{"id":45779,"date":"2013-10-18T00:57:58","date_gmt":"2013-10-17T16:57:58","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=45779"},"modified":"2021-10-06T16:20:02","modified_gmt":"2021-10-06T08:20:02","slug":"%e6%b0%af%e5%8c%96%e9%8b%85zinc-chloride","status":"publish","type":"post","link":"http:\/\/localhost\/%e6%b0%af%e5%8c%96%e9%8b%85zinc-chloride\/","title":{"rendered":"\u6c2f\u5316\u92c5(Zinc Chloride)"},"content":{"rendered":"

\u6c2f\u5316\u92c5(Zinc Chloride)<\/span>
\n\u570b\u7acb\u81fa\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u78a9\u58eb\u73ed\u4e8c\u5e74\u7d1a\u6c5f\u5b5f\u6f54<\/span><\/strong><\/strong><\/p>\n

\u6c2f\u5316\u92c5\u7684\u6027\u8cea<\/strong><\/span><\/p>\n

\u5916\u89c0\u7121\u8272\u6216\u767d\u8272\u6676\u9ad4\uff0c\u6cb8\u9ede $$756^\\circ C$$ $$(1029~K)$$\uff0c\u7194\u9ede $$275^\\circ C$$ $$(548~K)$$\uff0c\u5bc6\u5ea6 $$2.907~g\/cm^3$$\uff0c\u6613\u6eb6\u65bc\u6c34\uff0c\u6eb6\u65bc\u7532\u9187\u3001\u4e59\u9187\u3001\u7518\u6cb9\u3001\u4e19\u916e\u3001\u4e59\u919a\uff0c\u4e0d\u6eb6\u65bc\u6c28\u6c34\u3002\u7121\u6c34\u7684\u6c2f\u5316\u92c5\u53d7\u5230\u7a7a\u6c23\u4e2d\u7684\u6fd5\u6c23\u6f6e\u89e3\u5f62\u6210\u9e7d\u9178\uff0c\u540c\u6642\u4e5f\u6703\u8207\u6c34\u3001\u6c28\u548c\u5176\u4ed6\u6709\u6a5f\u6eb6\u5291\u5f62\u6210\u8907\u5408\u7269\u96e2\u5b50\uff0c\u9e7c\u6027\u7269\u8cea\u5728\u6c2f\u5316\u92c5\u6eb6\u6db2\u4e2d\u7522\u751f\u6c89\u6fb1\u6c2b\u6c27\u5316\u92c5\u3002\u6c2f\u5316\u92c5\u7684\u6027\u8cea\u70ba\u8def\u6613\u58eb\u9178\u56e0\u6b64\u4e5f\u5177\u6709\u89aa\u96fb\u6027\u8cea\u30021-2<\/sup><\/p>\n

\"p1\"<\/a><\/p>\n

<\/p>\n

\u88fd\u5099<\/strong><\/span><\/p>\n

(1) \u00a0\u5229\u7528\u92c5\u548c\u6c2f\u5316\u6c2b\u53cd\u61c9\uff0c\u5f62\u6210\u7121\u6c34\u6c2f\u5316\u92c5<\/p>\n

\"e1\"<\/a><\/p>\n

(2) \u00a0\u6fc3\u9e7d\u9178\u548c\u92c5(\u4e5f\u53ef\u4ee5\u4f7f\u7528\u6c27\u5316\u92c5<\/a>\u6216\u786b\u5316\u92c5<\/a>)\u53cd\u61c9\uff0c\u53ef\u5f62\u6210\u6c34\u5408\u7684\u6c2f\u5316\u92c5<\/p>\n

\"e2\"<\/a><\/p>\n

\u7528\u9014\u53ca\u61c9\u7528<\/strong><\/span><\/p>\n

\u5728\u710a\u63a5\u9435\u76ae\uff0c\u7528\u6c2f\u5316\u92c5\u6eb6\u6db2\u6e05\u9664\u91d1\u5c6c\u8868\u9762\u7684\u6c27\u5316\u7269\uff0c$$\\bf{H[ZnCl_2(OH)]}$$ \u6709\u986f\u8457\u9178\u6027\u80fd\u6e05\u9664\u91d1\u5c6c\u8868\u9762\u4e0d\u640d\u5bb3\u91d1\u5c6c\u8868\u9762\u3002<\/p>\n

\"e3\"<\/a><\/p>\n

\u76e7\u5361\u65af\u8a66\u5291\uff08Lucas reagent\uff09\u662f\u7121\u6c34\u6c2f\u5316\u92c5\u6eb6\u65bc\u9ad8\u6fc3\u5ea6\u9e7d\u9178\u6240\u914d\u88fd\u6210\u7684\u4e00\u7a2e\u6eb6\u6db2\u3002\u9019\u7a2e\u6eb6\u6db2\u88ab\u7528\u65bc\u9451\u5225\u4f4e\u5206\u5b50\u91cf\u7684\u9187\uff0c\u53cd\u61c9\u4e2d\u6c2f\u6703\u53d6\u4ee3\u77ed\u93c8\u9187\u4e2d\u7684\u7fa5\u57fa\uff0c\u751f\u6210\u4e0d\u6eb6\u65bc\u6c34\u7684\u6c2f\u4ee3\u70f7\uff0c\u5448\u73fe\u6c89\u6fb1\uff0c\u901a\u904e\u53cd\u61c9\u7684\u5feb\u6162\u5224\u65b7\u9187\u7684\u7d50\u69cb\u30023<\/sup><\/p>\n

ROH + HCl \u2192 RCl + H2<\/sub>O<\/span><\/p>\n

\"p2\"<\/a>

(\u5716\u53d6\u81eaPushpananda A. Senaratne, Organic Process Research & Development ,2003, 7, 185)<\/p><\/div>\n

\u5229\u7528\u6c2f\u5316\u92c5\u70ba\u8def\u6613\u58eb\u9178\u5728\u5ba4\u6eab\u4e0b\u4ee5\u4e8c\u6c2f\u7532\u70f7\u70ba\u6eb6\u6db2\uff0c\u900f\u904e\u916e\u57fa\u5c0d\u7094\u57fa\u9032\u884c5-Endo-dig\u7684\u5408\u74b0\u53cd\u61c9\u3002\u53ef\u4ee5\u9ad8\u7522\u7387\u7684\u5f97\u5230\u544b\u5583\uff08furan\uff09\u4e09\u53d6\u4ee3\u884d\u751f\u7269\uff0c\u4e26\u4e14\u5177\u6709\u826f\u597d\u7684\u4f4d\u7f6e\u9078\u64c7\u6027\u30024<\/sup><\/p>\n

\"p3\"<\/a>

(\u5716\u53d6\u81eaRoman Dembinski, Org. Lett., 2007, 9, 1175-1178)<\/p><\/div>\n

\u57281871\u5e74\u963f\u9053\u592b\u00b7\u99ae\u00b7\u8c9d\u8036\u723e(Adolf von Baeyer)\u9996\u6b21\u5408\u6210\u7192\u5149\u9ec3\uff0c\u53ef\u4ee5\u5f9e\u9130\u82ef\u4e8c\u7532\u9178\u9150\uff0c\u9593\u82ef\u4e8c\u915a<\/a>\u5728\u6c2f\u5316\u92c5\u7684\u5b58\u5728\u4e0b\uff0c\u901a\u904e\u592b[\u91cc\u5fb7\u8033]-\u5938[\u592b\u7279]\u53cd\u61c9\uff08Friedel-Crafts\uff09\u53cd\u61c9\u4f86\u88fd\u5099\u30021<\/sup><\/p>\n

\"p4\"<\/a>

(http:\/\/upload.wikimedia.org\/wikipedia\/commons\/thumb\/5\/5a\/ZnCl2_fluorescein.png\/480px-ZnCl2_fluorescein.png)<\/p><\/div>\n

\u53ef\u5229\u7528\u96fb\u89e3\u6c2f\u5316\u92c5\uff0c\u5f97\u5230\u92c5\u91d1\u5c6c\u548c\u6c2f\u6c23\u3002<\/p>\n

\"p5\"<\/a><\/p>\n

\"e5\"<\/a><\/p>\n

\u5473\u9053\u63a7\u5236\u53ef\u4ee5\u7528\u6c2f\u5316\u92c5\u548c\u786b\u5316\u7269\u9032\u884c\u53cd\u61c9\uff0c\u964d\u4f4e\u786b\u5316\u6c2b\u6c23\u9ad4\u5728\u5ee2\u6c34\u8655\u7406\u8a2d\u5099\u4e2d\u7684\u91cb\u653e\u3002\u4e7e\u96fb\u6c60\u4e2d\u7684\u6c2f\u5316\u92c5\u7576\u4f5c\u6c2f\u5316\u92a8\u96fb\u89e3\u6db2\u4e2d\u7684\u5438\u6fd5\u5291\uff0c\u4f5c\u70ba\u8150\u8755\u92c5\u5916\u6bbc\u7684\u963b\u71c3\u5291\u3002\u6c2f\u5316\u92c5\u4e5f\u6613\u5438\u6536\u6d3b\u6027\u78b3\u6216\u4e8c\u6c27\u5316\u77fd\uff0c\u85c9\u7531Friedel-Crafts\u53cd\u61c9\u9032\u884c\u91af\u5316\u53cd\u61c9\u548c\u70f7\u5316\u53cd\u61c9\uff1b\u5728\u916f\u5316\u53cd\u61c9\u548c\u7e2e\u5408\u53cd\u61c9\uff0c\u6c2f\u5316\u92c5\u6709\u5229\u65bc\u812b\u53bb\u53cd\u61c9\u7269\u7684\u6c34\u6216\u6c28\u5206\u5b50\uff0c\u5176\u4f8b\u5b50\u70baFischer indole \u5408\u6210\u3002<\/p>\n

\u6ce8\u610f\u4e8b\u9805<\/strong><\/span><\/p>\n

\u6c2f\u5316\u92c5\u6bd2\u6027\u5f88\u5f37\uff0c\u80fd\u5287\u70c8\u523a\u6fc0\u53ca\u71d2\u707c\u76ae\u819a\u548c\u7c98\u819c\uff0c\u9577\u671f\u8207\u6b64\u85e5\u54c1\u7522\u751f\u7684\u84b8\u6c23\u63a5\u89f8\u6642\uff0c\u5c0d\u547c\u5438\u9053\u3001\u6c23\u7ba1\u3001\u652f\u6c23\u7ba1\u9ecf\u819c\u6709\u640d\u5bb3\u3002\u4fdd\u6301\u5bb9\u5668\u5bc6\u5c01\uff0c\u8981\u5728\u6709\u8db3\u5920\u7684\u901a\u98a8\u689d\u4ef6\u4e0b\u4f7f\u7528\u3002\u751f\u7522\u4eba\u54e1\u5de5\u4f5c\u6642\u8981\u7a7f\u5de5\u4f5c\u670d\uff0c\u6234\u9632\u8b77\u773c\u93e1\u3001\u9632\u6bd2\u53e3\u7f69\u3001\u4e73\u81a0\u624b\u5957\uff0c\u4ee5\u4fdd\u8b77\u76ae\u819a\u3001\u773c\u775b\u3001\u547c\u5438\u5668\u5b98\u3002\u5728\u63a5\u89f8\u7684\u60c5\u6cc1\u4e0b\uff0c\u7acb\u5373\u7528\u5927\u91cf\u7684\u6c34\u6c96\u6d17\u773c\u775b\u6216\u76ae\u819a\u81f3\u5c1115\u5206\u9418\u3002<\/p>\n

\u53c3\u8003\u8cc7\u6599<\/strong><\/span><\/p>\n

    \n
  1. \u6c2f\u5316\u92c5http:\/\/en.wikipedia.org\/wiki\/Zinc_chloride<\/a><\/li>\n
  2. http:\/\/www.zaclon.com\/pdf\/zinc_chloride_sol_and_solid_data.pdf<\/a><\/li>\n
  3. Pushpananda A. Senaratne, <\/i>Felix M. Orihuela, Arcelio J. Malcolm, and Keith G. Anderson, Organic Process Research <\/i>& Development, 2003, 7, <\/i>185<\/li>\n
  4. Adam Sniady, Audrey Durham, Marco S. Morreale, Kraig A. Wheeler, Roman Dembinski, Org. Lett.,<\/i> 2007<\/b>, 9<\/i>, 1175<\/li>\n<\/ol>\n<\/div>","protected":false},"excerpt":{"rendered":"

    \u6c2f\u5316\u92c5(Zinc Chloride) \u570b\u7acb\u81fa\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u78a9\u58eb\u73ed\u4e8c\u5e74\u7d1a\u6c5f\u5b5f\u6f54 \u6c2f\u5316\u92c5\u7684\u6027\u8cea \u5916\u89c0\u7121\u8272\u6216\u767d\u8272\u6676…<\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[57,108,48],"tags":[5466,5465],"class_list":["post-45779","post","type-post","status-publish","format-standard","hentry","category-chemistry02-03","category-chemistry00","category-chemistry01","tag-5466","tag-5465","loop-entry","cat-57","cat-108","cat-48","no-thumbnail"],"views":13119,"_links":{"self":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/45779","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/comments?post=45779"}],"version-history":[{"count":1,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/45779\/revisions"}],"predecessor-version":[{"id":87411,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/45779\/revisions\/87411"}],"wp:attachment":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/media?parent=45779"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/categories?post=45779"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/tags?post=45779"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}