{"id":46020,"date":"2025-12-16T17:00:29","date_gmt":"2025-12-16T09:00:29","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=46020"},"modified":"2025-12-17T09:50:04","modified_gmt":"2025-12-17T01:50:04","slug":"%e5%be%9e%e7%8f%a0%e5%af%b6%e7%95%8c%e5%88%b0%e7%a7%91%e6%8a%80%e7%95%8c%e7%9a%84%e8%b6%85%e7%b4%9a%e6%96%9c%e6%a7%93%e4%bb%a3%e8%a1%a8%ef%bc%9a%e8%97%8d%e5%af%b6%e7%9f%b3%ef%bc%88sapphire%ef%bc%89","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=46020","title":{"rendered":"\u5f9e\u73e0\u5bf6\u754c\u5230\u79d1\u6280\u754c\u7684\u8d85\u7d1a\u659c\u69d3\u4ee3\u8868\uff1a\u85cd\u5bf6\u77f3\uff08Sapphire\uff09"},"content":{"rendered":"

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 <\/p>\n

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\u5929\u7136\u7684\u85cd\u5bf6\u77f3\u662f\u92c1\u6c27\u5316\u7269 (Al2<\/sub>O3<\/sub>) \u7684\u55ae\u6676\uff0c\u4e5f\u53eb\u505a\u300c\u525b\u7389\u300d\uff0c\u5b83\u7684\u786c\u5ea6\u50c5\u6b21\u65bc\u947d\u77f3\uff0c\u5916\u8868\u5149\u4eae\u5254\u900f\uff0c\u5b83\u4e4b\u6240\u4ee5\u5448\u73fe\u85cd\u8272\uff0c\u4e26\u4e0d\u662f\u56e0\u70ba\u92c1\u6c27\u5316\u7269\u672c\u8eab\uff0c\u800c\u662f\u56e0\u70ba\u5929\u7136\u85cd\u5bf6\u77f3\u542b\u6709\u6975\u5fae\u91cf\u7684\u9435\u8207\u9226\uff0c\u7576\u5149\u7a7f\u904e\u6676\u9ad4\u6642\uff0c\u96fb\u5b50\u6703\u5728Fe2+<\/sup>\u548cTi4+<\/sup>\u4e4b\u9593\u300c\u8df3\u8e8d\u300d\uff0c\u9019\u7a2e\u96fb\u8377\u8f49\u79fb\u9700\u8981\u5438\u6536\u7279\u5b9a\u80fd\u91cf\u7684\u5149\uff0c\u800c\u9019\u500b\u80fd\u91cf\u525b\u597d\u843d\u5728\u7d05\u5149\u8207\u90e8\u5206\u7da0\u5149\u7684\u7bc4\u570d\uff0c\u65bc\u662f\u9019\u4e9b\u6696\u8272\u5149\u88ab\u5438\u6536\uff0c\u53ea\u5269\u4e0b\u85cd\u5149\u8207\u7d2b\u5149\u901a\u904e\uff0c\u6211\u5011\u7684\u773c\u775b\u56e0\u6b64\u770b\u5230\u6df1\u85cd\u8272\uff0c\u56e0\u6b64\uff0c\u82e5\u628a\u6240\u6709\u96dc\u8cea\u90fd\u53bb\u6389\uff0c\u85cd\u5bf6\u77f3\u5176\u5be6\u662f\u5b8c\u5168\u900f\u660e\u7684\u3002<\/p>\n

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 <\/p>\n

\u85cd\u5bf6\u77f3\u7684\u7269\u7406\u7279\u6027<\/strong><\/span><\/h6>\n

\u70ba\u4ec0\u9ebc\u85cd\u5bf6\u77f3\u80fd\u7576\u534a\u5c0e\u9ad4\u754c\u7684\u300c\u8d85\u7d1a\u57fa\u677f\u300d\uff1f\u5728\u773e\u591a\u57fa\u677f\u6750\u6599\u4e2d\uff0c\u85cd\u5bf6\u77f3\u4e4b\u6240\u4ee5\u88ab\u5ee3\u6cdb\u63a1\u7528\uff0c\u662f\u56e0\u70ba\u5b83\u540c\u6642\u5177\u5099\u9ad8\u6eab\u7a69\u5b9a\u6027\u3001\u6676\u9ad4\u7d50\u69cb\u76f8\u5bb9\u6027\uff0c\u4ee5\u53ca\u96fb\u7d55\u7de3\u8207\u5149\u5b78\u900f\u660e\u7b49\u6027\u8cea\uff0c\u9019\u4e9b\u7269\u7406\u7279\u6027\u8b93\u5b83\u80fd\u652f\u6490\u591a\u7a2e\u6750\u6599\u7684\u5916\u5ef6\u6210\u9577\u8207\u5404\u5f0f\u5149\u96fb\u5143\u4ef6\u7684\u904b\u4f5c\uff0c\u4ee5\u4e0b\u6211\u5011\u4e00\u4e00\u4f86\u4e86\u89e3\u9019\u4e9b\u7269\u7406\u7279\u6027\u3002<\/p>\n

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  • \u8010\u9ad8\u6eab\u3001\u8010\u5316\u5b78\u8150\u8755<\/strong><\/li>\n<\/ul>\n

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    • \u6676\u9ad4\u7d50\u69cb\u8207\u591a\u7a2e\u516d\u89d2\u6216\u8fd1\u516d\u89d2\u6750\u6599\u76f8\u5bb9<\/strong><\/li>\n<\/ul>\n

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        \n
      • \u7d55\u7de3\u6027\u9ad8\u3001\u5149\u5b78\u900f\u660e<\/strong><\/li>\n<\/ul>\n

        \u85cd\u5bf6\u77f3\u7684\u96fb\u963b\u7387\u6975\u9ad8\uff08>1011<\/sup>\u03a9cm\uff09\uff0c\u6210\u70ba\u4e86\u7d55\u4f73\u7684\u7d55\u7de3\u9ad4\uff0c\u5e7e\u4e4e\u4e0d\u8b93\u96fb\u5b50\u901a\u904e\uff0c\u56e0\u6b64\u80fd\u6709\u6548\u907f\u514d\u9ad8\u58d3\u96fb\u5b50\u5143\u4ef6\u6216\u5c04\u983b\u96fb\u8def\u4e2d\u7684\u6f0f\u96fb\u8207\u96dc\u8a0a\uff0c\u53e6\u4e00\u65b9\u9762\uff0c\u5728\u6c92\u6709\u96dc\u8cea\u7684\u85cd\u5bf6\u77f3\u57fa\u677f\u4e2d\uff0c\u5f9e\u53ef\u898b\u5149\u5230\u7d05\u5916\u7dda\u90fd\u80fd\u4fdd\u6301\u9ad8\u900f\u5149\u7387\uff0c\u56e0\u5176\u80fd\u9699\u5c0d\u53ef\u898b\u5149\u800c\u8a00\u904e\u5927\uff0c\u4e0d\u6703\u5438\u6536\u9019\u4e9b\u6ce2\u6bb5\u7684\u5149\uff0c\u4f7f\u5176\u6210\u70ba\u5149\u96fb\u8a2d\u5099\u7684\u7406\u60f3\u57fa\u6750\uff0c\u5e38\u88ab\u7528\u4f5c\u96f7\u5c04\u51fa\u5149\u7a97\u3001\u7d05\u5916\u7dda\u611f\u6e2c\u5668\u4fdd\u8b77\u84cb\u8207\u771f\u7a7a\u8154\u9ad4\u7684\u89c0\u5bdf\u7a97\u3002<\/p>\n

        \u85cd\u5bf6\u77f3\u57fa\u677f\u5728\u79d1\u6280\u767c\u5c55\u4e2d\u6700\u5177\u4ee3\u8868\u6027\u7684\u7a81\u7834\uff0c\u5c31\u662f\u85cd\u5149LED\u7684\u8a95\u751f\uff0c\u8981\u8b93GaN\u9577\u6210\u9ad8\u54c1\u8cea\u8584\u819c\uff0c\u9700\u8981\u4e00\u500b\u80fd\u8010\u9ad8\u6eab\u3001\u4e0d\u5c0e\u96fb\u3001\u6676\u683c\u53c8\u8db3\u4ee5\u652f\u6490\u516d\u89d2\u7d50\u69cb\u7684\u57fa\u677f\uff0c\u800c\u7576\u6642\u80fd\u540c\u6642\u6eff\u8db3\u9019\u4e09\u500b\u689d\u4ef6\u7684\u6750\u6599\u4e26\u4e0d\u591a\uff0c\u85cd\u5bf6\u77f3\u4fbf\u56e0\u5176\u9ad8\u7194\u9ede\u3001\u7a69\u5b9a\u6027\u8207\u6676\u9ad4\u76f8\u5bb9\u6027\u6210\u70ba\u6700\u4f73\u7684\u9078\u64c7\uff0c\u6b63\u56e0\u70ba\u6c2e\u5316\u93b5\u80fd\u5728\u85cd\u5bf6\u77f3\u4e0a\u6210\u529f\u6210\u9577\uff0c1990\u5e74\u4ee3\u7684\u85cd\u5149LED\u624d\u5f97\u4ee5\u5be6\u73fe\uff0c\u4e26\u9032\u4e00\u6b65\u50ac\u751f\u767d\u5149LED\u3001\u80cc\u5149\u6e90\u3001\u624b\u6a5f\u7167\u660e\u8207\u7bc0\u80fd\u8def\u71c8\u7b49\u61c9\u7528\uff0c\u5fb9\u5e95\u6539\u8b8a\u4e86\u4eba\u985e\u7684\u7167\u660e\u65b9\u5f0f\u3002<\/p>\n

        \"\"
        \u57163 \u85cd\u5149LED\uff0c\u5b83\u7684\u8a95\u751f\u5b8c\u6210\u4e86\u88fd\u4f5c\u767d\u5149LED\u7684\u6700\u5f8c\u4e00\u54e9\u8def\uff5c\u4f86\u6e90\uff1aMotionElements<\/figcaption><\/figure>\n

        \u85cd\u5bf6\u77f3\u5728\u73e0\u5bf6\u754c\u8ca0\u8cac\u9583\u8000\uff0c\u5728\u79d1\u6280\u754c\u5247\u8ca0\u8cac\u767c\u5149\uff0c\u4e0d\u540c\u821e\u81fa\uff0c\u540c\u6a23\u6436\u773c\uff0c\u4f60\u9084\u77e5\u9053\u4ec0\u9ebc\u659c\u69d3\u5f88\u5927\u7684\u6750\u6599\u55ce\uff1f\uff01<\/p>\n

         <\/p>\n

        \n

        \u8a3b\u91cb\uff1a\u6587\u4e2d\u63d0\u5230\u7684\u79d1\u5b78\u5bb6\u8207\u6280\u8853<\/strong><\/p>\n

          \n
        • Verneuil\uff08Auguste Verneuil\uff0c\u6cd5\u570b\u5316\u5b78\u5bb6\uff09<\/li>\n<\/ul>\n

          1902\u5e74\u767c\u660e\u300c\u706b\u7130\u7194\u878d\u6cd5\u300d(Verneuil process)\uff0c\u662f\u7b2c\u4e00\u500b\u771f\u6b63\u80fd\u5927\u91cf\u88fd\u9020\u4eba\u9020\u85cd\u5bf6\u77f3\u7684\u6280\u8853\uff0c\u900f\u904e\u9ad8\u6eab\u706b\u7130\u7194\u878d\u6c27\u5316\u92c1\u7c89\u672b\uff0c\u518d\u8b93\u5176\u9010\u5c64\u51dd\u56fa\uff0c\u4fbf\u80fd\u9577\u51fa\u5982\u6676\u67f1\u822c\u7684\u85cd\u5bf6\u77f3\uff0c\u662f\u73fe\u4ee3\u6676\u9ad4\u751f\u9577\u6280\u8853\u7684\u8d77\u9ede\u3002<\/p>\n

            \n
          • Czochralski\uff08Jan Czochralski\uff0c\u6ce2\u862d\u5316\u5b78\u5bb6\uff09<\/li>\n<\/ul>\n

            1916\u5e74\u63d0\u51fa\u300c\u62c9\u6676\u6cd5\u300d(Czochralski process)\uff0c\u539f\u672c\u7528\u65bc\u7814\u7a76\u91d1\u5c6c\u51b7\u537b\u901f\u5ea6\uff0c\u5f8c\u4f86\u6210\u70ba\u5168\u7403\u88fd\u9020\u77fd\u6676\u5713\u7684\u4e3b\u529b\u65b9\u6cd5\uff0c\u5c07\u7a2e\u6676\u5b50\u5728\u7194\u878d\u6750\u6599\u4e2d\u7de9\u7de9\u62c9\u8d77\uff0c\u4fbf\u80fd\u751f\u9577\u51fa\u9ad8\u54c1\u8cea\u55ae\u6676\uff0c\u4e5f\u80fd\u61c9\u7528\u65bc\u751f\u9577\u85cd\u5bf6\u77f3\u3002<\/p>\n

              \n
            • Kyropoulos\uff08Spyro Kyropoulos\uff0c\u5e0c\u81d8\u7269\u7406\u5b78\u5bb6\uff09<\/li>\n<\/ul>\n

              1930\u5e74\u4ee3\u767c\u5c55\u7684\u300cKyropoulos\u6cd5\u300d\u5229\u7528\u6162\u901f\u3001\u5747\u52fb\u7684\u964d\u6eab\uff0c\u4f7f\u6574\u584a\u7194\u878d\u6750\u6599\u81ea\u4e2d\u5fc3\u958b\u59cb\u51dd\u56fa\uff0c\u9010\u6f38\u9577\u6210\u5927\u578b\u900f\u660e\u6676\u9ad4\u3002\u56e0\u61c9\u529b\u8f03\u5c0f\u3001\u7f3a\u9677\u5c11\uff0c\u662f\u4eca\u65e5\u751f\u9577\u5927\u5c3a\u5bf8\u85cd\u5bf6\u77f3\u7684\u4e3b\u6d41\u6280\u8853\u3002<\/p>\n

                \n
              • HEM\uff08Heat Exchanger Method\uff0c\u71b1\u4ea4\u63db\u6cd5\uff09<\/li>\n<\/ul>\n

                1960\u201370\u5e74\u4ee3\u9010\u6b65\u6210\u719f\uff0c\u5176\u539f\u7406\u662f\u5229\u7528\u4e0a\u4e0b\u6eab\u5dee\u63a7\u5236\u6676\u9ad4\u5f9e\u9ad8\u6eab\u5340\u5411\u4f4e\u6eab\u5340\u7a69\u5b9a\u6210\u9577\uff0c\u80fd\u751f\u9577\u51fa\u6975\u5927\u3001\u6975\u900f\u660e\u3001\u7f3a\u9677\u5bc6\u5ea6\u6975\u4f4e\u7684\u85cd\u5bf6\u77f3\u6676\u68d2\uff0c\u662f\u9ad8\u968e\u5149\u96fb\u8207\u91cf\u6e2c\u8a2d\u5099\u5e38\u7528\u7684\u85cd\u5bf6\u77f3\u4f86\u6e90\u3002<\/p>\n

                 <\/p>\n

                \n

                \u53c3\u8003\u6587\u737b<\/strong><\/p>\n

                  \n
                1. Bruni, F. J. (2015). Crystal growth of sapphire for substrates for high\u2010brightness, light emitting diodes. Crystal Research and Technology, 50(1), 133-142.<\/li>\n
                2. Ryou, J. H. (2014). Gallium nitride (GaN) on sapphire substrates for visible LEDs. In\u00a0Nitride Semiconductor Light-Emitting Diodes (LEDs)<\/em>(pp. 66-98). Woodhead Publishing.<\/li>\n
                3. Harris, D. C. (2003, September). A peek into the history of sapphire crystal growth. In Window and Dome Technologies VIII (Vol. 5078, pp. 1-11). SPIE.<\/li>\n
                4. Tomaszewski, P. E. (2002). Jan Czochralski\u2014father of the Czochralski method.\u00a0Journal of crystal growth<\/em>,\u00a0236<\/em>(1-3), 1-4.<\/li>\n
                5. Falckenberg, R. (1978). The Verneuil Process. In Crystal Growth: Theory and Techniques Volume 2 (pp. 109-184). Boston, MA: Springer US.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

                  \u85cd\u5bf6\u77f3\uff08Al2O3\uff09\u4e0d\u53ea\u662f\u73cd\u8cb4\u73e0\u5bf6\uff0c\u66f4\u662f\u73fe\u4ee3\u96fb\u5b50\u8207\u5149\u96fb\u79d1\u6280\u4e0d\u53ef\u6216\u7f3a\u7684\u300c\u8d85\u7d1a\u57fa\u677f\u300d\u3002\u5b83\u6191\u85c9\u8457\u5e7e\u9805\u95dc\u9375\u7279\u6027\uff0c\u6210\u70ba\u534a\u5c0e\u9ad4\u5143\u4ef6\u751f\u9577\u7684\u7406\u60f3\u300c\u5730\u57fa\u300d\u3002\u7b2c\u4e00\u662f\u7a69\u5b9a\u6027\uff0c\u5b83\u7684\u7194\u9ede\u9ad8\u9054 2050\u00b0C\uff0c\u4e14\u5316\u5b78\u7a69\u5b9a\u6027\u6975\u4f73\uff0c\u80fd\u627f\u53d7\u6750\u6599\u5728\u5916\u5ef6\u751f\u9577\u6642\u6240\u9700\u7684\u9ad8\u6eab\uff0c\u7b2c\u4e8c\u662f\u516d\u89d2\u6676\u9ad4\u7d50\u69cb\uff0c\u80fd\u8207\u8a31\u591a\u5177\u7d50\u6676\u6027\u7684\u6750\u6599\u5339\u914d\uff0c\u6210\u70ba\u7406\u60f3\u7684\u6750\u6599\u6210\u9577\u57fa\u677f\uff0c\u7b2c\u4e09\u662f\u85cd\u5bf6\u77f3\u7684\u7d55\u7de3\u96fb\u6027\u8207\u9ad8\u900f\u5149\u6027\uff0c\u80fd\u5920\u9632\u6b62\u975e\u9810\u671f\u7684\u96fb\u6d41\u6548\u61c9\uff0c\u4e26\u4e14\u80fd\u5141\u8a31\u53ef\u898b\u5149\u5230\u7d05\u5916\u5149\u6ce2\u6bb5\u7684\u5149\u7dda\u901a\u904e\uff0c\u6210\u70ba\u5149\u96fb\u8a2d\u5099\u7684\u57fa\u790e\uff0c\u800c\u9019\u4e9b\u7368\u7279\u7684\u7269\u7406\u7279\u6027\u4e5f\u4fc3\u6210\u4e86\u85cd\u5149LED\u7684\u8a95\u751f\uff0c\u9769\u547d\u6027\u5730\u6539\u8b8a\u4e86\u4eba\u985e\u7684\u7167\u660e\u6280\u8853\u3002<\/p>\n","protected":false},"author":20,"featured_media":46022,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1023,3293,3005,2977],"tags":[1460,1045,7489,1348],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2025\/12\/\u57161.png","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/46020"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=46020"}],"version-history":[{"count":2,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/46020\/revisions"}],"predecessor-version":[{"id":46025,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/46020\/revisions\/46025"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/46022"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=46020"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=46020"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=46020"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}