{"id":4634,"date":"2009-07-25T14:07:30","date_gmt":"2009-07-25T06:07:30","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=4634"},"modified":"2021-10-06T16:48:44","modified_gmt":"2021-10-06T08:48:44","slug":"%e5%af%8c%e5%8b%92%e7%83%af%ef%bc%88fullerene%ef%bc%89","status":"publish","type":"post","link":"http:\/\/localhost\/%e5%af%8c%e5%8b%92%e7%83%af%ef%bc%88fullerene%ef%bc%89\/","title":{"rendered":"\u5bcc\u52d2\u70ef"},"content":{"rendered":"<div class=\"pf-content\"><p><strong><span style=\"color: #ff6600;\">\u5bcc\u52d2\u70ef (Fullerene)<\/span><br \/>\n<span style=\"color: #008000;\">\u570b\u7acb\u65b0\u838a\u9ad8\u7d1a\u4e2d\u5b78\u5316\u5b78\u79d1\u9673\u5049\u6c11\u6559\u5e2b\/\u570b\u7acb\u81fa\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u8449\u540d\u5009\u6559\u6388\u8cac\u4efb\u7de8\u8f2f<\/span><\/strong><\/p>\n<p>\u5bcc\u52d2\u70ef\u662f\u78b3\u540c\u7d20\u7570\u5f62\u9ad4\u4e2d\u7684\u4e00\u985e\uff0c\u5206\u5b50\u5b8c\u5168\u7531\u78b3\u7d44\u6210\uff0c\u5206\u5b50\u5f62\u72c0\u53ef\u80fd\u70ba\u4e2d\u7a7a\u7684\u7403\u5f62\u3001\u6a62\u9762\u3001\u7ba1\u72c0\u6216\u5e73\u9762\u3002\u7403\u72c0\u7684\u5bcc\u52d2\u70ef\u53c8\u7a31\u70ba\u5df4\u514b\u7403\uff0c\u800c\u7ba1\u72c0\u7684\u5247\u7a31\u70ba\u5948\u7c73\u78b3\u7ba1\u6216\u5df4\u514b\u7ba1\u3002\u77f3\u58a8\u70ef\u5c31\u662f\u5e73\u9762\u5bcc\u52d2\u70ef\u8584\u7247\u7684\u5be6\u4f8b\u4e4b\u4e00\u3002\u77f3\u58a8\u662f\u7531\u8a31\u591a\u516d\u89d2\u74b0\u9023\u6210\u7684\u8584\u7247\u5806\u758a\u800c\u6210\uff0c\u5bcc\u52d2\u70ef\u7684\u7d50\u69cb\u975e\u5e38\u50cf\u77f3\u58a8\uff0c\u4f46\u5176\u4e2d\u53ef\u80fd\u542b\u6709\u4e94\u89d2\u74b0\uff08\u6709\u6642\u5019\u542b\u4e03\u89d2\u74b0\uff09\uff0c\u9019\u6a23\u5c31\u4e0d\u4e00\u5b9a\u6703\u5448\u5e73\u9762\u5f62\u3002<\/p>\n<p>\u5bcc\u52d2\u70ef\u662f1985\u5e74\u7531\u8607\u8b1d\u514b\u65af\u5927\u5b78 (University of Sussex) \u53ca\u840a\u65af\u5927\u5b78 (University of Rice)\u7684\u67ef\u723e (Robert Curl)\u3001\u514b\u7f85\u6258(Harold Kroto)\u548c\u65af\u83ab\u5229 (Richard Smalley)\u4e09\u4f4d\u5b78\u8005\u767c\u73fe\uff0c\u56e0\u70ba\u4ed6\u5011\u6240\u767c\u73fe\u7684\u5206\u5b50\u5f62\u72c0\u985e\u4ee5\u5efa\u7bc9\u5e2b\u7406\u67e5\u2027\u5df4\u514b\u660e\u65af\u7279\u2027\u5bcc\u52d2(Richard Buckminster Fuller)\u6240\u5efa\u9020\u7684\u4e00\u5ea7\u62f1\u9802\u5c55\u89bd\u9928\uff0c\u56e0\u6b64\u4ee5\u5efa\u7bc9\u5e2b\u7684\u540d\u5b57\u70ba\u5206\u5b50\u547d\u540d\u3002<\/p>\n<p><strong>\u9810\u8a00\u8207\u767c\u73fe<\/strong><\/p>\n<p>\u57281970\u5e74\uff0c\u8c50\u6a4b\u79d1\u6280\u5927\u5b78\u7684\u5927\u6fa4\u6620\u5152\u5c31\u5728\u65e5\u672c\u96dc\u8a8c\u4e0a\u9810\u8a00C<sub>60<\/sub>\u7684\u5b58\u5728\u3002\u4ed6\u6ce8\u610f\u5230corannulene\uff08\u4e00\u7a2e\u591a\u74b0\u82b3\u9999\u70f4\uff0c\u5206\u5b50\u5f0f\u70baC<sub>20<\/sub>H<sub>10<\/sub>\uff09\u662f\u8db3\u7403\u5f62\u7684\u4e00\u90e8\u5206\uff0c\u56e0\u6b64\uff0c\u4ed6\u63d0\u51fa\u5047\u8aaa\uff0c\u8a8d\u70ba\u5b8c\u6574\u8db3\u7403\u5f62\u7684\u5206\u5b50\u4e5f\u53ef\u80fd\u5b58\u5728\u3002\u4ed6\u7684\u89c0\u9ede\u767c\u8868\u5728\u65e5\u672c\u96dc\u8a8c\u4e0a\uff0c\u4f46\u6b50\u6d32\u4eba\u548c\u7f8e\u570b\u4eba\u4e26\u4e0d\u77e5\u6089\u3002<\/p>\n<p>1985\u5e74\u514b\u7f85\u6258\uff08\u7576\u6642\u5728\u8607\u8b1d\u514b\u65af\u5927\u5b78\uff09\uff0c\u4ee5\u53ca\u840a\u65af\u5927\u5b78\u7684\u595a\u65af\uff08James R. Heath\uff09\u3001\u6b50\u5e03\u4f86\u6069\uff08Sean O\u2019Brien\uff09\u3001\u67ef\u723e\u53ca\u65af\u83ab\u5229\u5728\u7814\u7a76\u67d0\u4e9b\u542b\u78b3\u5206\u5b50\u6642\uff0c\u7531\u8cea\u8b5c\u5100\u6e2c\u5f97\u7684\u8a0a\u865f\u986f\u793a\u5206\u5b50\u5177\u6709\u516d\u5341\u6216\u4e03\u5341\u6216\u66f4\u591a\u7684\u78b3\u539f\u5b50\uff0c\u56e0\u800c\u767c\u73feC<sub>60<\/sub>\uff08\u5982\u4e0b\u5716\uff09\u3002\u904e\u4e0d\u4e45\uff0c\u4ed6\u5011\u53c8\u767c\u73fe\u5176\u4ed6\u5bcc\u52d2\u70ef\u3002\u514b\u7f85\u6258\u3001\u67ef\u723e\u548c\u65af\u83ab\u5229\u56e0\u70ba\u767c\u73fe\u6b64\u985e\u5206\u5b50\u800c\u7372\u5f971996\u5e74\u8afe\u8c9d\u723e\u5316\u5b78\u596c\u3002\u5f8c\u4f86\u767c\u73fe\u5728\u5be6\u9a57\u5ba4\u4e4b\u5916\u4e5f\u6709C60\u548c\u5176\u4ed6\u5bcc\u52d2\u70ef\u5b58\u5728\uff08\u4f8b\u5982\u666e\u901a\u881f\u71ed\u71c3\u71d2\u5f8c\u7684\u6cb9\u7159\uff09\u3002\u5230\u4e861991\u5e74\uff0c\u904b\u7528\u54c8\u592b\u66fc\uff08Donald Huffman\uff09\u548c\u67ef\u62c9\u5e0c\u9ed8\uff08Wolfgang Kr\u00e4tschmer\uff09\u7684\u65b9\u6cd5\uff0c\u53ef\u4ee5\u8f15\u6613\u88fd\u51fa\u7da0\u8c46\u5927\u5c0f\u7684\u5bcc\u52d2\u70ef\u7c89\u672b\u3002\u5982\u4f55\u7d14\u5316\u5bcc\u52d2\u70ef\u4e00\u76f4\u662f\u5316\u5b78\u5bb6\u7684\u6311\u6230\uff0c\u800c\u4e14\u4e5f\u5f71\u97ff\u5bcc\u52d2\u70ef\u7684\u50f9\u683c\u3002\u6240\u8b02\u5bcc\u52d2\u70ef\u5305\u5408\u7269\uff08endohedral fullerenes\uff09\u662f\u6307\u5bcc\u52d2\u70ef\u5f62\u6210\u7684\u7c60\u72c0\u5206\u5b50\u4e2d\u542b\u6709\u96e2\u5b50\u6216\u5c0f\u5206\u5b50\u3002\u5728\u8a31\u591a\u6709\u6a5f\u5316\u5b78\u53cd\u61c9\u4e2d\uff0c\u59821993\u5e74\u767c\u73fe\u7684\u8cd3\u683c\u53cd\u61c9\uff08Bingel reaction\uff09\uff0c\u5bcc\u52d2\u70ef\u662f\u7279\u6b8a\u7684\u53cd\u61c9\u7269\u3002\u7b2c\u4e00\u500b\u5948\u7c73\u78b3\u7ba1\u57281991\u5e74\u88fd\u6210\u3002<\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/07\/Fullerene_2.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-8794\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/07\/Fullerene_2.png\" alt=\"\" width=\"360\" height=\"352\" 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\u5bcc&hellip;<\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[108,50,48],"tags":[2455,2563],"class_list":["post-4634","post","type-post","status-publish","format-standard","hentry","category-chemistry00","category-chemistry01-02","category-chemistry01","tag-2455","tag-2563","loop-entry","cat-108","cat-50","cat-48","no-thumbnail"],"views":10001,"_links":{"self":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4634","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/comments?post=4634"}],"version-history":[{"count":1,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4634\/revisions"}],"predecessor-version":[{"id":90804,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4634\/revisions\/90804"}],"wp:attachment":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/media?parent=4634"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/categories?post=4634"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/tags?post=4634"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}