

{"id":44592,"date":"2024-09-10T18:00:33","date_gmt":"2024-09-10T10:00:33","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=44592"},"modified":"2024-09-10T14:44:37","modified_gmt":"2024-09-10T06:44:37","slug":"%e7%9f%b3%e5%a2%a8%e7%83%af%e7%9a%84%e8%9d%b4%e8%9d%b6%e6%95%88%e6%87%89%e5%9c%a8%e9%87%8f%e5%ad%90%e7%a7%91%e6%8a%80%e4%b8%8a%e6%8e%80%e8%b5%b7%e9%a2%a8%e6%9a%b4","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=44592","title":{"rendered":"\u77f3\u58a8\u70ef\u7684\u8774\u8776\u6548\u61c9\u5728\u91cf\u5b50\u79d1\u6280\u4e0a\u6380\u8d77\u98a8\u66b4"},"content":{"rendered":"<p><span style=\"color: #000080;\"><strong>\u77f3\u58a8\u70ef\u662f\u4e00\u7a2e\u7531\u78b3\u539f\u5b50\u6392\u5217\u6210\u8702\u5de2\u72c0\u55ae\u5c64\u7d50\u69cb\u7684\u6750\u6599\uff0c\u81ea2004\u5e74\u88ab\u6210\u529f\u5206\u96e2\u5f8c\uff0c\u7531\u65bc\u5b83\u512a\u7570\u7684\u7269\u7406\u7279\u6027\uff0c\u5f15\u8d77\u4e86\u6750\u6599\u79d1\u5b78\u7684\u9769\u547d\uff0c\u79d1\u5b78\u5bb6\u7d1b\u7d1b\u6295\u5165\u77f3\u58a8\u70ef\u7684\u7814\u7a76\uff0c\u57282024\u5e742\u6708\uff0c\u65b0\u52a0\u5761\u570b\u7acb\u5927\u5b78\u7684\u7814\u7a76\u5718\u968a\u5728\u300a\u81ea\u7136\u5316\u5b78\u300b(<em>Nature Chemistry<\/em>) \u4e0a\u767c\u8868\u4e86\u4e00\u9805\u9769\u547d\u6027\u6210\u679c\uff0c\u4ed6\u5011\u900f\u904e\u5c07\u77f3\u58a8\u70ef\u4fee\u98fe\u6210\u8774\u8776\u5f62\u72c0\uff0c\u4f7f\u5176\u540c\u6642\u5177\u6709\u9435\u78c1\u6027\u548c\u53cd\u9435\u78c1\u6027\uff0c\u800c\u7576\u4e2d\u7684\u96fb\u5b50\u5247\u5177\u6709\u9ad8\u5ea6\u7684\u91cf\u5b50\u81ea\u65cb\u7cfe\u7e8f\uff0c\u9019\u4e00\u767c\u73fe\u88ab\u8a8d\u70ba\u662f\u91cf\u5b50\u79d1\u6280\u767c\u5c55\u7684\u91cd\u5927\u7a81\u7834\uff0c\u6709\u671b\u6210\u70ba\u65b0\u4e00\u4ee3\u91cf\u5b50\u6750\u6599\u7684\u57fa\u790e\uff0c\u63a8\u52d5\u91cf\u5b50\u8a08\u7b97\u548c\u901a\u4fe1\u6280\u8853\u7684\u9032\u6b65\u3002<\/strong><\/span><\/p>\n<p><strong>\u64b0\u6587\uff5c\u9ec3\u9f0e\u921e<\/strong><\/p>\n<p>\u77f3\u58a8\u70ef\u662f\u4e00\u7a2e\u7531\u78b3\u539f\u5b50\u6392\u5217\u6210\u8702\u5de2\u72c0\u55ae\u5c64\u7d50\u69cb\u7684\u6750\u6599\uff0c\u81ea2004\u5e74\u88ab\u6210\u529f\u5206\u96e2\u51fa\u4f86\u5f8c\uff0c\u56e0\u7368\u7279\u7684\u7269\u7406\u6027\u8cea\uff0c\u5305\u62ec\u6975\u9ad8\u7684\u5c0e\u96fb\u6027\u3001\u6a5f\u68b0\u5f37\u5ea6\u548c\u67d4\u97cc\u6027\uff0c\u4f7f\u5176\u6210\u70ba\u5404\u7a2e\u96fb\u5b50\u5de5\u7a0b\u61c9\u7528\u7684\u7406\u60f3\u6750\u6599\uff0c\u5f15\u8d77\u4e86\u6750\u6599\u79d1\u5b78\u7684\u9769\u547d\uff0c\u66f4\u591a\u95dc\u65bc\u77f3\u58a8\u70ef\u7684\u4ecb\u7d39\u53ef\u4ee5\u53c3\u8003\u300a<a href=\"https:\/\/case.ntu.edu.tw\/blog\/?p=41233\">\u5e02\u9762\u4e0a\u7684\u77f3\u58a8\u70ef\u7522\u54c1\uff0c\u771f\u7684\u6709\u90a3\u9ebc\u53b2\u5bb3\u55ce\uff1f<\/a>\u300b\u3002\u4e0d\u53ea\u77f3\u58a8\u70ef\u672c\u8eab\u7684\u7279\u6b8a\u7269\u7406\u6027\u8cea\uff0c\u7531\u65bc\u77f3\u58a8\u70ef\u7684\u7d50\u69cb\u7c21\u55ae\uff0c\u4e5f\u63d0\u4f9b\u4e86\u4e00\u500b\u5e73\u81fa\u4f7f\u79d1\u5b78\u5bb6\u80fd\u5920\u900f\u904e\u5c0d\u6750\u6599\u7684\u300c\u4fee\u98fe\u300d\uff0c\u4f7f\u77f3\u58a8\u70ef\u7522\u751f\u5176\u4ed6\u7684\u529f\u80fd\u3002\u57282024\u5e742\u6708\uff0c\u65b0\u52a0\u5761\u570b\u7acb\u5927\u5b78 (National University of Singapore, NUS) \u5728\u300a\u81ea\u7136\u5316\u5b78\u300b(Nature Chemistry) \u4e0a\u767c\u8868\u4e86\u4e00\u9805\u7a81\u7834\u6027\u7684\u7814\u7a76\u6210\u679c\uff0c\u4ed6\u5011\u5c07\u77f3\u58a8\u70ef\u4fee\u98fe\u6210\u300c\u8774\u8776\u5f62\u72c0\u300d\uff0c\u7adf\u7136\u53ef\u4ee5\u4f7f\u77f3\u58a8\u70ef\u540c\u6642\u7522\u751f\u9435\u78c1\u6027\u3001\u53cd\u9435\u78c1\u6027\uff0c\u4e14\u6750\u6599\u4e4b\u4e2d\u7684\u96fb\u5b50\u5177\u6709\u9ad8\u5ea6\u7684\u91cf\u5b50\u81ea\u65cb\u7cfe\u7e8f\uff0c\u88ab\u671f\u5f85\u80fd\u6210\u70ba\u91cf\u5b50\u79d1\u6280\u767c\u5c55\u7684\u9769\u547d\u6027\u6750\u6599\u3002<\/p>\n<figure id=\"attachment_44595\" aria-describedby=\"caption-attachment-44595\" style=\"width: 400px\" class=\"wp-caption aligncenter\"><img fetchpriority=\"high\" decoding=\"async\" class=\"wp-image-44595\" src=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57161-1-772x1024.jpg\" alt=\"\" width=\"400\" height=\"531\" srcset=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57161-1-772x1024.jpg 772w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57161-1-226x300.jpg 226w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57161-1-768x1019.jpg 768w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57161-1.jpg 1158w\" sizes=\"(max-width: 400px) 100vw, 400px\" \/><figcaption id=\"caption-attachment-44595\" class=\"wp-caption-text\">\u57161\uff1a\u8774\u8776\u578b\u77f3\u58a8\u70ef\u793a\u610f\u5716\uff0c\u900f\u904e\u6b64\u7279\u6b8a\u7d50\u69cb\uff0c\u8655\u5728\u77f3\u58a8\u70ef\u908a\u7de3\u7684\u96fb\u5b50\u80fd\u5c55\u73fe\u51fa\u81ea\u65cb\u7279\u6027\uff0c\u4f7f\u6574\u500b\u7cfb\u7d71\u5e36\u6709\u9435\u78c1\u6027\u53ca\u53cd\u9435\u78c1\u6027\uff0c\u4e14\u96fb\u5b50\u4e4b\u9593\u80fd\u7522\u751f\u91cf\u5b50\u7cfe\u7e8f\uff5c\u4f86\u6e90\uff1aNational University of Singappore<\/figcaption><\/figure>\n<p>&nbsp;<\/p>\n<h6><span style=\"color: #008000;\"><strong>\u5177\u6709\u78c1\u6027\u7684\u8774\u8776\u578b\u77f3\u58a8\u70ef<\/strong><\/span><\/h6>\n<p>\u50b3\u7d71\u78c1\u6027\u6750\u6599\u4e3b\u8981\u4f9d\u8cf4\u65bc\u91cd\u91d1\u5c6c\u4e2d\u7684d\u6216f\u8ecc\u9053\u96fb\u5b50\u4f86\u5be6\u73fe\u78c1\u6027\uff0c\u5982\u5e38\u898b\u7684\u9435\u3001\u9237\u53ca\u9477\uff0c\u7136\u800c\uff0c\u9019\u4e9b\u6750\u6599\u5728\u5be6\u73fe\u91cf\u5b50\u8a08\u7b97\u6642\u5b58\u5728\u8457\u4e00\u4e9b\u9650\u5236\uff0c\u9996\u5148\uff0cd\u6216f\u8ecc\u9053\u4e0a\u5177\u6709\u8f03\u591a\u7684\u96fb\u5b50\uff0c\u9019\u4e9b\u96fb\u5b50\u4e4b\u9593\u7684\u4ea4\u4e92\u4f5c\u7528\u5c07\u4f7f\u5f97\u96fb\u5b50\u81ea\u65cb\u72c0\u614b\u88ab\u5e72\u64fe\uff0c\u4f7f\u5f97\u91cf\u5b50\u72c0\u614b\u5728\u77ed\u6642\u9593\u5167\u5c31\u6d88\u5931\u4e86\uff0c\u53e6\u5916\uff0c\u91cd\u91d1\u5c6c\u7684\u88fd\u5099\u548c\u52a0\u5de5\u6210\u672c\u8f03\u9ad8\uff0c\u4e14\u5c0d\u74b0\u5883\u4e5f\u6709\u4e00\u5b9a\u7684\u6c59\u67d3\uff0c\u56e0\u6b64\u57fa\u65bc\u529f\u80fd\u8207\u4fdd\u8b77\u74b0\u5883\u7684\u8003\u91cf\uff0c\u79d1\u5b78\u5bb6\u5e0c\u671b\u80fd\u627e\u5230\u66f4\u512a\u7570\u4e14\u74b0\u4fdd\u7684\u6750\u6599\uff0c\u800c\u8774\u8776\u5f62\u77f3\u58a8\u70ef\u53ef\u80fd\u5c31\u662f\u79d1\u5b78\u5bb6\u8981\u5c0b\u627e\u7684\u89e3\u65b9\uff0c\u8774\u8776\u578b\u77f3\u58a8\u70ef\u5b58\u5728\u8457\u56db\u500b\u672a\u6210\u5c0d\u7684\u96fb\u5b50\uff0c\u56e0\u8457\u8774\u8776\u578b\u7684\u7279\u6b8a\u7d50\u69cb\uff0c\u9019\u4e9b\u96fb\u5b50\u7522\u751f\u4e86\u300c\u62c9\u626f\u300d\u548c\u300c\u63a8\u64e0\u300d\uff0c\u9019\u6a23\u7684\u76f8\u4e92\u4f5c\u7528\u7adf\u8b93\u96fb\u5b50\u7522\u751f\u4e86\u7279\u5b9a\u65b9\u5411\u7684\u6392\u5217\uff0c\u4f7f\u77f3\u58a8\u70ef\u7522\u751f\u4e86\u7368\u7279\u7684\u78c1\u6027\u3002\u82e5\u628a\u4eba\u6bd4\u55bb\u6210\u96fb\u5b50\u7684\u8a71\uff0c\u5c31\u50cf\u662f\u4e00\u7fa4\u4eba\u64e0\u9032\u53bb\u96fb\u68af\u88e1\u9762\u6642\uff0c\u5728\u9019\u72f9\u7a84\u7684\u7a7a\u9593\u4e2d\uff0c\u5927\u5bb6\u5728\u88e1\u9762\u6703\u627e\u5c0b\u4e00\u500b\u7279\u5b9a\u7684\u65b9\u5411\uff0c\u597d\u632a\u51fa\u66f4\u591a\u7684\u7a7a\u9593\uff0c\u4e5f\u8b93\u81ea\u5df1\u5f85\u7684\u8212\u9069\uff0c\u4f46\u82e5\u4e00\u500b\u4eba\u642d\u96fb\u68af\u6642\uff0c\u53ef\u80fd\u5ffd\u800c\u770b\u93e1\u5b50\u6574\u7406\u5100\u5bb9\uff0c\u5ffd\u800c\u770b\u6a13\u5c64\u4ecb\u7d39\uff0c\u8f49\u4f86\u8f49\u53bb\u7684\u6c92\u6709\u65b9\u5411\u3002\u4e0d\u50c5\u5982\u6b64\uff0c\u9019\u4e9b\u5177\u6709\u81ea\u65cb\u7684\u96fb\u5b50\u5f7c\u6b64\u9084\u5b58\u5728\u8457\u5f37\u70c8\u7684\u7cfe\u7e8f\u73fe\u8c61\uff0c\u9019\u6b63\u662f\u5728\u91cf\u5b50\u79d1\u6280\u767c\u5c55\u7684\u57fa\u790e\u4e4b\u4e00\u3002\u5728\u6c38\u7e8c\u74b0\u5883\u7684\u89c0\u9ede\u4e0a\uff0c\u7531\u65bc\u77f3\u58a8\u70ef\u50c5\u7531\u78b3\u539f\u5b50\u7d44\u6210\uff0c\u78b3\u539f\u5b50\u4e0d\u50cf\u91d1\u5c6c\u6703\u5c0d\u74b0\u5883\u9020\u6210\u6c59\u67d3\uff0c\u7562\u7adf\u5730\u7403\u4e0a\u7684\u751f\u7269\u672c\u8eab\u5c31\u662f\u78b3\u57fa\u7d44\u6210\u7684\u554a\uff01<\/p>\n<figure id=\"attachment_44593\" aria-describedby=\"caption-attachment-44593\" style=\"width: 600px\" class=\"wp-caption aligncenter\"><img decoding=\"async\" class=\"wp-image-44593\" src=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57162-1024x576.png\" alt=\"\" width=\"600\" height=\"338\" srcset=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57162-1024x576.png 1024w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57162-300x169.png 300w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57162-768x432.png 768w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57162-1536x864.png 1536w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57162.png 1920w\" sizes=\"(max-width: 600px) 100vw, 600px\" \/><figcaption id=\"caption-attachment-44593\" class=\"wp-caption-text\">\u57162\uff1a\u5169\u500bp\u8ecc\u57df\u5f62\u6210\u4e00\u500b\u03c0\u9375\uff0c\u5c0d\u61c9\u7684\u8ecc\u57df\u7a31\u70ba\u03c0\u8ecc\u57df\uff5c\u4f86\u6e90\uff1aWikimedia Commons<\/figcaption><\/figure>\n<p>&nbsp;<\/p>\n<h6><span style=\"color: #008000;\"><strong>\u8774\u8776\u578b\u77f3\u58a8\u70ef\u80cc\u5f8c\u7684\u7269\u7406\u6a5f\u5236<\/strong><\/span><\/h6>\n<p>\u8774\u8776\u578b\u77f3\u58a8\u70ef\u4e4b\u6240\u4ee5\u80fd\u7522\u751f\u78c1\u6027\uff0c\u80cc\u5f8c\u6709\u8457\u8907\u96dc\u7684\u6a5f\u5236\uff0c\u4e3b\u8981\u4f86\u81ea\u5169\u500b\u91cd\u8981\u7684\u7269\u7406\u6a21\u578b\uff0c\u7b2c\u4e00\u662f\u300c\u55ae\u5360\u5206\u5b50\u8ecc\u9053\u300d(Singly Occupied Molecular Orbital)\uff0c\u53e6\u4e00\u5247\u662f\u300c\u62d3\u6a38\u632b\u6298\u300d\uff08Topological Frustration\uff09\u3002\u55ae\u5360\u5206\u5b50\u8ecc\u9053\u662f\u4e00\u7a2e\u5206\u5b50\u8ecc\u9053\u7406\u8ad6\uff0c\u610f\u601d\u662f\u5728\u4e00\u500b\u80fd\u91cf\u6700\u4f4e\u7684\u8ecc\u9053\u4e2d\uff0c\u53ea\u6709\u4e00\u500b\u672a\u914d\u5c0d\u7684\u96fb\u5b50\u5b58\u5728\uff0c\u800c\u9019\u500b\u672a\u914d\u5c0d\u7684\u96fb\u5b50\u80fd\u70ba\u6750\u6599\u5e36\u4f86\u78c1\u6027\uff0c\u540c\u6642\uff0c\u9019\u4e00\u500b\u300c\u5b64\u55ae\u300d\u7684\u96fb\u5b50\uff0c\u5177\u6709\u9ad8\u5ea6\u7684\u53cd\u61c9\u6d3b\u6027\uff0c\u5bb9\u6613\u53c3\u8207\u5176\u4ed6\u7684\u5316\u5b78\u53cd\u61c9\uff0c\u9019\u96fb\u5b50\u5c31\u50cf\u662f\u5728\u6d3e\u5c0d\u4e2d\u843d\u55ae\u7684\u5e25\u54e5\u6216\u7f8e\u5973\uff0c\u5bb9\u6613\u5f15\u4eba\u6ce8\u76ee\u5462\uff01\u4e8b\u5be6\u4e0a\uff0c\u9019\u6a23\u7684\u72c0\u614b\u4f86\u81ea\u65bc\u66f4\u5e95\u5c64\u7684\u7269\u7406\u6a5f\u5236\uff0c\u4e5f\u5c31\u662f\u300c\u62d3\u6a38\u632b\u6298\u300d\uff0c\u5728\u6750\u6599\u7522\u751f\u7279\u6b8a\u7684\u5e7e\u4f55\u7d50\u69cb\u6642\uff0c\u81ea\u65cb\u7cfb\u7d71\u6703\u7522\u751f\u7af6\u722d\u6027\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u50cf\u662f\u5728\u4e00\u500b\u7b49\u908a\u4e09\u89d2\u5f62\u7684\u6676\u683c\u4e2d\uff0c\u8655\u5728\u4e09\u500b\u9802\u9ede\u4e0a\u7684\u81ea\u65cb\u90fd\u5e0c\u671b\u8207\u9130\u8fd1\u81ea\u65cb\u53cd\u5e73\u884c\u5c0d\u9f4a\uff0c\u4f46\u9019\u662f\u4e0d\u53ef\u80fd\u7684\u4e8b\u60c5\uff0c\u56e0\u6b64\u7121\u6cd5\u6eff\u8db3\u6240\u6709\u81ea\u65cb\u7684\u9700\u6c42\uff0c\u5c0e\u81f4\u6240\u6709\u81ea\u65cb\u7522\u751f\u4e00\u7a2e\u300c\u9000\u5316\u300d\uff0c\u5927\u5bb6\u90fd\u8dd1\u56de\u53bb\u4e86\u300c\u57fa\u614b\u300d\uff0c\u4e5f\u5c31\u662f\u300c\u55ae\u5360\u5206\u5b50\u8ecc\u9053\u300d\u4e4b\u4e2d\uff0c\u56e0\u800c\u7522\u751f\u4e86\u8907\u96dc\u7684\u78c1\u6027\u884c\u70ba\u3002\u56de\u5230\u525b\u525b\u6d3e\u5c0d\u7684\u6545\u4e8b\uff0c\u7576\u4e00\u500b\u5e25\u54e5\u53ea\u80fd\u8207\u4e00\u500b\u7f8e\u5973\u7d04\u6703\uff0c\u5e25\u54e5\u537b\u540c\u6642\u53bb\u642d\u8a15\u5169\u4f4d\u7f8e\u5973\u6642\uff0c\u9019\u4f4d\u5e25\u54e5\u4e0d\u5c08\u60c5\u7684\u884c\u70ba\u5c07\u5c0e\u81f4\u4e09\u4eba\u50f5\u6301\u4e0d\u4e0b\uff0c\u4e09\u4eba\u53ea\u597d\u56de\u5230\u5404\u81ea\u7684\u300c\u57fa\u614b\u300d\u5ea7\u4f4d\uff0c\u4e09\u4eba\u540c\u6642\u611f\u5230\u300c\u632b\u6298\u300d\uff0c\u537b\u53c8\u6563\u767c\u8457\u300c\u78c1\u6027\u9b45\u529b\u300d\uff0c\u8b93\u6574\u500b\u6d3e\u5c0d\u7522\u751f\u4e86\u4e00\u7a2e\u7279\u5225\u7684\u6c1b\u570d\uff0c\u5c31\u50cf\u8b93\u6574\u500b\u6750\u6599\u7cfb\u7d71\u7522\u751f\u5947\u7570\u7684\u91cf\u5b50\u73fe\u8c61\u4e00\u6a23\u3002\u4e0d\u50c5\u5982\u6b64\uff0c\u56de\u5230\u5ea7\u4f4d\u7684\u4e09\u4eba\u4ecd\u5e38\u5e38\u9059\u671b\u8457\u5f7c\u6b64\uff0c\u9084\u6703\u7522\u751f\u300c\u91cf\u5b50\u7cfe\u7e8f\u300d\uff0c\u7576\u5176\u4e2d\u4e00\u65b9\u6709\u4e9b\u52d5\u4f5c\u6642\uff0c\u53e6\u4e00\u65b9\u4e5f\u6703\u8ddf\u8457\u6709\u53cd\u61c9\uff0c\u6240\u4ee5\uff0c\u62d3\u64b2\u632b\u6298\u7684\u5b58\u5728\u5c07\u5c0e\u81f4\u6750\u6599\u7cfb\u7d71\u7522\u751f\u8a31\u591a\u65b0\u7a4e\u7684\u91cf\u5b50\u73fe\u8c61\uff0c\u662f\u79d1\u5b78\u5bb6\u4e00\u76f4\u5728\u7814\u7a76\uff0c\u4e5f\u671f\u5f85\u80fd\u5920\u61c9\u7528\u5728\u91cf\u5b50\u79d1\u6280\u4e0a\u7684\u7269\u7406\u6a5f\u5236\u3002<\/p>\n<figure id=\"attachment_44594\" aria-describedby=\"caption-attachment-44594\" style=\"width: 387px\" class=\"wp-caption aligncenter\"><img decoding=\"async\" class=\"wp-image-44594 size-full\" src=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57163-1.jpg\" alt=\"\" width=\"387\" height=\"258\" srcset=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57163-1.jpg 387w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57163-1-300x200.jpg 300w\" sizes=\"(max-width: 387px) 100vw, 387px\" \/><figcaption id=\"caption-attachment-44594\" class=\"wp-caption-text\">\u57163\uff1a\u7db2\u8def\u77e5\u540d\u8ff7\u56e0\uff0c\u62d3\u6a38\u632b\u6298\u5c31\u50cf\u662f\u4e09\u500b\u4eba\u4e0d\u80fd\u4e00\u8d77\u7d04\u6703\uff0c\u82e5\u662f\u50cf\u662f\u4e2d\u9593\u7684\u7537\u5b50\u5206\u5fc3\u7684\u8a71\uff0c\u6700\u7d42\u5927\u5bb6\u90fd\u5c07\u6210\u70ba\u4e00\u500b\u4eba\uff0c\u800c\u5728\u7cfb\u7d71\u7d42\u5c07\u6210\u70ba\u4e09\u500b\u55ae\u7368\u7684\u96fb\u5b50\uff0c\u4e14\u5f62\u6210\u8907\u96dc\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u7522\u751f\u7279\u6b8a\u7684\u91cf\u5b50\u73fe\u8c61\uff5c\u4f86\u6e90\uff1aWikimedia Commons<\/figcaption><\/figure>\n<p>\u5f9e\u77f3\u58a8\u70ef\u7b2c\u4e00\u6b21\u88ab\u5206\u96e2\u51fa\u4f86\u81f3\u4eca\u5df2\u670920\u5e74\u7684\u6642\u9593\uff0c\u5f9e\u5b83\u7522\u751f\u7684\u7269\u7406\u6027\u8cea\u4e00\u6b21\u53c8\u4e00\u6b21\u7684\u9a5a\u8277\u8457\u79d1\u5b78\u5bb6\uff0c\u4e5f\u4f7f\u5f97\u8a31\u591a\u79d1\u5b78\u5bb6\u722d\u76f8\u7684\u6295\u5165\u7814\u7a76\uff0c\u76f4\u5230\u8fd1\u5e74\u5b83\u7684\u8d85\u5c0e\u6027\u3001\u78c1\u6027\u4ee5\u53ca\u5176\u4ed6\u91cf\u5b50\u73fe\u8c61\u4e0d\u65b7\u5730\u88ab\u6316\u6398\u51fa\u4f86\uff0c\u9019\u7c21\u55ae\u7684\u78b3\u539f\u5b50\u7d50\u69cb\uff0c\u5230\u5e95\u9084\u80fd\u88ab\u79d1\u5b78\u5bb6\u73a9\u51fa\u4ec0\u9ebc\u82b1\u6a23\uff0c\u53c8\u80fd\u5982\u4f55\u7684\u5275\u65b0\u4eba\u985e\u76ee\u524d\u7684\u79d1\u6280\uff0c\u8b93\u6211\u5011\u62ed\u76ee\u4ee5\u5f85\u3002<\/p>\n<p>&nbsp;<\/p>\n<hr \/>\n<p><strong>\u53c3\u8003\u6587\u737b<\/strong><\/p>\n<ol>\n<li>Song, S., Pinar Sol\u00e9, A., Mat\u011bj, A., Li, G., Stetsovych, O., Soler, D., ... &amp; Lu, J. (2024). Highly entangled polyradical nanographene with coexisting strong correlation and topological frustration. Nature Chemistry, 1-7.<\/li>\n<li>Jemmis, E. D., Pathak, B., King, R. B., &amp; Schaefer Iii, H. F. (2006). Bond length and bond multiplicity: \u03c3-bond prevents short \u03c0-bonds. Chemical communications, (20), 2164-2166.<\/li>\n<li>Wang, W. L., Yazyev, O. V., Meng, S., &amp; Kaxiras, E. (2009). Topological frustration in graphene nanoflakes: magnetic order and spin logic devices. Physical review letters, 102(15), 157201.<\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n<hr \/>\n<p><strong>\u273e<\/strong>\u5ef6\u4f38\u95b1\u8b80\uff1a\u300a<a href=\"https:\/\/case.ntu.edu.tw\/blog\/?p=43125\" target=\"_blank\" rel=\"noopener\">\u65b0\u6642\u4ee3\u7684\u6ffe\u7db2\uff1a\u5f9e\u75c5\u6bd2\u5230\u6d77\u6c34\u90fd\u80fd\u904e\u6ffe\u7684\u77f3\u58a8\u70ef<\/a>\u300b\u300a<a href=\"http:\/\/case.ntu.edu.tw\/blog\/?p=42825\">\u77f3\u58a8\u70ef\u8207\u5b83\u7684\u597d\u670b\u53cb\u2014\u2014\u516d\u89d2\u787c\u6c2e<\/a>\u300b\u3001\u300a<a href=\"http:\/\/case.ntu.edu.tw\/blog\/?p=41233\">\u5e02\u9762\u4e0a\u7684\u77f3\u58a8\u70ef\u7522\u54c1\uff0c\u771f\u7684\u6709\u90a3\u9ebc\u53b2\u5bb3\u55ce\uff1f<\/a>\u300b\u3001\u300a<a href=\"http:\/\/case.ntu.edu.tw\/blog\/?p=42952\">\u8f49\u89d2\u96fb\u5b50\u5b78\uff1a\u8d85\u5c0e\u8207\u7d55\u7de3\u81ea\u7531\u5207\u63db\u7684\u8f49\u626d<\/a>\u300b<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u77f3\u58a8\u70ef\u662f\u4e00\u7a2e\u7531\u78b3\u539f\u5b50\u6392\u5217\u6210\u8702\u5de2\u72c0\u55ae\u5c64\u7d50\u69cb\u7684\u6750\u6599\uff0c\u81ea2004\u5e74\u88ab\u6210\u529f\u5206\u96e2\u5f8c\uff0c\u7531\u65bc\u5b83\u512a\u7570\u7684\u7269\u7406\u7279\u6027\uff0c\u5f15\u8d77\u4e86\u6750\u6599\u79d1\u5b78\u7684\u9769\u547d\uff0c\u79d1\u5b78\u5bb6\u7d1b\u7d1b\u6295\u5165\u77f3\u58a8\u70ef\u7684\u7814\u7a76\uff0c\u57282024\u5e742\u6708\uff0c\u65b0\u52a0\u5761\u570b\u7acb\u5927\u5b78\u7684\u7814\u7a76\u5718\u968a\u5728\u300a\u81ea\u7136\u5316\u5b78\u300b(Nature Chemistry) \u4e0a\u767c\u8868\u4e86\u4e00\u9805\u9769\u547d\u6027\u6210\u679c\uff0c\u4ed6\u5011\u900f\u904e\u5c07\u77f3\u58a8\u70ef\u4fee\u98fe\u6210\u8774\u8776\u5f62\u72c0\uff0c\u4f7f\u5176\u540c\u6642\u5177\u6709\u9435\u78c1\u6027\u548c\u53cd\u9435\u78c1\u6027\uff0c\u800c\u7576\u4e2d\u7684\u96fb\u5b50\u5247\u5177\u6709\u9ad8\u5ea6\u7684\u91cf\u5b50\u81ea\u65cb\u7cfe\u7e8f\uff0c\u9019\u4e00\u767c\u73fe\u88ab\u8a8d\u70ba\u662f\u91cf\u5b50\u79d1\u6280\u767c\u5c55\u7684\u91cd\u5927\u7a81\u7834\uff0c\u6709\u671b\u6210\u70ba\u65b0\u4e00\u4ee3\u91cf\u5b50\u6750\u6599\u7684\u57fa\u790e\uff0c\u63a8\u52d5\u91cf\u5b50\u8a08\u7b97\u548c\u901a\u4fe1\u6280\u8853\u7684\u9032\u6b65\u3002<\/p>\n","protected":false},"author":20,"featured_media":44595,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1023,3293,39],"tags":[504,7213,6782],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/09\/\u57161-1.jpg","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/44592"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=44592"}],"version-history":[{"count":1,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/44592\/revisions"}],"predecessor-version":[{"id":44596,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/44592\/revisions\/44596"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/44595"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=44592"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=44592"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=44592"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}