\u3002\u6240\u4ee5\u904e\u6e21\u72c0\u614b\u8b8a\u6210\u7522\u7269\u3001\u6216\u8005\u6cbf\u539f\u9014\u5f91\u8b8a\u56de\u53cd\u61c9\u7269\u4e0d\u9700\u8981\u984d\u5916\u589e\u52a0\u4efb\u4f55\u80fd\u91cf\u5c31\u53ef\u4ee5\u9054\u5230\uff0c\u800c\u4e14\u8f49\u8b8a\u904e\u7a0b\u6703\u91cb\u653e\u51fa\u80fd\u91cf\u3002\u54c8\u8499\u5fb7\u5047\u8aaa(Hammond Postulate)\u5247\u662f\u5229\u7528\u904e\u6e21\u614b\u8207\u53cd\u61c9\u7269\u548c\u7522\u7269\u7684\u80fd\u91cf\u95dc\u4fc2\u4f86\u63a8\u6e2c\u51fa\u8a72\u904e\u6e21\u614b\u7684\u72c0\u614b\u8207\u53cd\u61c9\u7269\u548c\u7522\u7269\u7684\u72c0\u614b\u4f55\u8005\u8f03\u76f8\u4f3c\u3002<\/p>\n

\u4e8c\u3001\u54c8\u8499\u5fb7\u5047\u8aaa(Hammond Postulate)<\/strong><\/p>\n

\u5728\u53cd\u61c9\u904e\u7a0b\u4e2d\uff0c\u904e\u6e21\u72c0\u614b\u77ac\u9593\u6d88\u5931\uff0c\u6c92\u6709\u4efb\u4f55\u7269\u7406\u6280\u8853\u53ef\u4ee5\u6e2c\u5f97\u904e\u6e21\u72c0\u614b\u3002<\/p>\n

\u800c\u5316\u5b78\u53cd\u61c9\u662f\u5206\u5b50\u9593\u767c\u751f\u5316\u5b78\u9375\u7684\u65b7\u88c2\u6216\u751f\u6210\u3002\u56e0\u6b64\u79d1\u5b78\u5bb6\u63a8\u8ad6\uff0c\u904e\u6e21\u72c0\u614b\u61c9\u8a72\u662f\u53cd\u61c9\u7269\u7684\u5316\u5b78\u9375\u767c\u751f\u4e86\u90e8\u5206\u65b7\u88c2\u4e26\u4e14\u90e8\u5206\u5f62\u6210\u65b0\u7684\u5316\u5b78\u9375\u64c1\u6709\u7522\u7269\u7684\u7279\u5fb5\uff0c\u70ba\u540c\u6642\u64c1\u6709\u90e8\u5206\u53cd\u61c9\u7269\u8207\u90e8\u5206\u7522\u7269\u7684\u4e2d\u9593\u72c0\u614b\u3002<\/p>\n

\u54c8\u8499\u5fb7\u5047\u8aaa<\/span>\uff1a\u5728\u5316\u5b78\u53cd\u61c9\u4e2d\uff0c\u904e\u6e21\u72c0\u614b\u6700\u50cf\u80fd\u91cf\u8ddf\u4ed6\u63a5\u8fd1\u7684\u7a69\u5b9a\u7269\u8cea\u3002<\/p>\n

\u65e2\u7136\u8aaa\u5230\u80fd\u91cf\uff0c\u6211\u5011\u77e5\u9053\u5316\u5b78\u53cd\u61c9\u5206\u70ba\u5438\u71b1\u53cd\u61c9\u8207\u653e\u71b1\u53cd\u61c9\u5169\u7a2e\u3002\u5176\u53cd\u61c9\u80fd\u91cf\u5716\u5982\u4e0b\u5716\uff1a<\/p>\n

\"fig1\"<\/a> \"fig2\"<\/a><\/p>\n

\u5716\u7247\u4f86\u6e90\uff1ahttp:\/\/blog.udn.com\/Gabriel33\/4672144<\/p>\n

\u4e5f\u5c31\u662f\u8aaa\uff0c\u54c8\u8499\u5fb7\u5047\u8aaa\u8a8d\u70ba\uff0c\u5728\u5438\u71b1\u53cd\u61c9\u6642\u904e\u6e21\u72c0\u614b\u8207\u7522\u7269\u80fd\u91cf\u8f03\u76f8\u8fd1\uff0c\u56e0\u6b64\u904e\u6e21\u72c0\u614b\u6bd4\u8f03\u50cf\u7522\u7269\u800c\u4e0d\u662f\u53cd\u61c9\u7269\uff0c\u800c\u5728\u653e\u71b1\u53cd\u61c9\u6642\uff0c\u904e\u6e21\u72c0\u614b\u80fd\u91cf\u8207\u53cd\u61c9\u7269\u8f03\u76f8\u8fd1\uff0c\u6703\u6bd4\u8f03\u50cf\u53cd\u61c9\u7269\u3002\u800c\u6211\u5011\u5c07\u6bd4\u8f03\u50cf\u53cd\u61c9\u7269\u7684\u904e\u6e21\u72c0\u614b\u7a31\u70ba\u300c\u65e9(early)\u904e\u6e21\u614b\u300d\uff0c\u800c\u628a\u6bd4\u8f03\u50cf\u7522\u7269\u7684\u7a31\u70ba\u300c\u665a (late)\u904e\u6e21\u614b\u300d\u3002<\/p>\n

\u6211\u5011\u8209\u500b\u4f8b\u5b50\u4f86\u8aaa\u660e\uff1a\u7576\u6211\u5011\u4ee5\u7532\u70f7\u70ba\u53cd\u61c9\u7269\u9032\u884c\u6c1f\u5316\u8207\u7898\u5316\u53cd\u61c9\u6642\uff0c\u5176\u901f\u7387\u6c7a\u5b9a\u6b65\u9a5f\u5206\u5225\u70ba\u653e\u71b1\u8207\u5438\u71b1\u53cd\u61c9\uff0c\u5176\u80fd\u91cf\u5716\u5982\u4e0b\uff1a<\/p>\n

\"fig3-1\"<\/a> \"fig3-2\"<\/a><\/p>\n

\u5716\u7247\u4f86\u6e90\uff1ahttp:\/\/www.chemgapedia.de\/<\/p>\n

\u6c1f\u5316\u53cd\u61c9\u70ba\u5438\u71b1\u53cd\u61c9\uff0c\u70ba\u300c\u65e9\u904e\u6e21\u72c0\u614b\u300d\uff0c\u56e0\u6b64\u5176\u904e\u6e21\u72c0\u614b\u70baH-F\u9375\u4e9b\u5fae\u751f\u6210\uff0cH-C\u9375\u4e9b\u5fae\u65b7\u88c2\uff0c\u8f03\u5177\u6709\u53cd\u61c9\u7269\u7279\u5fb5\u3002\u800c\u7898\u5316\u53cd\u61c9\u70ba\u5438\u71b1\u53cd\u61c9\uff0c\u70ba\u201d\u665a\u904e\u6e21\u72c0\u614b\u201d\uff0c\u56e0\u6b64\u904e\u6e21\u72c0\u614b\u70baH-I\u9375\u5927\u90e8\u5206\u751f\u6210\uff0cH-C\u9375\u5927\u90e8\u5206\u65b7\u88c2\uff0c\u8f03\u5177\u6709\u7522\u7269\u7279\u5fb5\u3002<\/p>\n

\u53e6\u5916\uff0c\u5316\u5b78\u53cd\u61c9\u70ba\u591a\u968e\u6bb5\u53cd\u61c9\uff0c\u5177\u6709\u4e2d\u9593\u7522\u7269\u6642\uff0c\u5176\u80fd\u91cf\u5716\u5982\u4e0b\uff1a<\/p>\n

\"fig4\"<\/a>

\u5716\u7247\u4f86\u6e90\uff1ahttp:\/\/blog.udn.com\/Gabriel33\/4672144<\/p><\/div>\n

\u4e0a\u5716\u70ba\u4e8c\u968e\u6bb5\u53cd\u61c9\uff0c\u53ef\u5206\u6210R\u2192I\u8207I\u2192P\u5169\u500b\u6b65\u9a5f\u3002\u524d\u534a\u90e8R\u2192I\u70ba\u5438\u71b1\u53cd\u61c9\uff0c\u904e\u6e21\u72c0\u614b\u8f03\u985e\u4f3c\u65bc\u7522\u7269(\u4e2d\u9593\u7522\u7269)\uff0c\u5f8c\u534a\u90e8I\u2192P\u70ba\u653e\u71b1\u53cd\u61c9\uff0c\u904e\u6e21\u72c0\u614b\u8f03\u985e\u4f3c\u65bc\u53cd\u61c9\u7269(\u4e2d\u9593\u7522\u7269)\u3002\u56e0\u6b64\uff0c\u5728\u591a\u968e\u6bb5\u7684\u5316\u5b78\u53cd\u61c9\u4e2d\uff0c\u300c\u4e2d\u9593\u7522\u7269\u300d\u6700\u80fd\u8aaa\u660eR\u2192P\u7684\u53cd\u61c9\u9014\u5f91\u3002\u7531\u65bc\u904e\u6e21\u72c0\u614b\u77ac\u9593\u6d88\u5931\u7121\u6cd5\u5229\u7528\u7269\u7406\u6280\u8853\u6e2c\u5f97\uff0c\u56e0\u6b64\u5728\u4e8c\u968e\u6bb5\u53cd\u61c9\u4e2d\uff0c\u82e5\u60f3\u8981\u4e00\u6b65\u6b65\u4e86\u89e3\u53cd\u61c9\u7684\u904e\u7a0b\uff0c\u6700\u57fa\u672c\u5730\u5fc5\u9808\u5148\u4e86\u89e3\u300c\u4e2d\u9593\u7522\u7269\u300d\uff0c\u56e0\u70ba\u9019\u5169\u500b\u904e\u6e21\u72c0\u614b\u4e0d\u985e\u4f3c\u53cd\u61c9\u7269\u4e5f\u4e0d\u985e\u4f3c\u7522\u7269\uff0c\u800c\u662f\u300c\u4e2d\u9593\u7522\u7269\u300d\u3002<\/p>\n

\n

\u53c3\u8003\u8cc7\u6599<\/strong><\/p>\n

    \n
  1. L.G. Wade, JR. <<Organic Chemistry>>, 7th<\/sup> edition, p.151.<\/li>\n
  2. \u54c8\u8499\u5fb7\u5047\u8aaahttp:\/\/en.wikipedia.org\/wiki\/Hammond’s_postulate<\/a><\/li>\n<\/ol>\n<\/div>","protected":false},"excerpt":{"rendered":"

    \u54c8\u8499\u5fb7\u5047\u8aaa (Hammond Postulate) \u570b\u7acb\u81fa\u7063\u5e2b\u7bc4\u5927\u5b78\u78a9\u58eb\u751f\u4e8c\u5e74\u7d1a\u9673\u57f9\u6770 \u4e00\u3001\u7c21\u4ecb \u5728\u767c\u751f\u5316\u5b78\u53cd…<\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[108,63,62],"tags":[7819,7820,4450,7053],"class_list":["post-56194","post","type-post","status-publish","format-standard","hentry","category-chemistry00","category-chemistry04-01","category-chemistry04","tag-hammond-postulate","tag-7820","tag-4450","tag-7053","loop-entry","cat-108","cat-63","cat-62","no-thumbnail"],"views":13322,"_links":{"self":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/56194","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/comments?post=56194"}],"version-history":[{"count":1,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/56194\/revisions"}],"predecessor-version":[{"id":86895,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/56194\/revisions\/86895"}],"wp:attachment":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/media?parent=56194"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/categories?post=56194"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/tags?post=56194"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}