{"id":4558,"date":"2009-05-21T13:17:30","date_gmt":"2009-05-21T05:17:30","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=4558"},"modified":"2021-10-06T16:49:53","modified_gmt":"2021-10-06T08:49:53","slug":"%e5%91%8b%e5%96%83%ef%bc%88furan%ef%bc%89","status":"publish","type":"post","link":"http:\/\/localhost\/%e5%91%8b%e5%96%83%ef%bc%88furan%ef%bc%89\/","title":{"rendered":"\u544b\u5583\uff08Furan\uff09"},"content":{"rendered":"<div class=\"pf-content\"><p><strong><span style=\"color: #ff6600;\">\u544b\u5583\uff08Furan\uff09<\/span><br \/>\n<span style=\"color: #008000;\">\u570b\u7acb\u65b0\u838a\u9ad8\u7d1a\u4e2d\u5b78\u5316\u5b78\u79d1\u9673\u5049\u6c11\u9000\u4f11\u6559\u5e2b\/\u570b\u7acb\u53f0\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u8449\u540d\u5009\u6559\u6388\u8cac\u4efb\u7de8\u8f2f<\/span><\/strong><\/p>\n<p>\u544b\u5583\u662f\u4e00\u7a2e\u96dc\u74b0\u6709\u6a5f\u5316\u5408\u7269\u3002\u901a\u5e38\u7531\u542b\u7e96\u7dad\u7d20\u56fa\u9ad4\u5982\u677e\u6728\uff0c\u6216\u542b\u4e94\u78b3\u91a3\u7684\u7269\u8cea\u7d93\u7531\u71b1\u5206\u89e3\u88fd\u53d6\u3002\u544b\u5583\u70ba\u7121\u8272\u3001\u53ef\u71c3\uff0c\u5177\u9ad8\u5ea6\u63ee\u767c\u6027\u7684\u6db2\u9ad4\uff0c\u5176\u6cb8\u9ede31.3 \u2103\uff0c\u63a5\u8fd1\u5ba4\u6eab\uff0c\u6709\u6bd2\u4e14\u53ef\u80fd\u6709\u81f4\u764c\u6027\u3002\u544b\u5583\u7d93\u7531\u9200\u50ac\u5316\uff0c\u53ef\u6c2b\u5316\u7522\u751f\u56db\u6c2b\u544b\u5583\uff0c\u70ba\u4e3b\u8981\u7684\u6709\u6a5f\u6eb6\u5291\u3002<\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image001.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-11221\" title=\"\u544b\u5583\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image001.jpg\" alt=\"\" width=\"343\" height=\"122\" \/><\/a><br \/>\n<!--more--><\/p>\n<p><strong>\u6b77\u53f2<\/strong><br \/>\n\u544b\u5583\u547d\u540d\u7684\u7531\u4f86\u662f\u6e90\u81ea\u62c9\u4e01\u5b57furfur\uff0c\u610f\u601d\u662f\u7ce0\u3002\u57281780\u5e74\u8b1d\u7d2f\uff08Carl Wilhelm Scheele\uff09\u7b2c\u4e00\u500b\u88fd\u6210\u544b\u5583\u7684\u884d\u751f\u7269\u2500\u25002-\u7ce0\u9178\uff082-furoic acid\uff09\u3002\u53e6\u4e00\u7a2e\u91cd\u8981\u7684\u544b\u5583\u884d\u751f\u7269\u7ce0\u919b\uff08furfural\uff09\u5247\u662f\u57281831\u5e74\u7531\u5fb7\u57f9\u840a\u7d0d\uff08Johann Wolfgang D\u00f6bereiner\uff09\u9996\u6b21\u88fd\u53d6\u6210\u529f\uff0c\u4e5d\u5e74\u4e4b\u5f8c\u7531\u65af\u767b\u8c6a\u65af\uff08John Stenhouse\uff09\u78ba\u8a8d\u5176\u6027\u8cea\u3002\u544b\u5583\u672c\u8eab\u5230\u4e861870\u5e74\u624d\u7531\u6797\u666e\u5229\u7279\uff08Heinrich Limpricht\uff09\u88fd\u5099\u6210\u529f\uff0c\u4e0d\u904e\u4ed6\u7a31\u4e4b\u70ba\u300c\u56db\u915a\u300d\u3002<\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image003.jpg\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-11222\" title=\"2-\u7ce0\u9178\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image003.jpg\" alt=\"\" width=\"413\" height=\"129\" \/><\/a><\/p>\n<p><strong>\u5408\u6210\u8207\u5206\u96e2<\/strong><br \/>\n\u2027\u738b\u7c73\u687f\u8207\u786b\u9178\u6df7\u5408\u5f8c\uff0c\u7d93\u71b1\u88c2\u89e3\u88fd\u5f97\u7ce0\u919b\uff0c\u7ce0\u919b\u7d93\u7531\u6c27\u5316\u8207\u53bb\u7fa7\u57fa\u53ef\u88fd\u5f97\u544b\u5583\u3002<br \/>\n\u2027\u5178\u578b\u7684\u544b\u5583\u6709\u6a5f\u5408\u6210\u6cd5\u662f\u83f2\u601d\u7279\uff0d\u6bd4\u5948\u745e\u5408\u6210\u6cd5\uff08Feist-Benary synthesis\uff09\uff0c \u6b64\u6cd5\u662f\u5229\u7528\u03b1\uff0d\u9e75\u916e\u8207\u03b2\uff0d\u96d9\u7fb0\u5316\u5408\u7269\u4e4b\u9593\u7684\u6709\u6a5f\u53cd\u61c9\uff0c\u751f\u6210\u544b\u5583\u7684\u884d\u751f\u7269\u3002<br \/>\n<a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image004.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-11223\" title=\"\u544b\u5583\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image004.png\" alt=\"\" width=\"500\" height=\"94\" \/><\/a><\/p>\n<p>\u2027\u5408\u6210\u544b\u5583\u6700\u7c21\u55ae\u7684\u65b9\u6cd5\u662f\u5df4\uff0d\u8afe\u5408\u6210\u6cd5\uff08Paal-Knorr Synthesis\uff09\uff0c\u6b64\u6cd5\u662f\u75311,4-\u4e8c\u916e\u8207\u4e94\u6c27\u5316\u4e8c\u78f7\uff08P2O5\uff09\u767c\u751f\u53cd\u61c9\u3002\u4e94\u6c27\u5316\u4e8c\u78f7\u6709\u540c\u8cea\u591a\u6676\u73fe\u8c61\uff08polymorphism\uff09\uff0c\u5176\u4e2d\u6700\u666e\u904d\u7684\u4e00\u7a2e\u6676\u5f62\u70ba\u5341\u6c27\u5316\u56db\u78f7\uff08P<sub>4<\/sub>O<sub>10<\/sub>\uff09\u3002\u6709\u8da3\u7684\u662f\u4ee51,4-\u4e8c\u916e\u8207\u52de\u68ee\u8a66\u5291\uff08Lawesson\u2019s reagent \uff09\u767c\u751f\u53cd\u61c9\u88fd\u53d6\u567b\u5429\uff08thiophene\uff09\u6642\uff0c\u544b\u5583\u70ba\u5176\u526f\u7522\u54c1\u3002<\/p>\n<p>\u00a0<a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image006.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-11224\" title=\"\u5408\u6210\u544b\u5583\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image006.png\" alt=\"\" width=\"500\" height=\"108\" \/><\/a><\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image008.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-11225\" title=\"\u5408\u6210\u544b\u5583\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image008.png\" alt=\"\" width=\"500\" height=\"99\" \/><\/a><\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2010\/06\/\u544b\u5583\uff08Furan\uff09-5.png\"><\/a><\/p>\n<p><strong>\u5316\u5b78<\/strong><br \/>\n\u56e0\u70ba\u6c27\u539f\u5b50\u4e0a\u6709\u4e00\u5b64\u96fb\u5b50\u5c0d\u53c3\u8207\u74b0\u4e0a\u7684\u975e\u5b9a\u57df\u96fb\u5b50\u96f2\uff0c\u8207\u82ef\u4e00\u6a23\u7b26\u54084n+2\u82b3\u9999\u65cf\u7cfb\u7d71\uff08\u53c3\u770b\u4f11\u514b\u723e\u6cd5\u5247\uff09\uff0c\u56e0\u6b64\u544b\u5583\u5c6c\u82b3\u9999\u65cf\u3002\u65e2\u7136\u5c6c\u65bc\u82b3\u9999\u65cf\uff0c\u544b\u5583\u662f\u5e73\u9762\u5206\u5b50\u4e14\u6c92\u6709\u7368\u7acb\u7684\u96d9\u9375\u3002\u6c27\u539f\u5b50\u4e0a\u7684\u53e6\u4e00\u5b64\u96fb\u5b50\u5c0d\u7531\u74b0\u4e0a\u7cfb\u7d71\u4e0a\u7684\u5e73\u9762\u5411\u5916\u5ef6\u4f38\uff0csp2\u6df7\u5408\u8ecc\u57df\u5141\u8a31\u6c27\u539f\u5b50\u7684\u4e00\u5b64\u96fb\u5b50\u5c0d\u7559\u5728p\u8ecc\u57df\uff0c\u56e0\u6b64\u53ef\u5728\u03c0\u7cfb\u7d71\u5167\u4ea4\u4e92\u4f5c\u7528\u3002\u56e0\u70ba\u544b\u5583\u5c6c\u82b3\u9999\u65cf\uff0c\u5176\u6027\u8cea\u8207\u5178\u578b\u7684\u96dc\u74b0\u919a\u5982\u56db\u6c2b\u544b\u5583\u975e\u5e38\u4e0d\u540c\u3002<\/p>\n<p>\u2027\u56e0\u70ba\u96dc\u74b0\u4e0a\u7684\u6c27\u539f\u5b50\u4f9b\u61c9\u96fb\u5b50\u7684\u6548\u61c9\uff0c\u544b\u5583\u5728\u89aa\u96fb\u5b50\u53d6\u4ee3\u53cd\u61c9\u4e2d\uff0c\u5176\u6d3b\u6027\u6bd4\u82ef\u7684\u6d3b\u6027\u5927\u5f88\u591a\u3002\u56e0\u5171\u632f\u589e\u52a0\u4e86\u74b0\u4e0a\u7684\u96fb\u5b50\u5bc6\u5ea6\uff0c\u5c0e\u81f4\u89aa\u96fb\u5b50\u53d6\u4ee3\u7684\u53cd\u61c9\u901f\u7387\u589e\u52a0\u3002<\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image010.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-11226\" title=\"\u544b\u5583\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image010.png\" alt=\"\" width=\"500\" height=\"88\" \/><\/a><\/p>\n<p>\u2027 \u5728\u72c4-\u963f\u53cd\u61c9\uff08Diels-Alder reactions\uff09\u4e2d\uff0c\u544b\u5583\u4f5c\u70ba\u4e8c\u70ef\uff0c\u8207\u7f3a\u96fb\u5b50\u7684\u89aa\u4e8c\u70ef\u7269\uff08dienophile\uff09\u5982\u53cd3-\u785d\u57fa\u4e19\u70ef\u9178\u4e59\u916f\u767c\u751f\u53cd\u61c9\uff0c\u7522\u7269\u70ba\u6df7\u5408\u7269\u3002<\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image012.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-11227\" title=\"\u544b\u5583\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image012.png\" alt=\"\" width=\"500\" height=\"101\" \/><\/a><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2010\/06\/\u544b\u5583\uff08Furan\uff09-7.png\"><\/a><\/p>\n<p>\u2027 \u5728\u544b\u5583\u7684\u6c2b\u5316\u53cd\u61c9\u4e2d\uff0c\u53ef\u7522\u751f\u4e8c\u6c2b\u544b\u5583\uff0c\u518d\u9032\u4e00\u6b65\u7522\u751f\u56db\u6c2b\u544b\u5583\u3002<\/p>\n<p>\u00a0<a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image014.png\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone size-full wp-image-11228\" title=\"\u544b\u5583\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2009\/05\/4558_image014.png\" alt=\"\" width=\"500\" height=\"85\" \/><\/a><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2010\/06\/\u544b\u5583\uff08Furan\uff09-8.png\"><\/a><\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"<p>\u544b\u5583\uff08Furan\uff09 \u570b\u7acb\u65b0\u838a\u9ad8\u7d1a\u4e2d\u5b78\u5316\u5b78\u79d1\u9673\u5049\u6c11\u9000\u4f11\u6559\u5e2b\/\u570b\u7acb\u53f0\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u8449\u540d\u5009\u6559\u6388\u8cac\u4efb\u7de8\u8f2f \u544b\u5583\u662f\u4e00\u7a2e&hellip;<\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[108,50,48],"tags":[2555,2554,1246],"class_list":["post-4558","post","type-post","status-publish","format-standard","hentry","category-chemistry00","category-chemistry01-02","category-chemistry01","tag-furan","tag-2554","tag-1246","loop-entry","cat-108","cat-50","cat-48","no-thumbnail"],"views":10118,"_links":{"self":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4558","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/comments?post=4558"}],"version-history":[{"count":1,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4558\/revisions"}],"predecessor-version":[{"id":91109,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/4558\/revisions\/91109"}],"wp:attachment":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/media?parent=4558"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/categories?post=4558"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/tags?post=4558"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}