{"id":26711,"date":"2011-05-05T11:22:47","date_gmt":"2011-05-05T03:22:47","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=26711"},"modified":"2021-10-06T16:27:03","modified_gmt":"2021-10-06T08:27:03","slug":"%e6%b4%bb%e5%8c%96%e9%8c%af%e5%90%88%e7%89%a9activated-complex","status":"publish","type":"post","link":"http:\/\/localhost\/%e6%b4%bb%e5%8c%96%e9%8c%af%e5%90%88%e7%89%a9activated-complex\/","title":{"rendered":"\u6d3b\u5316\u932f\u5408\u7269(Activated Complex)"},"content":{"rendered":"<div class=\"pf-content\"><p><strong><span style=\"color: #ff6600;\">\u6d3b\u5316\u932f\u5408\u7269(Activated Complex)<br \/>\n<\/span><span style=\"color: #008000;\">\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u5b78\u58eb\u751f\u5f35\u80b2\u5510\/\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u9673\u85f9\u7136\u535a\u58eb\u8cac\u4efb\u7de8\u8f2f<\/span><\/strong><\/p>\n<p>\u6d3b\u5316\u932f\u5408\u7269(Activated Complex) \u7528\u4f86\u63cf\u8ff0\u4e00\u500b\u5316\u5b78\u53cd\u61c9\u88e1\uff0c\u53cd\u61c9\u7269\u8f49\u8b8a\u6210\u7522\u7269\u904e\u7a0b\u4e2d\uff0c\u539f\u5b50\u91cd\u7d44\u7684\u904e\u6e21\u72c0\u614b\u5316\u5408\u7269\uff0c\u6d3b\u5316\u932f\u5408\u7269\u6975\u4e0d\u7a69\u5b9a\uff0c\u53ef\u4ee5\u9032\u4e00\u6b65\u5206\u89e3\u6210\u7522\u7269\uff0c\u4e5f\u53ef\u80fd\u5728\u80fd\u91cf\u4e0d\u8db3\u7684\u72c0\u614b\u4e0b\u56de\u5fa9\u6210\u751f\u6210\u7269\u3002<\/p>\n<p>\u5206\u5b50\u8981\u9032\u884c\u5316\u5b78\u53cd\u61c9\uff0c\u9996\u5148\u5206\u5b50\u5fc5\u9808\u8981\u6709\u8db3\u5920\u767c\u751f\u53cd\u61c9\u7684\u80fd\u91cf\uff0c\u767c\u751f\u53cd\u61c9\u7684\u81e8\u754c\u80fd\u91cf\u7a31\u70ba\u6d3b\u5316\u80fd(Activation energy, Ea)\uff0c\u901a\u5e38\u53ea\u6709\u90e8\u4efd\u7684\u5206\u5b50\u7684\u80fd\u91cf\u5927\u65bc\u6d3b\u5316\u80fd\u53ef\u4ee5\u9032\u884c\u53cd\u61c9\u3002\u5728\u904e\u6e21\u614b\u7406\u8ad6(transition state theory)\uff0c\u53cd\u61c9\u7269\u5206\u5b50\u78b0\u649e\u9054\u5230\u6d3b\u5316\u80fd\u6642\u5f62\u6210\u300c\u6d3b\u5316\u932f\u5408\u7269\u300d\u3002 \u6b64\u5916\uff0c\u7531\u65bc\u6d3b\u5316\u932f\u5408\u7269\u80fd\u91cf\u9760\u8fd1\u6d3b\u5316\u80fd\uff0c\u986f\u793a\u7121\u8ad6\u662f\u5438\u71b1\u53cd\u61c9\u9084\u662f\u653e\u71b1\u53cd\u61c9\u90fd\u9700\u8981\u5438\u6536\u80fd\u91cf\u624d\u80fd\u5f62\u6210\u3002\u6d3b\u5316\u932f\u5408\u7269\u7684\u751f\u5b58\u6642\u9593\u975e\u5e38\u77ed\uff0c\u4ee510<sup>-12<\/sup>\u79d2(picoseconds)\u8a08\uff0c\u5f9e\u524d\u6d3b\u5316\u932f\u5408\u7269\u662f\u7121\u6cd5\u5075\u6e2c\u7684\uff0c\u4f46\u662f\u73fe\u5728\u79d1\u5b78\u5bb6\u5df2\u7d93\u627e\u5230\u65b9\u6cd5\uff0c\u5229\u752810<sup>-15<\/sup>\u79d2(femtosecond)\u7684\u8108\u885d\u96f7\u5c04(pulsed laser)\u5149\u4f86\u89c0\u5bdf\u6d3b\u5316\u932f\u5408\u7269\u3002\u900f\u904e\u7814\u7a76\u6d3b\u5316\u932f\u5408\u7269\uff0c\u53ef\u4ee5\u4e86\u89e3\u53cd\u61c9\u6a5f\u5236(Mechanism)\u548c\u53cd\u61c9\u80fd\u91cf\u8b8a\u5316\u3002<\/p>\n<p><!--more--><\/p>\n<p>\u5728\u8a31\u591a\u666e\u5316\u8ab2\u672c\u4e2d\u6d3b\u5316\u932f\u5408\u7269\u53c8\u7a31\u904e\u6e21\u614b(transition state)\uff0c\u4f46\u662f\u5728\u9032\u968e\u7684\u7269\u7406\u5316\u5b78\u8ab2\u672c\u4e2d\uff0c\u300c\u6d3b\u5316\u932f\u5408\u7269\u300d\u548c\u300c\u904e\u6e21\u614b\u300d\u5176\u5be6\u5177\u6709\u4e0d\u540c\u7684\u5316\u5b78\u610f\u7fa9\u3002\u6211\u5011\u5e38\u4ee5\u5316\u5b78\u53cd\u61c9\u4f4d\u80fd\u5716\uff08Reaction profile\u6216reaction energy diagram\uff09\u4f86\u63cf\u8ff0\u4e00\u500b\u5316\u5b78\u53cd\u61c9 \u7684\u80fd\u91cf\u6539\u8b8a\u3002\u53cd\u61c9\u4f4d\u80fd\u5716\u4ee5\u5316\u5b78\u53cd\u61c9\u7684\u9032\u884c\u70ba\u6a6b\u5750\u6a19\uff0c\u53cd\u61c9\u4f4d\u80fd\u70ba\u7e31\u5750\u6a19\uff0c\u53cd\u61c9\u7269\u548c\u7522\u7269\u7684\u4f4d\u80fd\u9ad8\u4f4e\u4f9d\u7269\u8cea\u6027\u8cea\u800c\u5b9a\uff0c\u53cd\u61c9\u7269\u7684\u80fd\u91cf\u4e0d\u4e00\u5b9a\u6bd4\u7522\u7269\u4f4e\u3002\u53cd\u61c9\u7269\u6cbf\u53cd\u61c9\u4f4d\u80fd\u66f2\u7dda\u8b8a\u6210\u7522\u7269\uff0c\u7531\u65bc\u53c3\u8207\u53cd\u61c9\u7684\u53cd\u61c9\u7269\u5206\u5b50\u9700\u8981\u6709\u8db3\u5920\u7684\u80fd\u91cf\u9032\u884c\u539f\u5b50\u91cd\u7d44\uff0c\u6545\u53cd\u61c9\u4f4d\u80fd\u4e0a\u5347\uff0c\u5176\u6700\u80fd\u91cf\u9ad8\u9ede\u548c\u53cd\u61c9\u7269\u8d77\u59cb\u4f4d\u80fd\u5dee\u70ba\u6d3b\u5316\u80fd(Ea)\u3002\u525b\u597d\u4f4d\u65bc\u53cd\u61c9\u4f4d\u80fd\u6700\u9ad8\u9ede\u7684\u904e\u6e21\u5316\u5408\u7269\u7a31\u70ba\u300c\u904e\u6e21\u614b\u300d\u3002\u6d3b\u5316\u932f\u5408\u7269\u5247\u662f\u6cdb\u6307\u300c\u80fd\u91cf\u63a5\u8fd1\u6d3b\u5316\u80fd\u7684\u53cd\u61c9\u4e2d\u9593\u7d50\u69cb\u300d\u3002\u63db\u53e5\u8a71\u8aaa\uff0c\u904e\u6e21\u614b\u662f\u6d3b\u5316\u932f\u5408\u7269\u7684\u4e00\u7a2e\u3002<\/p>\n<div id=\"attachment_26712\" style=\"width: 290px\" class=\"wp-caption aligncenter\"><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2011\/05\/127.jpg\" onfocus=\"undefined\"><img loading=\"lazy\" decoding=\"async\" aria-describedby=\"caption-attachment-26712\" class=\"size-full wp-image-26712\" title=\"1\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2011\/05\/127.jpg\" alt=\"\" width=\"280\" height=\"164\" \/><\/a><p id=\"caption-attachment-26712\" class=\"wp-caption-text\">\u5716\u4e00\u3001\u53cd\u61c9\u4f4d\u80fd\u5716\u3002\u7d05\u8272\u9ede\u4ee3\u8868\u904e\u6e21\u614b\uff0c\u85cd\u8272\u7bc4\u570d\u70ba\u6d3b\u5316\u932f\u5408\u7269\u3002<\/p><\/div>\n<p style=\"text-align: left;\">\n<p><strong>\u53c3\u8003\u8cc7\u6599\uff1a<br \/>\n<\/strong>1. Zumdahl, S. S. Chemical Principles, 5<sup>th<\/sup> edition; Houghton Mifflin Company: Boston, 2003; p. 736.<br \/>\n2. Atkins, P. W.; De Paula, J. Atkins\u2019 Physical Chemistry, 8<sup>th<\/sup> edition; Oxford University Press: New York, 2006, pp. 880-883.<br \/>\n3. Wikipedia\u2014Activated complex\u00a0\u00a0<a href=\"http:\/\/en.wikipedia.org\/wiki\/Activated_complex\" target=\"_blank\">http:\/\/en.wikipedia.org\/wiki\/Activated_complex<\/a><br \/>\n4. \u9673\u7af9\u4ead\u4e3b\u7de8\uff0c\u9ad8\u7d1a\u4e2d\u5b78\u7269\u8cea\u79d1\u5b78\u5316\u5b78\u7bc7\uff08\u4e0a\u518a\uff09\uff0c\u7b2c130\u9801\u81f3131\u9801\uff0c\u5927\u8003\u901a\u8a0a\u793e\u51fa\u7248\uff0c2002\u5e74\u3002<\/p>\n<p style=\"text-align: left;\">\u00a0<\/p>\n<\/div>","protected":false},"excerpt":{"rendered":"<p>\u6d3b\u5316\u932f\u5408\u7269(Activated Complex) \u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u5b78\u58eb\u751f\u5f35\u80b2\u5510\/\u570b\u7acb\u81fa\u7063\u5927\u5b78\u5316\u5b78\u7cfb\u9673\u85f9\u7136\u535a\u58eb&hellip;<\/p>\n","protected":false},"author":50,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[108,68,67],"tags":[2985,2984],"class_list":["post-26711","post","type-post","status-publish","format-standard","hentry","category-chemistry00","category-chemistry05-01","category-chemistry05","tag-activated-complex","tag-2984","loop-entry","cat-108","cat-68","cat-67","no-thumbnail"],"views":15375,"_links":{"self":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/26711","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/users\/50"}],"replies":[{"embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/comments?post=26711"}],"version-history":[{"count":1,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/26711\/revisions"}],"predecessor-version":[{"id":88534,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/posts\/26711\/revisions\/88534"}],"wp:attachment":[{"href":"http:\/\/localhost\/wp-json\/wp\/v2\/media?parent=26711"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/categories?post=26711"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/localhost\/wp-json\/wp\/v2\/tags?post=26711"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}