{"id":44362,"date":"2024-07-16T18:00:21","date_gmt":"2024-07-16T10:00:21","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=44362"},"modified":"2024-07-16T10:26:35","modified_gmt":"2024-07-16T02:26:35","slug":"%e9%bb%83%e9%87%91%e6%99%82%e4%bb%a3%e5%b0%b1%e8%a6%81%e4%be%86%e4%ba%86%e5%97%8e%ef%bc%9f%e4%b8%96%e7%95%8c%e4%b8%8a%e6%9c%80%e8%96%84%e7%9a%84%e9%bb%83%e9%87%91%e6%9b%9d%e5%85%89%e4%ba%86%ef%bc%81","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=44362","title":{"rendered":"\u9ec3\u91d1\u6642\u4ee3\u5c31\u8981\u4f86\u4e86\u55ce\uff1f\u4e16\u754c\u4e0a\u6700\u8584\u7684\u9ec3\u91d1\u66dd\u5149\u4e86\uff01"},"content":{"rendered":"

\u91d1\u7b94\u662f\u4e00\u7a2e\u6975\u8584\u7684\u9ec3\u91d1\u8584\u7247\uff0c\u5e38\u7528\u65bc\u88dd\u98fe\u751c\u9ede\u4ee5\u63d0\u5347\u5962\u83ef\u611f\uff0c\u5176\u539a\u5ea6\u7d04\u70ba10-7<\/sup>\u7c73\u3002\u96a8\u8457\u79d1\u6280\u9032\u6b65\uff0c\u6750\u6599\u79d1\u5b78\u5bb6\u5408\u6210\u4e86\u50c5\u4e00\u539f\u5b50\u5c64\u539a\u7684\u91d1\u7b94\u7247\uff0c\u7a31\u70baGoldene\uff0c\u9019\u662f\u4e00\u7a2e\u4e8c\u7dad\u6750\u6599\uff0c\u53c8\u88ab\u7a31\u70ba\u77f3\u58a8\u7a00\u7684\u91d1\u9ec3\u8868\u5144\u5f1f\u3002Goldene\u662f\u4e00\u7a2e\u534a\u5c0e\u9ad4\u6750\u6599\uff0c\u80fd\u5e6b\u52a9\u7cbe\u78ba\u63a7\u5236\u96fb\u6d41\uff0c\u6eff\u8db3\u5948\u7c73\u96fb\u5b50\u5143\u4ef6\u9700\u6c42\uff0c\u800c\u4e14\u5176\u5de8\u5927\u7684\u8868\u9762\u7a4d\u4f7f\u5176\u6210\u70ba\u512a\u7570\u7684\u50ac\u5316\u5291\uff0c\u53ef\u964d\u4f4e\u5316\u5b78\u53cd\u61c9\u6d3b\u5316\u80fd\u3002\u745e\u5178\u6797\u96ea\u5e73\u5927\u5b78\u767c\u5c55\u51fa\u9632\u6b62Goldene\u6372\u66f2\u7684\u65b9\u6cd5\uff0c\u4f46\u88fd\u5099\u904e\u7a0b\u76f8\u7576\u8017\u6642\uff0c\u82e5\u8981\u5927\u898f\u6a21\u751f\u7522\u4ecd\u6709\u96e3\u5ea6\u3002\u672a\u4f86\uff0c\u96a8\u8457\u88fd\u5099\u6280\u8853\u7684\u5b8c\u5584\uff0cGoldene\u5c07\u5728\u5948\u7c73\u5143\u4ef6\u548c\u50ac\u5316\u9818\u57df\u767c\u63ee\u66f4\u5927\u4f5c\u7528\uff0c\u8b93\u6211\u5011\u4e00\u8d77\u904e\u4e0a\u4e00\u500b\u771f\u6b63\u7684\u300c\u9ec3\u91d1\u6642\u4ee3\u300d\u3002<\/strong><\/span><\/p>\n

\u64b0\u6587\uff5c\u9ec3\u9f0e\u921e<\/strong><\/p>\n

\u91d1\u7b94\u662f\u4e00\u7a2e\u9ec3\u91d1\u8584\u7247\uff0c\u7531\u65bc\u9ec3\u91d1\u7684\u9ad8\u5ea6\u5ef6\u5c55\u6027\uff0c\u53ef\u4ee5\u900f\u904e\u9318\u6253\u9ec3\u91d1\u4f7f\u5176\u8b8a\u70ba\u8584\u7247\uff0c\u5e38\u88ab\u7528\u4f86\u88dd\u98fe\u751c\u9ede\uff0c\u63d0\u5347\u98df\u7269\u7684\u5962\u83ef\u611f\u3002\u5b83\u7684\u539a\u5ea6\u7d04\u572810-7<\/sup>\u7c73\u5de6\u53f3\uff0c\u90a3\u9ebc\u91d1\u7247\u5230\u5e95\u53ef\u4ee5\u6709\u591a\u8584\u5462\uff1f\u96a8\u8457\u79d1\u5b78\u6280\u8853\u7684\u9032\u6b65\uff0c\u6750\u6599\u79d1\u5b78\u5bb6\u5df2\u7d93\u80fd\u5408\u6210\u51fa\u50c5\u4e00\u539f\u5b50\u5c64\u539a\u5ea6\u7684\u91d1\u7b94\u7247\uff0c\u9019\u7a2e\u4e8c\u7dad\u6750\u6599\u88ab\u7a31\u70baGoldene\u3002\u57282024\u5e744\u6708\u4efd\u7684\u300aNature Synthesis<\/em>\u300b\u671f\u520a\u4e0a\uff0cGoldene\u53c8\u88ab\u7a31\u70ba\u77f3\u58a8\u70ef\u7684\u300c\u8868\u5144\u5f1f\u300d\u3002<\/p>\n

\"\"
\u57161\uff1aGoldene\u793a\u610f\u5716\uff5c\u4f86\u6e90\uff1aDALL-E AI<\/figcaption><\/figure>\n

 <\/p>\n

\u5f9e\u5c0e\u9ad4\u8b8a\u6210\u534a\u5c0e\u9ad4\uff0c\u60f0\u6027\u91d1\u5c6c\u8b8a\u50ac\u5316\u9ad8\u624b<\/strong><\/span><\/h6>\n

\u7576\u77f3\u58a8\u8b8a\u6210\u4e8c\u7dad\u7d50\u69cb\u7684\u77f3\u58a8\u70ef\u6642\uff0c\u5176\u96fb\u6027\u7522\u751f\u4e86\u5287\u70c8\u7684\u8b8a\u5316\uff0c\u5728\u7279\u5b9a\u60c5\u6cc1\u4e0b\uff0c\u5c0e\u96fb\u5ea6\u53ef\u4ee5\u63d0\u5347\u4e00\u842c\u500d\u4ee5\u4e0a\uff1b\u540c\u6a23\u5730\uff0c\u7576\u9ec3\u91d1\u8b8a\u6210\u4e8c\u7dad\u7d50\u69cbGoldene\u6642\uff0c\u4e5f\u7522\u751f\u4e86\u5de8\u5927\u7684\u8b8a\u5316\uff0c\u4e0d\u540c\u7684\u662f\uff0c\u5b83\u53cd\u800c\u5f9e\u5c0e\u9ad4\u8b8a\u6210\u4e86\u534a\u5c0e\u9ad4\uff0c\u6210\u70ba\u5948\u7c73\u5143\u4ef6\u7684\u61c9\u7528\u6750\u6599\u3002<\/p>\n

\u9019\u7a2e\u8b8a\u5316\u4e3b\u8981\u4f86\u81ea\u65bc\u5eab\u502b\u963b\u585e\u6548\u61c9 (Coulomb Blockade Effect)\uff0c\u7576\u5c0e\u96fb\u9ad4\u7684\u9ad4\u7a4d\u8b8a\u5f97\u8db3\u5920\u5c0f\uff0c\u96fb\u5b50\u4e4b\u9593\u7684\u8ddd\u96e2\u8b8a\u5f97\u975e\u5e38\u8fd1\uff0c\u56e0\u800c\u7522\u751f\u65a5\u529b\uff0c\u5c0e\u81f4\u96fb\u5b50\u79fb\u52d5\u6642\u9700\u8981\u514b\u670d\u4e00\u5b9a\u7684\u80fd\u91cf\u969c\u7919\uff0c\u56e0\u6b64\u9700\u8981\u5916\u52a0\u96fb\u5834\u624d\u80fd\u9a45\u52d5\u96fb\u6d41\u3002\u60f3\u50cf\u4e00\u4e0b\uff0c\u96fb\u5b50\u5728\u5c0e\u9ad4\u4e2d\u5c31\u50cf\u8dd1\u8eca\u5728\u9ad8\u901f\u516c\u8def\u4e0a\u99b3\u9a01\uff0c\u4f46\u82e5\u8eca\u8f1b\u592a\u5bc6\u96c6\uff0c\u8dd1\u8eca\u4e5f\u6703\u585e\u8eca\uff0c\u7121\u6cd5\u81ea\u7531\u884c\u99db\uff0c\u9019\u5c31\u662f\u96fb\u5b50\u5728Goldene\u4e2d\u7684\u56f0\u5883\u3002<\/p>\n

\u6b64\u5916\uff0c\u5728\u9019\u7a2e\u96fb\u5b50\u7cfb\u7d71\u4e2d\uff0c\u9084\u6703\u7522\u751f\u96fb\u5b50\u632f\u76ea\uff0c\u9019\u73fe\u8c61\u63cf\u8ff0\u4e86\u96fb\u5b50\u96a8\u8457\u65bd\u52a0\u7684\u96fb\u58d3\u7522\u751f\u9031\u671f\u6027\u7684\u6d41\u52d5\uff0c\u5c31\u50cf\u9ad8\u901f\u516c\u8def\u7684\u531d\u9053\u7ba1\u63a7\uff0c\u96fb\u5b50\u6703\u4ee5\u7279\u5b9a\u7684\u7bc0\u594f\u901a\u904e\u5c0e\u96fb\u9ad4\uff0c\u85c9\u7531\u5eab\u502b\u963b\u585e\u6548\u61c9\u548c\u96fb\u5b50\u632f\u76ea\uff0c\u6211\u5011\u53ef\u4ee5\u5728Goldene\u4e0a\u7cbe\u78ba\u63a7\u5236\u96fb\u6d41\uff0c\u4ee5\u6eff\u8db3\u5948\u7c73\u96fb\u5b50\u5143\u4ef6\u7684\u9700\u6c42\u3002<\/p>\n

\u9664\u4e86\u96fb\u6027\u7684\u8f49\u8b8a\u4e4b\u5916\uff0c\u9ec3\u91d1\u539f\u672c\u5c6c\u65bc\u60f0\u6027\u91d1\u5c6c\uff0c\u4e0d\u6613\u8207\u5176\u4ed6\u5316\u5b78\u5143\u7d20\u53cd\u61c9\uff0c\u4f46\u5728\u5fae\u89c0\u4e16\u754c\u4e2d\uff0c\u5948\u7c73\u7d1a\u7684\u91d1\u537b\u6210\u70ba\u5177\u6709\u512a\u7570\u50ac\u5316\u80fd\u529b\u7684\u6750\u6599\u3002\u50ac\u5316\u4f5c\u7528\u6307\u7684\u662f\u81ea\u8eab\u4e0d\u88ab\u6d88\u8017\uff0c\u537b\u80fd\u964d\u4f4e\u53cd\u61c9\u7684\u6d3b\u5316\u80fd\uff0c\u63d0\u4f9b\u4e0d\u540c\u7684\u53cd\u61c9\u8def\u5f91\uff0c\u4f7f\u5316\u5b78\u53cd\u61c9\u66f4\u6613\u767c\u751f\u7684\u6548\u679c\u3002\u904e\u53bb\u7684\u7814\u7a76\u767c\u73fe\uff0c\u5948\u7c73\u91d1\u7c92\u53ef\u4ee5\u50ac\u5316\u4e00\u6c27\u5316\u78b3\u53ca\u63ee\u767c\u6027\u6709\u6a5f\u5316\u5408\u7269\u7684\u53cd\u61c9\uff0c\u6709\u52a9\u65bc\u6e05\u9664\u6709\u5bb3\u6c23\u9ad4\uff0c\u6e1b\u5c11\u7a7a\u6c23\u6c59\u67d3\uff0c\u9084\u80fd\u9032\u884c\u6c34\u5206\u89e3\uff0c\u7522\u751f\u6c2b\u6c23\u80fd\u6e90\uff0c\u6e1b\u5c11\u5c0d\u5316\u77f3\u71c3\u6599\u7684\u4f9d\u8cf4\u3002Goldene\u5177\u6709\u66f4\u5927\u7684\u8868\u9762\u7a4d\uff0c\u9810\u671f\u6703\u6709\u6bd4\u5948\u7c73\u91d1\u7c92\u66f4\u512a\u7570\u7684\u50ac\u5316\u6548\u679c\u3002<\/p>\n

 <\/p>\n

\u5982\u4f55\u88fd\u4f5cGoldene\uff1f<\/strong><\/span><\/h6>\n

\u65e9\u57282015\u5e74\uff0c\u5c31\u6709\u7406\u8ad6\u8a08\u7b97\u9810\u6e2c\u4e8c\u7dad\u8584\u91d1Goldene\u7684\u5b58\u5728\uff0c\u4e26\u6307\u51fa\u5176\u6027\u8cea\u7a69\u5b9a\u4e14\u5805\u56fa\uff0c\u7136\u800c\uff0c\u5927\u591a\u6578\u7814\u7a76\u5f97\u5230\u7684Goldene\u537b\u5bb9\u6613\u6372\u66f2\uff0c\u7121\u6cd5\u50cf\u77f3\u58a8\u70ef\u4e00\u6a23\u6210\u70ba\u7a69\u5b9a\u5e73\u5766\u7684\u8584\u819c\uff0c\u4e3b\u8981\u539f\u56e0\u662f\u88fd\u5099\u904e\u7a0b\u4e2dGoldene\u53d7\u5230\u4e0d\u5747\u52fb\u7684\u640d\u50b7\uff0c\u4f7f\u7d50\u69cb\u4e2d\u6b98\u7559\u61c9\u529b\uff0c\u5c0e\u81f4\u805a\u96c6\u73fe\u8c61\u30022024\u5e74\uff0c\u745e\u5178\u6797\u96ea\u5e73\u5927\u5b78 (Link\u00f6ping University) \u767c\u5c55\u51fa\u4e00\u5957\u88fd\u5099\u65b9\u6cd5\u4f86\u9632\u6b62Goldene\u6372\u66f2\uff0c\u9019\u9805\u7814\u7a76\u767b\u4e0a\u4e86\u300aNature Synthesis<\/em>\u300b\u671f\u520a\u3002\u9996\u5148\uff0c\u4ed6\u5011\u5728SiC\u57fa\u677f\u4e0a\u751f\u9577Ti3SiC2\u819c\uff0c\u901a\u904e\u78c1\u63a7\u6ffa\u5c04\u6c89\u7a4d\u4e00\u5c64\u91d1\u3002\u63a5\u8457\uff0c\u5c07\u9019\u4e9b\u819c\u5728\u9ad8\u6eab\u4e0b\u9000\u706b\uff0c\u8b93\u91d1\u6ef2\u900f\u9032\u5165Ti3SiC2\u819c\uff0c\u5f62\u6210Ti3AuC2\u3002\u7136\u5f8c\uff0c\u4f7f\u7528Murakami\u8a66\u5291\u548c\u8868\u9762\u6d3b\u6027\u5291\uff08\u5982CTAB\u548c\u534a\u80f1\u6c28\u9178\uff09\u9032\u884c\u5316\u5b78\u9078\u64c7\u6027\u8755\u523b\uff0c\u53bb\u9664Ti3C2\u5c64\u4e26\u91cb\u653e\u51fa\u55ae\u539f\u5b50\u539a\u7684\u91d1\u5c64\uff0c\u4e14\u8868\u9762\u6d3b\u6027\u5291\u6709\u52a9\u65bc\u7a69\u5b9a\u91d1\u5c64\uff0c\u9632\u6b62\u6372\u66f2\u3002\u4e0d\u904e\uff0c\u9019\u500b\u8755\u523b\u904e\u7a0b\u9700\u6642\u81f3\u5c11\u4e00\u9031\uff0c\u589e\u52a0\u4e86\u4e00\u5b9a\u7684\u88fd\u5099\u56f0\u96e3\u5ea6\uff0c\u96e3\u4ee5\u5927\u898f\u6a21\u751f\u7522\u3002<\/p>\n

\"\"
\u57162\uff1aGoldene\u7684\u88fd\u5099\u904e\u7a0b\uff5c\u4f86\u6e90\uff1a\u53c3\u8003\u8cc7\u65992<\/figcaption><\/figure>\n

\u96a8\u8457\u79d1\u6280\u7684\u9032\u6b65\uff0c\u91d1\u7b94\u5c07\u4e0d\u50c5\u50c5\u7528\u65bc\u63d0\u5347\u751c\u9ede\u7684\u5962\u83ef\u611f\uff0c\u5b83\u5c07\u8b8a\u5f97\u66f4\u8584\uff0c\u6210\u70ba\u5948\u7c73\u5143\u4ef6\u4e2d\u7684\u91cd\u8981\u534a\u5c0e\u9ad4\u6750\u6599\u3002\u7576\u9ec3\u91d1\u4e8c\u7dad\u5316\u6210\u70baGoldene\u6642\uff0c\u5b83\u5c07\u5f9e\u5c0e\u9ad4\u8f49\u8b8a\u70ba\u534a\u5c0e\u9ad4\uff0c\u4e26\u5f9e\u60f0\u6027\u91d1\u5c6c\u8f49\u8b8a\u70ba\u512a\u7570\u7684\u50ac\u5316\u5291\u3002\u671f\u5f85\u672a\u4f86\u79d1\u5b78\u5bb6\u514b\u670dGoldene\u88fd\u5099\u7684\u56f0\u96e3\uff0c\u4ee5\u81f3\u65bc\u9ec3\u91d1\u80fd\u88ab\u61c9\u7528\u81f3\u6240\u6709\u7684\u79d1\u6280\u5de5\u696d\u88dd\u7f6e\u4e4b\u4e2d\uff0c\u6211\u5011\u7684\u751f\u6d3b\u6216\u5c07\u5145\u6eff\u9ec3\u91d1\uff0c\u9032\u5165\u771f\u6b63\u7684\u300c\u9ec3\u91d1\u6642\u4ee3\u300d\u3002<\/p>\n

 <\/p>\n

\n

\u53c3\u8003\u6587\u737b<\/strong><\/p>\n

    \n
  1. Sharma, S., Pasricha, R., Weston, J., Blanton, T., & Jagannathan, R. (2022). Synthesis of Self-Assembled Single Atomic Layer Gold Crystals-Goldene. ACS Applied Materials & Interfaces, 14, 54992 - 55003.<\/a><\/li>\n
  2. Kashiwaya, S., Shi, Y., Lu, J. et al. Synthesis of goldene comprising single-atom layer gold. Nat. Synth 3, 744\u2013751 (2024).<\/a><\/li>\n<\/ol>\n

     <\/p>\n

    \n

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