{"id":5091,"date":"2009-07-27T05:36:59","date_gmt":"2009-07-26T21:36:59","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=5091"},"modified":"2021-10-06T16:48:43","modified_gmt":"2021-10-06T08:48:43","slug":"%e9%8b%b0%e9%9b%bb%e6%b1%a0%ef%bc%88lithium-battery%ef%bc%89","status":"publish","type":"post","link":"http:\/\/localhost\/%e9%8b%b0%e9%9b%bb%e6%b1%a0%ef%bc%88lithium-battery%ef%bc%89\/","title":{"rendered":"\u92f0\u96fb\u6c60\uff08Lithium Battery\uff09"},"content":{"rendered":"

\u92f0\u96fb\u6c60\uff08Lithium Battery\uff09<\/span>
\n\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u9ec3\u4fca\u8aa0\u535a\u58eb\/\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u9673\u85f9\u7136\u535a\u58eb\u8cac\u4efb\u7de8\u8f2f<\/span><\/strong><\/p>\n

\u92f0\u96fb\u6c60\u7684\u7814\u7a76\u6700\u65e9\u662f\u57281912\u5e74\u7531Gilbert Newton Lewis\u958b\u59cb\u9032\u884c\u92f0\u96e2\u5b50\u96fb\u6c60\u4e4b\u7814\u7a76\uff0c\u771f\u6b63\u4e0a\u5e02\u7684\u7b2c\u4e00\u9846\u92f0\u96fb\u6c60\u662f\u57281970\u5e74\u4e0a\u5e02\uff0c\u4f46\u662f\u5b83\u4e0d\u80fd\u91cd\u8907\u5145\u96fb\u4f7f\u7528\uff0c\u70ba\u4e00\u6b21\u6027\u92f0\u96fb\u6c60\u3002\u4e00\u6b21\u6027\u92f0\u96fb\u6c60\u4ee5\u91d1\u5c6c\u92f0\u70ba\u967d\u6975\uff0c\u7898\u70ba\u9670\u6975\uff0c\u7898\u5316\u92f0\u70ba\u96fb\u89e3\u8cea\u3002\u92f0\u96fb\u6c60\u65e9\u671f\u7528\u65bc\u5fc3\u5f8b\u8abf\u6574\u5668\uff0c\u53ef\u7dad\u6301\u5341\u5e7e\u5e74\u7684\u58fd\u547d\u3002\u5176\u53cd\u61c9\u65b9\u7a0b\u5f0f\u5982\u4e0b\uff1a
\n\u967d\u6975\u53cd\u61c9\uff1a2Li(s<\/em>)<\/sub> + 2I–<\/sup>(aq<\/em>)\u00a0<\/sub>\u2192 2LiI(s<\/em>)<\/sub> + 2e–<\/sup>
\n\u9670\u6975\u53cd\u61c9\uff1aI2(l) + 2e–\u00a0<\/sup>\u2192 2I–<\/sup>(s)
\n\u7e3d\u53cd\u61c9\uff1a2Li(s<\/em>)<\/sub> + I2(l<\/em>)\u00a0<\/sub>\u2192 2LiI(s<\/em>)<\/sub>\u00a0\u00a0\u00a0\u00a0 \u7e3d\u96fb\u4f4d = 3.0 \u4f0f\u7279<\/p>\n

\u53ef\u91cd\u8907\u4f7f\u7528\u92f0\u96fb\u6c60\u7684\u958b\u767c\u662f\u81ea1980\u5e74\u82f1\u570b\u8c37\u767b\u62ff\uff08John B. Goodenough, \uff09\u6559\u6388\u767c\u8868\u92f0\u9237\u96fb\u6975\u6750\u6599\u7684\u8ad6\u6587\u958b\u59cb\uff0c1991\u5e74\u65e5\u672cSony\u516c\u53f8\u6b63\u5f0f\u63a8\u51fa\u92f0\u96e2\u5b50\u4e8c\u6b21\u96fb\u6c60\u5546\u54c1\u3002\u4e8c\u6b21\u92f0\u96fb\u6c60\u7279\u9ede\u70ba\u80fd\u91cf\u5bc6\u5ea6\u9ad8\u3001\u64cd\u4f5c\u96fb\u58d3\u9ad8\u3001\u8f38\u51fa\u529f\u7387\u5927\u3001\u653e\u96fb\u5e73\u7a69\u3001\u5de5\u4f5c\u6eab\u5ea6\u5340\u9593\u5927\u3001\u5145\u653e\u96fb\u5faa\u74b0\u53ef\u9054500\u6b21\u4ee5\u4e0a\u3001\u81ea\u653e\u96fb\u4f4e\u3001\u5132\u5b58\u58fd\u547d\u9577\uff0c\u88ab\u8996\u70ba\u76ee\u524d\u6700\u4e3b\u8981\u7684\u4e8c\u6b21\u96fb\u6c60\u3002<\/p>\n

\u92f0\u96fb\u6c60\u4f9d\u5176\u9694\u96e2\u5c64\u7cfb\u7d71\u7684\u4e0d\u540c\uff0c\u53c8\u5340\u5206\u70ba\u92f0\u96e2\u5b50\u96fb\u6c60\u8207\u92f0\u9ad8\u5206\u5b50\u4e8c\u6b21\u96fb\u6c60\uff0c\u5169\u8005\u5747\u4ee5\u78b3\u6750(\u5982\u77f3\u58a8)\u70ba\u967d\u6975\uff0c\u914d\u5408\u92f0\u9237\u6c27\u5316\u7269\uff08LiCoO2<\/sub>\uff09\u3001\u92f0\u9333\u6c27\u5316\u7269\uff08LiMn2<\/sub>O4<\/sub>\uff09\u6216\u92f0\u93b3\u6c27\u5316\u7269\uff08LiNiO2<\/sub>\uff09\u7b49\u9670\u6975\u6d3b\u6027\u7269\u8cea\u3002\u96fb\u6c60\u653e\u96fb\u53cd\u61c9\u5f0f\u5982\u4e0b\uff1a
\n\u967d\u6975\u53cd\u61c9\uff1a Lix<\/sub><\/em>C6(s<\/em>)\u00a0<\/sub>\u2192 \u00a0x<\/em> Li+<\/sup>(os<\/em>)<\/sub> + C6(s<\/em>)<\/sub> + x<\/em> e–<\/sup>
\n\u9670\u6975\u53cd\u61c9\uff1a Li1-x<\/sub><\/em>CoO2(s<\/em>)<\/sub> + x<\/em> Li(os<\/em>)<\/sub> + x<\/em> e\uff0d<\/sup>\u2192 LiCoO2(s<\/em>)<\/sub>
\n\u7e3d\u53cd\u61c9\uff1a Lix<\/sub><\/em>C6(s<\/em>)<\/sub> + Li1-x<\/sub><\/em>CoO2(s<\/em>)<\/sub> \u2192C6(s<\/em>)<\/sub> + LiCoO2(s<\/em>)<\/sub>
\n\u8a3b\uff1aLix<\/sub><\/em>C6(s<\/em>)<\/sub>\u70ba\u92f0\u8207\u77f3\u58a8\u6df7\u5408\uff0c\u88fd\u6210\u7279\u6b8a\u6750\u8cea\u7684\u96fb\u6975\uff0cC6(s<\/em>)<\/sub>\u70ba\u77f3\u58a8\u00a0\u3002<\/span><\/p>\n

 <\/p>\n

\u4e00\u822c\u7684\u92f0\u96e2\u5b50\u96fb\u6c60\u662f\u7528\u92f0\u9e7d\u6709\u6a5f\u6eb6\u6db2\u4f86\u7576\u96fb\u89e3\u8cea\u3002\u4f8b\u5982LiPF6<\/sub>\u3001Li[N(CF3<\/sub>SO2<\/sub>)2<\/sub>]\u3002\u800c\u9ad8\u5206\u5b50\u92f0\u96fb\u6c60\u662f\u57fa\u65bc\u92f0\u96e2\u5b50\u96fb\u6c60\u800c\u4f86\u7684\uff0c\u539f\u7406\u90e8\u5206\u5927\u81f4\u76f8\u540c\uff0c\u50c5\u65bc\u90e8\u5206\u6750\u6599\u6709\u6240\u5340\u5225\uff0c\u5169\u8005\u6700\u5927\u7684\u4e0d\u540c\u5c31\u662f\u4ee5\u9ad8\u5206\u5b50\u53d6\u4ee3\u539f\u6709\u96fb\u6975\uff0c\u6216\u662f\u5229\u7528\u9ad8\u5206\u5b50\u96fb\u89e3\u8cea\u53d6\u4ee3\u92f0\u96e2\u5b50\u96fb\u6c60\u4e2d\u7684\u6709\u6a5f\u6eb6\u6db2\u3002\u9ad8\u5206\u5b50\u5728\u96fb\u6975\u7684\u61c9\u7528\u591a\u7528\u65bc\u9670\u6975\u6750\u6599\u4e0a\uff0c\u9ad8\u5206\u5b50\u967d\u6975\u6750\u6599\u8f03\u70ba\u5c11\u898b\u3002\u5e38\u898b\u4f5c\u70ba\u9670\u6975\u7684\u4e09\u7a2e\u4e3b\u8981\u9ad8\u5206\u5b50\u6750\u6599\u5305\u62ec\u6709\u6a5f\u786b\u805a\u5408\u7269\uff08Organosulfur\u3001Organosulfide Polymer\uff09\u3001\u805a\u82ef\u80fa\uff08Polyanaline\uff09\u4ee5\u53ca\u805a\u4ef3\u54af\uff08Polypyrrole\uff09\u3002\u9ad8\u5206\u5b50\u96fb\u89e3\u8cea\u662f\u628a\u9e7d\u985e\u6eb6\u5728\u9ad8\u5206\u5b50\u4e2d\u800c\u5f62\u6210\uff0c\u9ad8\u5206\u5b50\u7684\u5c0e\u96fb\u4f86\u81ea\u65bc\u9ad8\u5206\u5b50\u5167\u96e2\u5b50\u7684\u79fb\u52d5\uff0c\u800c\u96e2\u5b50\u7684\u79fb\u52d5\u540c\u6642\u4f34\u96a8\u9ad8\u5206\u5b50\u7684\u79fb\u52d5\u3002\u76ee\u524d\u767c\u5c55\u4e2d\u7684\u9ad8\u5206\u5b50\u96fb\u89e3\u8cea\u5927\u7565\u53ef\u5206\u70ba\u56db\u7a2e\uff1aPEO\uff08Polyethylene Oxide\uff09\u7cfb\u3001Polyacrylate\u7cfb\u3001PAN\uff08Polyacrylonitrile\uff09\u7cfb\u4ee5\u53caPVDF\uff08Poly(vinylidene fluoride)\uff09\uff0fHFP\u7cfb\u3002\u5176\u4e2d\u9664\u4e86PEO\u7cfb\u70ba\u56fa\u614b\u96fb\u89e3\u8cea\u5916\uff0c\u5176\u9918\u4e09\u8005\u7686\u5c6c\u65bc\u81a0\u614b\u96fb\u89e3\u8cea\u3002\u9ad8\u5206\u5b50\u92f0\u96fb\u6c60\u76f8\u5c0d\u65bc\u92f0\u96e2\u5b50\u96fb\u6c60\u7684\u512a\u9ede\u70ba\uff1a
\n1. \u53ef\u8584\u578b\u5316\u6216\u4efb\u610f\u5f62\u72c0\u3002
\n2. \u53ef\u4e26\u806f\u6216\u4e32\u806f\u4ee5\u63d0\u9ad8\u96fb\u91cf\u6216\u96fb\u58d3\u3002
\n3. \u5927\u65bc1000\u7684\u5faa\u74b0\u58fd\u547d\u3002
\n4. \u53ef\u8010100\u00b0C\u7684\u9ad8\u6eab\uff0c\u96fb\u89e3\u6db2\u4e0d\u6703\u84b8\u767c\u3002
\n5. \u4e0d\u9700\u8981\u6602\u8cb4\u7684\u9694\u96e2\u6a21\u53ef\u50f9\u4f4e\u6210\u672c\u3002<\/p>\n

\u92f0\u96fb\u6c60\u7684\u5be6\u7528\u5316\uff0c\u4f7f\u4eba\u5011\u7684\u884c\u52d5\u96fb\u8a71\u3001\u7b46\u8a18\u672c\u96fb\u8166\u7b49\u651c\u5e36\u578b\u96fb\u5b50\u8a2d\u5099\u91cd\u91cf\u548c\u9ad4\u7a4d\u6025\u907d\u7e2e\u5c0f\uff0c\u4e14\u4f7f\u7528\u6642\u9593\u5927\u5e45\u5ef6\u9577\u3002\u7531\u65bc\u92f0\u96e2\u5b50\u96fb\u6c60\u4e2d\u4e0d\u542b\u6709\u91cd\u91d1\u5c6c\u9398\uff0c\u8207\u93b3\u9398\u96fb\u6c60\u76f8\u6bd4\uff0c\u5927\u5927\u6e1b\u5c11\u4e86\u5c0d\u74b0\u5883\u7684\u6c61\u67d3\u3002<\/p>\n

\u53c3\u8003\u8cc7\u6599\uff1a
\n1. http:\/\/en.wikipedia.org\/wiki\/Lithium_battery<\/a>
\n2. http:\/\/www.vr2xxt.com\/vr2xxt\/doc\/Diy\/Lion-Basic.htm<\/a>
\n3. http:\/\/tw.knowledge.yahoo.com\/question\/ \u2026 5102707065<\/a>
\n4. http:\/\/www.chemedu.ch.ntu.edu.tw\/lecture\/battery\/li.htm<\/a><\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"

\u92f0\u96fb\u6c60\uff08Lithium Battery\uff09 \u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u9ec3\u4fca\u8aa0\u535a\u58eb\/\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u9673\u85f9\u7136\u535a\u58eb\u8cac\u4efb\u7de8\u8f2f …<\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[108,74,72],"tags":[1145,1004],"class_list":["post-5091","post","type-post","status-publish","format-standard","hentry","category-chemistry00","category-chemistry06-04","category-chemistry06","tag-1145","tag-1004","loop-entry","cat-108","cat-74","cat-72","no-thumbnail"],"views":28571,"_links":{"self":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/5091","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/comments?post=5091"}],"version-history":[{"count":1,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/5091\/revisions"}],"predecessor-version":[{"id":90801,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/5091\/revisions\/90801"}],"wp:attachment":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/media?parent=5091"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/categories?post=5091"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/tags?post=5091"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}