{"id":45882,"date":"2025-10-28T18:00:22","date_gmt":"2025-10-28T10:00:22","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=45882"},"modified":"2025-10-28T15:02:41","modified_gmt":"2025-10-28T07:02:41","slug":"%e4%ba%8c%e7%b6%advs2%e7%9a%84%e9%9b%99%e9%87%8d%e9%9d%88%e9%ad%82%ef%bc%8c%e9%87%91%e5%b1%ac%e9%82%84%e6%98%af%e5%8d%8a%e5%b0%8e%e9%ab%94%ef%bc%9f%ef%bc%88%e4%b8%8b%ef%bc%89","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=45882","title":{"rendered":"\u4e8c\u7dadVS2\u7684\u96d9\u91cd\u9748\u9b42\uff0c\u91d1\u5c6c\u9084\u662f\u534a\u5c0e\u9ad4\uff1f\uff08\u4e0b\uff09"},"content":{"rendered":"

\u7576VS2<\/sub>\u7684\u539f\u5b50\u5806\u758a\u65b9\u5f0f\u7531T\u76f8\u7684\u516b\u9762\u9ad4\u8f49\u8b8a\u70baH\u76f8\u7684\u4e09\u89d2\u68f1\u67f1\uff0c\u5176\u96fb\u5b50\u8ecc\u57df\u8207\u80fd\u5e36\u7d50\u69cb\u88ab\u91cd\u65b0\u6392\u5217\uff0c\u958b\u555f\u4e86\u53ef\u8abf\u5e36\u9699\uff0c\u6210\u70ba\u4e86\u96fb\u8377\u50b3\u8f38\u53ef\u88ab\u63a7\u5236\u7684\u534a\u5c0e\u9ad4\uff0c\u800c\u5b83\u7684\u80fd\u9699\u7bc4\u570d\u6b63\u597d\u843d\u5728\u4eba\u773c\u53ef\u898b\u5149\u7bc4\u570d\u4e2d\uff0c\u80fd\u5438\u6536\u53ef\u898b\u5149\u8207\u50b3\u5c0e\u96fb\u5b50\uff0c\u56e0\u6b64\u9084\u80fd\u88ab\u61c9\u7528\u5728\u5149\u96fb\u5143\u4ef6\u4e2d\uff0c\u66f4\u91cd\u8981\u7684\u662f\uff0c\u5176\u5ba4\u6eab\u9435\u78c1\u6027\u8b93\u96fb\u5b50\u80fd\u540c\u6642\u651c\u5e36\u96fb\u8377\u8207\u81ea\u65cb\uff0c\u80fd\u70ba\u589e\u52a0\u8cc7\u8a0a\u4e58\u8f09\u91cf\u3001\u904b\u8f38\u901f\u7387\u53ca\u964d\u4f4e\u8017\u80fd\u3002\u8b93\u6211\u5011\u4e00\u8d77\u4f86\u8a8d\u8b58\u5177\u6709\u534a\u5c0e\u9ad4\u9748\u9b42\u7684H-VS2<\/sub>\u3002<\/strong><\/span><\/p>\n

\u64b0\u6587\uff5c\u9ec3\u9f0e\u921e<\/strong><\/p>\n

\u5728\u4e0a\u4e00\u7bc7\u3008\u4e8c\u7dadVS2<\/sub>\u7684\u96d9\u91cd\u9748\u9b42\u3009\u4e2d\uff0c\u6211\u5011\u770b\u898b\u4e86T\u76f8VS2<\/sub>\u5982\u4f55\u4ee5\u5c64\u72c0\u7d50\u69cb\u3001\u591a\u8b8a\u50f9\u614b\u3001\u91d1\u5c6c\u5c0e\u96fb\u6027\u4ee5\u53ca\u5ba4\u6eab\u9435\u78c1\u6027\u6210\u70ba\u4e86\u80fd\u6e90\u8207\u96fb\u5316\u5b78\u9818\u57df\u7684\u660e\u65e5\u4e4b\u661f\u3002\u9019\u4e00\u6b21\u6211\u5011\u8981\u4f86\u8a8d\u8b58VS2<\/sub>\u7684\u53e6\u4e00\u9762\u2014\u2014H\u76f8\uff0c\u7576\u539f\u5b50\u7684\u5806\u758a\u65b9\u5f0f\u5f9e\u516b\u9762\u9ad4\u8b8a\u70ba\u4e09\u89d2\u68f1\u67f1\uff0cVS2<\/sub>\u7684\u7269\u7406\u6027\u8cea\u7522\u751f\u4e86\u8b8a\u5316\uff0c\u5b83\u4e0d\u518d\u662f\u96fb\u5b50\u80fd\u81ea\u7531\u5f9c\u5f89\u7684\u91d1\u5c6c\uff0c\u800c\u662f\u96fb\u5b50\u904b\u52d5\u53d7\u63a7\u7684\u534a\u5c0e\u9ad4\u3002<\/p>\n

\"\"
\u57161\uff1aH-VS2\u793a\u610f\u5716\uff0c\u7d05\u8272\u70baV\u539f\u5b50\uff0c\u9ec3\u8272\u70baS\u539f\u5b50\uff5c\u4f86\u6e90\uff1a\u6539\u7de8\u81eaMaterials Explorer<\/figcaption><\/figure>\n

 <\/p>\n

\u5f9e\u91d1\u5c6c\u5230\u534a\u5c0e\u9ad4\u7684\u7d50\u69cb\u8f49\u63db<\/strong><\/span><\/h6>\n

H-VS2<\/sub>\u5c6c\u65bc\u4e09\u89d2\u68f1\u67f1 (trigonal prismatic) \u7d50\u69cb\uff0c\u8207T\u76f8\u76f8\u6bd4\uff0c\u5176V\u2013S\u9375\u89d2\u8207\u5c64\u9593\u8ddd\u96e2\u7684\u8b8a\u5316\uff0c\u4f7f\u5f97\u539f\u5b50\u6392\u5217\u8207\u96fb\u5b50\u8ecc\u57df\u7684\u91cd\u758a\u65b9\u5f0f\u6539\u8b8a\uff0c\u7279\u5225\u662f\u9020\u6210d\u8ecc\u57df\u7684\u80fd\u968e\u5206\u88c2\uff0c\u56e0\u800c\u6253\u958b\u4e86\u80fd\u9699 (bandgap) \u8abf\u6574\u4e86\u80fd\u5e36\u7d50\u69cb\uff0c\u8b93H-VS2<\/sub>\u5448\u73fe\u51fa\u534a\u5c0e\u9ad4\u6027\u8cea\uff0c\u56e0\u6b64\u96fb\u5b50\u53ef\u4ee5\u88ab\u4fb7\u9650\u5728\u80fd\u5e36\u4e2d\uff0c\u4f7f\u5f97\u96fb\u8377\u50b3\u8f38\u53ef\u88ab\u63a7\u5236\u3002\u6839\u64da\u7406\u8ad6\u8a08\u7b97\uff0cH-VS2<\/sub>\u7684\u80fd\u9699\u7d04\u4ecb\u65bc0.5\u81f31 eV\uff0c\u4e26\u4e14\u53ef\u900f\u904e\u5916\u52a0\u61c9\u8b8a\u529b\u3001\u96fb\u5834\u6216\u5c64\u6578\u63a7\u5236\u9032\u4e00\u6b65\u8abf\u6574\uff0c\u4f7f\u6211\u5011\u80fd\u6839\u64da\u7279\u5b9a\u7684\u96fb\u58d3\u9700\u6c42\u8a2d\u8a08\u96fb\u6676\u9ad4\u901a\u9053\u3001\u908f\u8f2f\u9598\uff0c\u4e14\u9019\u6a23\u7684\u80fd\u9699\u5927\u5c0f\u6b63\u597d\u843d\u5728\u53ef\u898b\u5149\u8207\u8fd1\u7d05\u5916\u5149\u4e4b\u9593\uff0c\u4e5f\u5c31\u662fH-VS2<\/sub>\u80fd\u5728\u4eba\u773c\u53ef\u898b\u7684\u5149\u8b5c\u7bc4\u570d\u4e2d\u4f86\u9032\u884c\u300c\u5438\u6536\u5149\u80fd\u300d\u8207\u300c\u50b3\u5c0e\u96fb\u5b50\u300d\uff0c\u4ea6\u88ab\u671f\u5f85\u61c9\u7528\u5728\u5149\u611f\u6e2c\u5668\u3001\u592a\u967d\u80fd\u96fb\u6c60\u6216\u5149\u901a\u8a0a\u6a21\u7d44\u7b49\u7b49\u7684\u5149\u96fb\u5143\u4ef6\u4e4b\u4e2d\u3002<\/p>\n

 <\/p>\n

\u9435\u78c1\u534a\u5c0e\u9ad4\u70ba\u5143\u4ef6\u958b\u5916\u639b<\/strong><\/span><\/h6>\n

\u7576\u7136\uff0cH-VS2<\/sub>\u6700\u5438\u5f15\u79d1\u5b78\u5bb6\u7684\u4e0d\u53ea\u662f\u534a\u5c0e\u9ad4\u7684\u7279\u6027\uff0c\u800c\u662f\u5b83\u7684\u5ba4\u6eab\u9435\u78c1\u6027\uff0c\u4e5f\u5c31\u662f\u8aaa\u6211\u5011\u6709\u6a5f\u6703\u88fd\u9020\u51fa\u300c\u81ea\u65cb\u53ef\u63a7\u7684\u534a\u5c0e\u9ad4\u300d\uff0c\u8207\u50b3\u7d71\u77fd\u57fa\u534a\u5c0e\u9ad4\u76f8\u6bd4\uff0c\u96fb\u5b50\u5728\u50b3\u8f38\u6642\u4e0d\u50c5\u651c\u5e36\u96fb\u8377\uff0c\u4e5f\u651c\u5e36\u81ea\u65cb\uff0c\u5b83\u4e0d\u50c5\u80fd\u8a18\u93040\u82071\uff0c\u9084\u80fd\u8a18\u9304\u300c\u81ea\u65cb\u5411\u4e0a\u300d\u8207\u300c\u81ea\u65cb\u5411\u4e0b\u300d\u5169\u7a2e\u91cf\u5b50\u72c0\u614b\uff0c\u4f7f\u904b\u7b97\u6548\u7387\u8207\u8cc7\u6599\u5bc6\u5ea6\u5927\u5e45\u63d0\u5347\uff0c\u9019\u6a23\u7684\u7279\u6027\u88ab\u671f\u5f85\u80fd\u61c9\u7528\u5728\u300c\u81ea\u65cb\u5834\u6548\u96fb\u6676\u9ad4 (spin-FET)\u300d\u8207\u300c\u78c1\u6027\u96a8\u6a5f\u5b58\u53d6\u8a18\u61b6\u9ad4 (MRAM)\u300d\u3002\u81ea\u65cb\u5834\u6548\u96fb\u6676\u9ad4\u5c31\u50cf\u4e00\u7a2e\u5347\u7d1a\u7248\u7684\u96fb\u6676\u9ad4\uff0c\u5b83\u4e0d\u53ea\u958b\u95dc\u96fb\u6d41\uff0c\u9084\u80fd\u63a7\u5236\u96fb\u5b50\u7684\u300c\u65b9\u5411\u300d\uff0c\u5c31\u50cf\u4e00\u689d\u9ad8\u901f\u516c\u8def\u4e0a\uff0c\u8eca\u6d41\u9664\u4e86\u5feb\u6162\uff0c\u9084\u80fd\u5206\u6210\u5411\u5317\u8207\u5411\u5357\u7684\u8eca\u9053\uff0c\u80fd\u63a7\u5236\u96fb\u5b50\u65b9\u5411\u7684\u597d\u8655\uff0c\u662f\u80fd\u8b93\u8a0a\u865f\u66f4\u7a69\u5b9a\u3001\u80fd\u91cf\u640d\u5931\u66f4\u5c11\uff0c\u751a\u81f3\u80fd\u540c\u6642\u5728\u540c\u4e00\u689d\u5c0e\u7dda\u4e0a\u8655\u7406\u591a\u7a2e\u8a0a\u606f\uff0c\u4f7f\u96fb\u8166\u904b\u7b97\u66f4\u5feb\u3001\u529f\u8017\u66f4\u4f4e\uff1b\u78c1\u6027\u96a8\u6a5f\u5b58\u53d6\u8a18\u61b6\u9ad4\uff0c\u5247\u662f\u4e00\u7a2e\u80fd\u7528\u78c1\u6027\u65b9\u5411\u8a18\u9304\u8cc7\u6599\u7684\u8a18\u61b6\u9ad4\uff0c\u5c31\u7b97\u65b7\u96fb\u8cc7\u6599\u4e5f\u4e0d\u6703\u6d88\u5931\uff0c\u8b80\u5beb\u901f\u5ea6\u5feb\u3001\u8017\u80fd\u4f4e\uff0c\u88ab\u8996\u70ba\u672a\u4f86\u96fb\u8166\u8207\u624b\u6a5f\u5132\u5b58\u6280\u8853\u7684\u91cd\u8981\u65b9\u5411\u3002<\/p>\n

\"\"
\u57162\uff1a\uff08\u5de6\uff09\u50b3\u7d71\u96fb\u6676\u9ad4 (FET) \u8a2d\u8a08\uff0c\u900f\u904e\u9598\u6975 (Gate) \u8abf\u6574\u4e2d\u9593\u7684\u96fb\u5834\uff0c\u53ef\u4ee5\u63a7\u5236\u96fb\u5b50\u662f\u5426\u80fd\u901a\u904e\u4e2d\u9593\u5c64 (Channel)\uff1b\uff08\u53f3\uff09\u81ea\u65cb\u96fb\u6676\u9ad4 (Spin-FET) \u793a\u610f\u5716\uff0c\u900f\u904e\u9598\u6975(Gate)\u8abf\u6574\u4e2d\u9593\u7684\u96fb\u5834\uff0c\u53ef\u4ee5\u4f7f\u5177\u6709\u65b9\u5411\u7684\u81ea\u65cb\u5728\u4e2d\u9593\u5c64 (Channel) \u7522\u751f\u7ffb\u8f49\uff0c\u4f7f\u5f97\u5176\u4e2d\u4e00\u65b9\u5411\u7684\u81ea\u65cb\u5f97\u4ee5\u901a\u904e\uff0c\u5f62\u6210\u901a\u9053 (On)\uff0c\u53cd\u4e4b\uff0c\u82e5\u7121\u7ffb\u8f49\u50c5\u6709\u67d0\u4e00\u65b9\u5411\u7684\u81ea\u65cb\uff0c\u5247\u7121\u6cd5\u901a\u904e (Off)\uff5c\u4f86\u6e90\uff1a\u4f5c\u8005\u63d0\u4f9b<\/figcaption><\/figure>\n

 <\/p>\n

\u71b1\u8d77\u4f86\u5c31\u8b8a\u81c9\u7684VS2<\/sub><\/strong><\/span><\/h6>\n

\u9996\u5148\uff0c\u53ea\u8981\u4e00\u71b1\u8d77\u4f86\uff0cH-VS2<\/sub>\u5c31\u6703\u300c\u8f49\u63db\u9748\u9b42\u300d\uff0c\u56e0\u70baH-VS2<\/sub>\u7684\u539f\u5b50\u9593\u9375\u7d50\u80fd\u8f03\u4f4e\u3001\u4e14\u8207T-VS2<\/sub>\u7684\u7d50\u69cb\u80fd\u91cf\u5dee\u8ddd\u5c0f\uff0c\u4f7f\u5f97H-VS2<\/sub>\u5bb9\u6613\u5728\u71b1\u64fe\u52d5\u4e0b\u8f49\u8b8a\u70baT-VS2<\/sub>\uff0c\u4e5f\u5c31\u662f\u5728\u9ad8\u6eab\u6642VS2<\/sub>\u5f88\u5bb9\u6613\u53c8\u5f9e\u534a\u5c0e\u9ad4\u53c8\u8b8a\u56de\u91d1\u5c6c\u76f8\uff0c\u56e0\u6b64\u5982\u4f55\u8b93H-VS2<\/sub>\u4fdd\u6301\u7a69\u5b9a\uff0c\u4ecd\u662f\u61c9\u7528\u4e0a\u8981\u514b\u670d\u7684\u6311\u6230\u3002\u53e6\u4e00\u500b\u6311\u6230\u5247\u662f\u8207\u73fe\u6709\u534a\u5c0e\u9ad4\u5143\u4ef6\u7684\u6574\u5408\u56f0\u96e3\uff0c\u56e0\u70ba\u6839\u64da\u76ee\u524d\u7684\u6587\u737b\u5831\u5c0e\uff0cH-VS2<\/sub>\u7684\u88fd\u7a0b\u6eab\u5ea6\u5728700\u5ea6\u4ee5\u4e0a\uff0c\u800c\u4e3b\u6d41\u7684\u534a\u5c0e\u9ad4\u6750\u6599\u5728450\u5ea6\u4ee5\u4e0a\u5c31\u6703\u7522\u751f\u8b8a\u8cea\uff0c\u9032\u800c\u9020\u6210\u5143\u4ef6\u53d7\u640d\uff0c\u56e0\u6b64\u5982\u4f55\u4ee5\u66f4\u4f4e\u6eab\u7684\u65b9\u6cd5\u4f86\u65b9\u6cd5\u4f86\u88fd\u5099VS2<\/sub>\uff0c\u4ee5\u81f4\u65bc\u80fd\u6574\u5408\u9032\u73fe\u6709\u7684\u534a\u5c0e\u9ad4\u5143\u4ef6\u4e2d\uff0c\u4ecd\u662f\u79d1\u5b78\u5bb6\u6b63\u5728\u63a2\u7d22\u7684\u3002\u70ba\u4e86\u514b\u670d\u9019\u4e9b\u6311\u6230\uff0c\u79d1\u5b78\u5bb6\u6b63\u7a4d\u6975\u63a2\u7d22\u4f4e\u6eab\u5316\u5b78\u6c23\u76f8\u6c89\u7a4d (CVD) \u6cd5\u3001\u9e7d\u8f14\u52a9\u6210\u9577\u8207\u539f\u5b50\u5c64\u8f49\u63db\u7b56\u7565\uff0c\u4ee5\u7a69\u5b9aH\u76f8\u7684\u5f62\u6210\u3002<\/p>\n

T-VS2<\/sub>\u56e0\u5176\u91d1\u5c6c\u5c0e\u96fb\u6027\u6210\u70ba\u96fb\u5316\u5b78\u8207\u80fd\u6e90\u7684\u7a81\u7834\uff1b\u800cH-VS2<\/sub>\u7684\u534a\u5c0e\u9ad4\u7279\u6027\u5247\u4fc3\u9032\u4e86\u8cc7\u8a0a\u8207\u81ea\u65cb\u908f\u8f2f\u7684\u767c\u5c55\uff0c\u800cVS2<\/sub>\u5e36\u6709\u7684\u9435\u78c1\u7279\u6027\u53c8\u540c\u6642\u6253\u958b\u4e86\u81ea\u65cb\u8abf\u63a7\u7684\u984d\u5916\u53ef\u80fd\uff0c\u55ae\u55ae\u4e00\u5c64\u539f\u5b50\u5c64\uff0c\u56e0\u70ba\u5806\u7a4d\u7684\u65b9\u5f0f\u4e0d\u540c\uff0c\u5c31\u6709\u622a\u7136\u4e0d\u540c\u7684\u5b8f\u89c0\u7279\u6027\uff0c \u8b93\u6211\u5011\u770b\u5230\u7269\u8cea\u4e16\u754c\u7684\u7cbe\u5999\u8a2d\u8a08\uff0c\u6b63\u6240\u8b02\uff1a\u300c\u5dee\u4e00\u9ede\u5c31\u5dee\u5f88\u591a\uff01\u300d\u5728VS2<\/sub>\u7684\u96d9\u91cd\u9748\u9b42\u4e2d\uff0c\u6211\u5011\u4e0d\u59a8\u53ef\u4ee5\u8a66\u8457\u5929\u99ac\u884c\u7a7a\u7684\u60f3\u50cf\uff1a\u300c\u5982\u679cVS2<\/sub>\u7684\u91d1\u5c6c\u8207\u534a\u5c0e\u9ad4\u80fd\u88ab\u81ea\u7531\u5207\u63db\uff0c\u6703\u600e\u9ebc\u6a23\uff1f\u300d\u6216\u8a31\uff0c\u6750\u6599\u672c\u8eab\u5c31\u80fd\u6839\u64da\u74b0\u5883\u8207\u6307\u4ee4\u8b8a\u5316\u884c\u70ba\uff1a\u7576\u9700\u8981\u9ad8\u5c0e\u96fb\u6027\u6642\uff0c\u5b83\u5316\u8eab\u70ba\u91d1\u5c6c\uff1b\u7576\u9700\u8981\u908f\u8f2f\u904b\u7b97\u6216\u8a0a\u865f\u8655\u7406\u6642\uff0c\u5b83\u8f49\u70ba\u534a\u5c0e\u9ad4\u3002\u9019\u6a23\u7684\u6750\u6599\u80fd\u8b93\u88dd\u7f6e\u81ea\u6211\u5b78\u7fd2\u3001\u5373\u6642\u53cd\u61c9\uff0c\u96fb\u8166\u4e0d\u518d\u53ea\u662f\u57f7\u884c\u6307\u4ee4\uff0c\u800c\u662f\u80fd\u300e\u611f\u89ba\u300f\u80fd\u6e90\u6d41\u52d5\u3001\u8abf\u6574\u7b56\u7565\uff0c\u4e5f\u5c31\u662f\u4e00\u7a2e\u300c\u6703\u601d\u8003\u7684\u6750\u6599\u300d\uff0c\u91dd\u5c0dVS2<\/sub>\u7684\u96d9\u91cd\u9748\u9b42\uff0c\u4f60\u4e5f\u6709\u4ec0\u9ebc\u5927\u81bd\u7684\u60f3\u50cf\u55ce\uff1f<\/p>\n

 <\/p>\n

\n

\u53c3\u8003\u6587\u737b<\/strong><\/p>\n

    \n
  1. Patel, A. K., Borah, A. J., & Srivastava, A. (2023). Optimized APCVD method for synthesis of monolayer H-Phase VS2 crystals. Oxford Open Materials Science, 3(1), itad020.<\/li>\n
  2. Wang, X., Ma, L., Wang, C., Wang, J., Guo, J., Tang, R., ... & Zou, G. (2023). Seed Engineering toward Layer\u2010Regulated Growth of Magnetic Semiconductor VS2. Advanced Functional Materials, 33(19), 2213295.<\/li>\n
  3. Littlejohn, A. J., Li, Z., Lu, Z., Sun, X., Nawarat, P., Wang, Y., ... & Wang, G. C. (2019). Large metallic vanadium disulfide ultrathin flakes for spintronic circuits and quantum computing devices. ACS Applied Nano Materials, 2(6), 3684-3694.<\/li>\n
  4. Ma, Y., Dai, Y., Guo, M., Niu, C., Zhu, Y., & Huang, B. (2012). Evidence of the existence of magnetism in pristine VX2 monolayers (X= S, Se) and their strain-induced tunable magnetic properties. ACS nano, 6(2), 1695-1701.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

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