{"id":44914,"date":"2024-12-24T18:00:12","date_gmt":"2024-12-24T10:00:12","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=44914"},"modified":"2024-12-24T10:51:23","modified_gmt":"2024-12-24T02:51:23","slug":"%e9%82%81%e5%90%91%e9%9b%b6%e7%a2%b3%e6%9c%aa%e4%be%86%ef%bc%9a%e4%bb%a5%e4%ba%8c%e7%b6%ad%e6%9d%90%e6%96%99%e8%a7%a3%e9%8e%96%e6%b0%ab%e6%b0%a3%e8%83%bd%e6%ba%90","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=44914","title":{"rendered":"\u9081\u5411\u96f6\u78b3\u672a\u4f86\uff1a\u4ee5\u4e8c\u7dad\u6750\u6599\u89e3\u9396\u6c2b\u6c23\u80fd\u6e90"},"content":{"rendered":"

\u5168\u7403\u80fd\u6e90\u9700\u6c42\u6301\u7e8c\u6500\u5347\uff0c\u800c\u7531\u65bc\u80fd\u6e90\u6d88\u8017\u5e36\u4f86\u7684\u5927\u91cf\u78b3\u6392\u653e\uff0c\u6211\u5011\u7684\u74b0\u5883\u6b63\u9762\u81e8\u8457\u524d\u6240\u672a\u6709\u7684\u58d3\u529b\uff0c\u79d1\u5b78\u5bb6\u5011\u958b\u59cb\u5c0b\u6c42\u6e05\u6f54\u800c\u9ad8\u6548\u7684\u80fd\u6e90\u2014\u6c2b\u6c23\uff0c\u6bcf\u516c\u65a4\u6c2b\u6c23\u80fd\u91cb\u653e\u9ad8\u9054142\u5146\u7126\u8033\u7684\u80fd\u91cf\uff0c\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u50b3\u7d71\u6c7d\u6cb9\u50c5\u80fd\u63d0\u4f9b\u7d0434.2\u5146\u7126\u8033\uff0c\u4e0d\u53ea\u5982\u6b64\uff0c\u6c2b\u6c23\u71c3\u71d2\u5f8c\u53ea\u7522\u751f\u6c34\u84b8\u6c23\uff0c\u4e0d\u6703\u91cb\u653e\u4e8c\u6c27\u5316\u78b3\uff0c\u7136\u800c\uff0c\u76ee\u524d\u5927\u591a\u6578\u6c2b\u6c23\u7684\u751f\u7522\u4ecd\u4f9d\u8cf4\u5316\u77f3\u71c3\u6599\uff0c\u4f7f\u5f97\u5176\u88fd\u5099\u6210\u672c\u9ad8\u6602\uff0c\u4e26\u4f34\u96a8\u5927\u91cf\u7684\u6eab\u5ba4\u6c23\u9ad4\u6392\u653e\uff0c\u56e0\u6b64\uff0c\u5982\u4f55\u4ee5\u74b0\u4fdd\u3001\u53ef\u6301\u7e8c\u7684\u65b9\u5f0f\u751f\u7522\u6c2b\u6c23\u6210\u70ba\u7576\u52d9\u4e4b\u6025\uff0c\u5176\u4e2d\u6c2b\u6c23\u6790\u51fa\u53cd\u61c9 (HER) \u56e0\u70ba\u5176\u80fd\u76f4\u63a5\u5c07\u6c34\u5206\u89e3\u70ba\u6c2b\u6c23\u800c\u5099\u53d7\u77da\u76ee\uff0c\u5118\u7ba1\u5982\u6b64\uff0c\u50b3\u7d71\u7684HER\u5728\u9178\u6027\u74b0\u5883\u4e0b\u9032\u884c\uff0c\u4f7f\u5f97\u96fb\u6975\u6750\u6599\u6613\u88ab\u8150\u8755\uff0c\u5fc5\u9808\u63a1\u7528\u8cb4\u91cd\u91d1\u5c6c\u9251 (Pt)\uff0c\u4f7f\u5176\u6210\u672c\u4ecd\u5c45\u9ad8\u4e0d\u4e0b\uff0c\u4ee5\u81f4\u65bc\u7121\u6cd5\u5c07\u6b64\u65b9\u6cd5\u666e\u53ca\u5728\u80fd\u6e90\u767c\u5c55\u4e4b\u4e2d\uff0c\u8fd1\u5e74\u4f86\uff0c\u79d1\u5b78\u5bb6\u767c\u73fe\u4e8c\u7dad\u6750\u6599\u7684\u5f15\u5165\u6216\u8a31\u80fd\u6210\u70ba\u7a81\u7834\u53e3\uff0c\u9019\u4e9b\u6750\u6599\u56e0\u5176\u50c5\u5177\u55ae\u5c64\u539f\u5b50\u7684\u7d50\u69cb\uff0c\u4e0d\u53ea\u80fd\u63d0\u4f9b\u66f4\u591a\u7684\u6d3b\u6027\u4f4d\u9ede\uff0c\u9084\u80fd\u7531\u4e0d\u540c\u6750\u6599\u7684\u5806\u758a\u80fd\u4f7f\u96fb\u6975\u81ea\u5e36\u96fb\u5834\uff0c\u4fc3\u9032\u6c2b\u6c23\u751f\u6210\u53cd\u61c9\u3002<\/strong><\/span><\/p>\n

\u64b0\u6587\uff5c\u9ec3\u9f0e\u921e<\/strong><\/p>\n

\u8fd1\u5e74\u4f86\uff0c\u9ad8\u983b\u7684\u6975\u7aef\u6c23\u5019\u5f62\u6210\u88ab\u5927\u591a\u6578\u79d1\u5b78\u5bb6\u8a8d\u70ba\u8207\u6eab\u5ba4\u6c23\u9ad4\u7684\u904e\u5ea6\u589e\u52a0\u9ad8\u5ea6\u76f8\u95dc\uff0c\u56e0\u6b64\uff0c\u96a8\u8457\u79d1\u6280\u9032\u6b65\u548c\u5730\u7403\u74b0\u5883\u60e1\u5316\uff0c\u5c0d\u6e05\u6f54\u80fd\u6e90\u7684\u9700\u6c42\u8b8a\u5f97\u66f4\u52a0\u8feb\u5207\uff0c\u6c2b\u6c23\u56e0\u6b64\u6210\u70ba\u6c38\u7e8c\u80fd\u6e90\u7684\u7406\u60f3\u5019\u9078\u8005\u4e4b\u4e00\u3002\u5c31\u80fd\u91cf\u7522\u751f\u7684\u6548\u7387\u800c\u8a00\uff0c\u6bcf\u516c\u65a4\u6c2b\u6c23\u53ef\u7522\u751f142\u5146\u7126\u8033\u7684\u80fd\u91cf\uff0c\u9060\u9ad8\u65bc\u4e00\u516c\u5347\u6c7d\u6cb9\u50c5\u7522\u751f34.2\u5146\u7126\u8033\u7684\u6c34\u6e96\uff0c\u66f4\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u6c2b\u6c23\u71c3\u71d2\u53ea\u6703\u7522\u751f\u6c34\u84b8\u6c23\uff0c\u4e0d\u6703\u6392\u653e\u4e8c\u6c27\u5316\u78b3\u7b49\u6eab\u5ba4\u6c23\u9ad4\uff0c\u7136\u800c\uff0c\u7531\u65bc\u6c2b\u6c23\u7684\u7522\u751f\u6210\u672c\u4ecd\u7136\u9ad8\u6602\uff0c\u76ee\u524d\u5168\u7403\u5927\u90e8\u5206\u6c2b\u6c23\u751f\u7522\u4ecd\u4f9d\u8cf4\u5316\u77f3\u71c3\u6599\uff0c\u5728\u5c0b\u6c42\u7d93\u6fdf\u5229\u76ca\u7684\u9a45\u52d5\u4e0b\uff0c\u5927\u90e8\u5206\u7684\u5de5\u696d\u4ecd\u7136\u4f9d\u8cf4\u5316\u77f3\u80fd\u6e90\uff0c\u4e26\u6301\u7e8c\u6392\u653e\u8457\u6eab\u5ba4\u6c23\u9ad4\uff0c\u56e0\u6b64\uff0c\u79d1\u5b78\u5bb6\u5011\u6b63\u7a4d\u6975\u63a2\u7d22\u4ee5\u518d\u751f\u80fd\u6e90\u9a45\u52d5\u7684\u6c34\u96fb\u89e3\u88fd\u6c2b\u65b9\u6cd5\uff0c\u5176\u4e2d\u6c2b\u6c23\u6790\u51fa\u53cd\u61c9 (HER) \u6210\u70ba\u7814\u7a76\u91cd\u9ede\uff0c\u4ee5\u671f\u63d0\u5347\u88fd\u6c2b\u6548\u7387\u4e26\u964d\u4f4e\u6210\u672c\u3002<\/p>\n

\"\"
\u57161\uff1aHER\u53cd\u61c9\u793a\u610f\u5716\uff0c\u7070\u8272\u5713\u7403\u4ee3\u8868\u9251\u91d1\u5c6c\u539f\u5b50\uff0c\u7d05\u8272\u7403\u4ee3\u8868\u6c27\u539f\u5b50\uff0c\u7da0\u8272\u7403\u4ee3\u8868\u6c2b\u539f\u5b50\uff0c\u9251\u91d1\u5c6c\u4f5c\u70ba\u50ac\u5316\u96fb\u6975\uff0c\u80fd\u5c07\u6c34\u5206\u5b50\u5206\u89e3\u6210\u6c2b\u6c23\uff5c\u4f86\u6e90\uff1a\u4f5c\u8005\u63d0\u4f9b<\/figcaption><\/figure>\n

 <\/p>\n

\u6c2b\u6c23\u6790\u51fa\u53cd\u61c9 (Hydrogen Evolution Reaction, HER)<\/strong><\/span><\/h6>\n

\u6c2b\u6c23\u6790\u51fa\u53cd\u61c9 (HER) \u662f\u4e00\u7a2e\u96fb\u5316\u5b78\u53cd\u61c9\uff0c\u662f\u6c34\u5206\u89e3\u904e\u7a0b\u7684\u6838\u5fc3\u90e8\u5206\uff0cHER\u5728\u9670\u6975\u9032\u884c\uff0c\u5c07\u6c34\u5206\u89e3\u70ba\u6c2b\u6c23\u548c\u6c27\u6c23\uff0c\u5728\u9178\u6027\u689d\u4ef6\u4e0b\uff0cHER\u904e\u7a0b\u53ef\u5206\u70ba\u4e09\u500b\u6b65\u9a5f\uff0c\u9996\u5148\u662fVolmer\u6b65\u9a5f\uff0c\u5373\u5c07\u6c2b\u96e2\u5b50 (H\u2083O\u207a) \u548c\u96fb\u5b50\u8f49\u5316\u70ba\u5438\u9644\u6c2b (H*<\/sup>)\uff0c\u63a5\u4e0b\u4f86\u53ef\u80fd\u767c\u751fHeyrovsky\u6b65\u9a5f\uff0c\u9019\u662f\u5438\u9644\u6c2b\u8207\u6c2b\u96e2\u5b50\u53ca\u96fb\u5b50\u53cd\u61c9\u751f\u6210\u6c2b\u6c23\uff1b\u6216\u8005\u767c\u751fTafel\u6b65\u9a5f\uff0c\u5176\u4e2d\u5169\u500b\u5438\u9644\u6c2b\u539f\u5b50\u76f4\u63a5\u7d50\u5408\u751f\u6210\u6c2b\u6c23\uff0c\u5177\u9ad4\u5316\u5b78\u5f0f\u5982\u88681\u6240\u793a\u3002Heyrovsky\u6b65\u9a5f\u6216Tafel\u6b65\u9a5f\u9019\u5169\u689d\u8def\u5f91\u53d6\u6c7a\u65bc\u96fb\u89e3\u8cea\u74b0\u5883\u548c\u50ac\u5316\u5291\u8868\u9762\u7279\u6027\u7b49\u56e0\u7d20\u3002\u5f9eHER\u7684\u904e\u7a0b\u4e2d\u53ef\u4ee5\u770b\u898b\uff0c\u4e0d\u53ea\u80fd\u76f4\u63a5\u7522\u751f\u6c2b\u6c23\uff0c\u4e14\u53ea\u6703\u7522\u751f\u6c34\u7684\u526f\u7522\u7269\u3002<\/p>\n

\"\"<\/p>\n

\u5118\u7ba1HER\u662f\u4e00\u500b\u7c21\u55ae\u4e14\u76f4\u63a5\u7684\u88fd\u6c2b\u65b9\u6cd5\uff0c\u4f46\u50b3\u7d71HER\u50ac\u5316\u5291\u9762\u81e8\u4e0d\u5c11\u6311\u6230\u3002HER\u901a\u5e38\u63a1\u7528\u786b\u9178\u4f5c\u70ba\u96fb\u89e3\u8cea\uff0c\u5728\u9019\u6a23\u7684\u9178\u6027\u74b0\u5883\u4e2d\uff0cHER \u901a\u904e\u6c2b\u96e2\u5b50\uff08H\u207a \u6216 H\u2083O\u207a\uff09\u9084\u539f\u751f\u6210\u6c2b\u6c23\uff0c\u7136\u800c\uff0c\u9019\u4e9b\u9178\u6027\u96fb\u89e3\u8cea\u5bb9\u6613\u8150\u8755\u5927\u90e8\u5206\u7684\u96fb\u6975\u6750\u6599\uff0c\u56e0\u6b64\u591a\u6578\u90fd\u63a1\u7528\u6602\u8cb4\u91d1\u5c6c\u2014\u9251 (Pt) \u4f5c\u70ba\u7a69\u5b9a\u7684\u96fb\u6975\u8207\u50ac\u5316\u5291\uff0c\u4f7f\u5f97HER\u7684\u6210\u672c\u5927\u589e\uff0c\u82e5\u6539\u63a1\u6c2b\u6c27\u5316\u9240\u4f5c\u70ba\u96fb\u89e3\u8cea\uff0c\u4f7fHER\u5728\u9e7c\u6027\u7684\u74b0\u5883\u4e2d\u9032\u884c\uff0c\u80fd\u964d\u4f4e\u8150\u8755\u6027\uff0c\u63a1\u7528\u8f03\u4f4e\u6210\u672c\u7684\u91d1\u5c6c\u96fb\u6975\uff08\u5982\u9435\u548c\u93b3\uff09\uff0c\u7136\u800c\uff0c\u5728\u9019\u6a23\u7684\u9e7c\u6027\u74b0\u5883\u4e2d\uff0c\u6c2b\u96e2\u5b50\u6fc3\u5ea6\u8f03\u4f4e\uff0c\u7121\u6cd5\u63d0\u4f9b\u8db3\u5920\u7684\u6548\u7387\u7522\u751f\u6c2b\u6c23\uff0c\u8981\u80fd\u5920\u6eff\u8db3\u5de5\u696d\u7684\u9700\u6c42\u4ecd\u6709\u76f8\u7576\u5927\u7684\u6311\u6230\uff0c\u9762\u5c0d\u9019\u4e9b\u9650\u5236\uff0cHER\u662f\u5426\u9084\u6709\u641e\u982d\uff1f\u79d1\u5b78\u5bb6\u5011\u767c\u73fe\uff0c\u4e8c\u7dad\u6750\u6599\u53ef\u80fd\u6210\u70ba\u89e3\u6c7a\u9019\u4e9b\u554f\u984c\u7684\u7a81\u7834\u53e3\u3002<\/p>\n

 <\/p>\n

\u4e8c\u7dad\u6750\u6599\u51fa\u99ac\u89e3\u6551HER\uff01\uff1f<\/strong><\/span><\/h6>\n

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\"\"
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 <\/p>\n

\n

\u53c3\u8003\u6587\u737b<\/strong><\/p>\n

    \n
  1. Zhao, G., Rui, K., Dou, S. X., & Sun, W. (2018). Heterostructures for electrochemical hydrogen evolution reaction: a review. Advanced Functional Materials, 28(43), 1803291.<\/li>\n
  2. Mondal, A., & Vomiero, A. (2022). 2D transition metal dichalcogenides\u2010based electrocatalysts for hydrogen evolution reaction. Advanced Functional Materials, 32(52), 2208994.<\/li>\n
  3. Ghosh, R., Singh, M., Chang, L. W., Lin, H. I., Chen, Y. S., Muthu, J., ... & Chen, Y. F. (2022). Enhancing the photoelectrochemical hydrogen evolution reaction through nanoscrolling of two-dimensional material heterojunctions. ACS nano, 16(4), 5743-5751.<\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

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