{"id":44251,"date":"2010-09-23T06:03:52","date_gmt":"2010-09-22T22:03:52","guid":{"rendered":"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/?p=8467"},"modified":"2010-09-23T06:03:52","modified_gmt":"2010-09-22T22:03:52","slug":"%e6%9c%89%e6%a9%9f%e5%a4%aa%e9%99%bd%e8%83%bd%e9%9b%bb%e6%b1%a0%ef%bc%88organic-solar-cell%ef%bc%89","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=44251","title":{"rendered":"\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\uff08Organic Solar Cell\uff09"},"content":{"rendered":"<p><strong><span style=\"color: #ff6600;\">\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\uff08Organic Solar Cell\uff09<\/span><\/strong><br \/>\n<strong><span style=\"color: #008000;\">\u570b\u7acb\u53f0\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u856d\u5168\u4f51\u7814\u7a76\u751f\/\u570b\u7acb\u53f0\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb\u8449\u540d\u5009\u6559\u6388\u8cac\u4efb\u7de8\u8f2f<\/span><\/strong><\/p>\n<p>\u592a\u967d\u80fd\u96fb\u6c60\u4e3b\u8981\u76ee\u7684\u662f\u5c07\u5149\u80fd\u8f49\u63db\u6210\u96fb\u80fd\u3002\u800c\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\u4e3b\u8981\u4fc2\u4ee5\u5177\u6709\u534a\u5c0e\u9ad4\u6027\u8cea\u4e4b\u6709\u6a5f\u6750\u6599\u88fd\u4f5c\uff0c\u5176\u512a\u9ede\uff1a\uff081\uff09\u88fd\u9020\u6210\u672c\u4f4e\uff082\uff09\u5316\u5408\u7269\u7d50\u69cb\u53ef\u8a2d\u8a08\u6027\uff083\uff09\u6750\uf9be\u8cea\u8f15\uff084\uff09\u52a0\u5de5\u6027\u80fd\u597d\uff085\uff09\u88fd\u9020\u5927\u9762\u7a4d\u7684\u592a\u967d\u80fd\u96fb\u6c60\u53ca\u5927\u91cf\u751f\u7522\uff086\uff09\u9ad8\u5438\u5149\u4fc2\u6578\uff087\uff09\u5177\u6709\u53ef\u6493\u66f2\uff0c\u534a\u900f\u660e\u7b49\u7279\u6027\u3002\u4f46\u76ee\u524d\u4ea6\u6709\u591a\u9805\u7f3a\u9ede\u5f85\u514b\u670d\uff0c\u5982\u529f\uf961\u8f49\u63db\u6548\uf961\u4f4e\uff0c\u8f09\u5b50\u9077\u79fb\uf961\u4f4e\uff0c\u9ad8\u96fb\u963b\uff0c\u8010\u4e45\u6027\u5dee\u7b49\u554f\u984c\u3002<\/p>\n<p>\u4f9d\u6709\u6a5f\u6750\u6599\u4e0d\u540c\u7279\u6027\uff0c\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\u53c8\u53ef\u5340\u5206\u70ba\uff081\uff09\u67d3\u6599\u654f\u5316\u592a\u967d\u80fd\u96fb\u6c60\uff08dye-sensitized solar cells\uff0cDSSC\uff09\uff0c1991\uf98e\u745e\u58eb\uf997\u90a6\uf9e4\u5de5\u5b78\u9662\u7684M. Graumltzel\u6559\u6388\u7684\u7814\u7a76\u5718\u968a\uff0c\u767c\u660e\u5177\u5149\u654f\u6027\u8cea\u4e4b\u67d3\uf9be\u5438\u9644\u65bc\u534a\u5c0e\u9ad4\uf90c\u7c73\u591a\u5b54\u6d1e\u7d50\u69cb\u4e4bTiO<sub>2<\/sub>\u96fb\u6975\uff0c\u642d\u914d\u5177\u6709\u6c27\u5316-\u9084\u539f\u6027\u8cea(I<sup>-<\/sup> \/ I<sup>3-<\/sup>)\u4e4b\u96fb\u89e3\u6db2\uff0c\u88fd\u4f5c\u51fa\u5149\u96fb\u8f49\u63db\u6548\uf961\u9ad8\u90547 %\u4e4b\u67d3\uf9be\u654f\u5316\u592a\u967d\u80fd\u96fb\u6c60\uff0c\u76ee\u524d\u9019\u7a2e\u96fb\u6c60\u7684\u5149\u96fb\u8f49\u63db\u6548\u7387\u6700\u9ad8\u5df2\u8d85\u904e 11%\uff0c\u5176\u767c\u5c55\u6f5b\u529b\u5099\u53d7\u77da\u76ee\u3002\uff082\uff09\u5c0f\u5206\u5b50\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\uff08Molecular Solar Cells\uff09\u3002\uff083\uff09\u9ad8\u5206\u5b50\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\uff08polymer solar cells\uff09\uff0c1981 \uf98e\u6642A. Takahashi\u7814\u7a76\u5718\u968a\u6700\u65e9\u5c07\u5171\u8edb\u9ad8\u5206\u5b50\u6750\uf9be\u4f7f\u7528\u65bc\u88fd\u4f5c\u592a\u967d\u80fd\u96fb\u6c60\u3002\u76ee\u524d\u9ad8\u5206\u5b50\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\u5e38\u7528\u7684\u6750\u6599\u70ba\u805a 3-\u5df1\u70f7\u57fa\u567b\u5429\uff08poly (3-hexylthiophene), P3HT\uff09 \u805a\u5408\u7269\u534a\u5c0e\u9ad4\uff08p \u578b\u6750\u6599\uff09\u3001\u82ef\u57fa-C61 \u4e01\u9178\u7532\u916f (phenyl-C61-butyric acid methylester, PCBM)\uff08n \u578b\u6750\u6599\uff09\u6240\u7d44\u6210\u3002\u5176\u505a\u6cd5\u662f\u5c07\u9019\u5169\u7a2e\u6709\u6a5f\u534a\u5c0e\u9ad4\u6750\u6599\u4ee5\u6eb6\u5291\u6eb6\u89e3\u5f8c\u9032\u884c\u6df7\u5408\uff0c\u800c\u5f8c\u518d\u5857\u4f48\u5230\u5143\u4ef6\u4e0a\u3002\u5747\u52fb\u6df7\u5408\u5f8c\u7684 pn \u4ecb\u9762\u9762\u7a4d\u80fd\u6709\u6548\u63d0\u9ad8\uff0c\u589e\u52a0\u6fc0\u5b50\u88ab\u62c6\u89e3\u7684\u6a5f\u6703\u800c\u63d0\u5347\u96fb\u6c60\u6548\u7387\u3002<!--more--><\/p>\n<p><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2010\/09\/cc5.png\"><\/a><\/p>\n<p style=\"text-align: center;\"><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2010\/09\/cc6.png\"><img fetchpriority=\"high\" decoding=\"async\" class=\"aligncenter size-full wp-image-8472\" title=\"cc\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2010\/09\/cc6.png\" alt=\"\" width=\"300\" height=\"342\" \/><\/a><\/p>\n<div>\u4ee5\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\u7d50\u69cb\uff0c\u53ef\u5340\u5206\u6210\u55ae\u5c64\u53ca\u96d9\u5c64\uff08\u6216\u7a31\u7570\u8cea\u63a5\u9762\uff09\u592a\u967d\u80fd\u96fb\u6c60\u3002\u55ae\u5c64\u4e3b\u8981\u4ee5\u967d\u6975\uff0c\u6709\u6a5f\u6750\u6599\u53ca\u9670\u6975\u6240\u7d44\u6210\u3002\u800c\u96d9\u5c64\u4e3b\u8981\u4ee5\u967d\u6975\uff0c\u53ef\u7576\u96fb\u5b50\u4e88\u9ad4\u6709\u6a5f\u6750\u6599\uff0c\u53ef\u7576\u96fb\u5b50\u53d7\u9ad4\u6709\u6a5f\u6750\u6599\u53ca\u9670\u6975\u6240\u7d44\u6210\u3002\u00a0<\/div>\n<p style=\"text-align: center;\">\u00a0<\/p>\n<div>\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\u5176\u767c\u5149\u539f\u7406\uff0c\u4ee5\u96fb\u5b50\u4e88\u9ad4\/\u53d7\u9ad4\u7570\u8cea\u63a5\u9762\uff08electro donor-acceptor heterojunction\uff09\u5143\u4ef6\u7d50\u69cb\u70ba\u4f8b\uff0c\u53c3\u8003\u4e0b\u5716\u00a0<\/div>\n<p style=\"text-align: center;\">\u00a0<\/p>\n<p style=\"text-align: center;\"><a href=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2010\/09\/ccc.png\"><img decoding=\"async\" class=\"size-full wp-image-8473 aligncenter\" title=\"ccc\" src=\"http:\/\/highscope.ch.ntu.edu.tw\/wordpress\/wp-content\/uploads\/2010\/09\/ccc.png\" alt=\"\" width=\"500\" height=\"153\" \/><\/a><\/p>\n<p>\u00a0<\/p>\n<p>\u9996\u5148\u4e88\u9ad4\uff08donor\uff09\u63a5\u6536\u5149\uff0c\u5149\u6fc0\u767c\u751f\u6210\u96fb\u5b50\u96fb\u6d1e\u5c0d\uff08electron-hole pair\uff09\u6216\u53ef\u7a31\u70ba\u6fc0\u5b50\uff08exciton\uff09\u3002\u7576\u6fc0\u5b50\u64f4\u6563\u81f3Donor-Acceptor\u4ecb\u9762\uff0c\u6fc0\u5b50\u5c07\u5206\u89e3\u6210\u7368\u7acb\u50b3\u5c0e\u7684\u96fb\u5b50\u53ca\u96fb\u6d1e\u3002\u7531\u65bcdonor\u53caacceptor\u5169\u8005\u7684LUMO\u3001HUMO\u80fd\u968e\u5dee\u7570\u7684\u95dc\u4fc2\uff0c\u96fb\u5b50\u6703\u5f80acceptor\u6750\u6599\uff0c\u800c\u96fb\u6d1e\u5247\u5f80donor\u6750\u6599\u50b3\u905e\u3002\u63a5\u8457\u900f\u904e\u96fb\u6975\uff0c\u7d93\u7531\u5916\u96fb\u8def\uff0c\u751f\u6210\u96fb\u6d41\u3002<\/p>\n<p>\u4e0d\u8ad6\u662f\u5c0f\u5206\u5b50\u6216\u9ad8\u5206\u5b50\u6709\u6a5f\u6750\u6599\uff0c\u4ed6\u5011\u90fd\u5177\u6709\u5171\u540c\u7279\u6027\uff1a\u9ad8\u5171\u8edb\u7cfb\u7d71\u9019\u4e9bpz\u8ecc\u57df\u975e\u5b9a\u57df\u5316\u96fb\u5b50\u6df7\u6210\u5f62\u6210\u4e00\u975e\u5b9a\u57df\u5316\u03c0\u53ca\u03c0\uff0a\u8ecc\u57df\u3002\u5176\u4e2d\u975e\u5b9a\u57df\u5316\u03c0\u8ecc\u57df\u70baHOMO\uff0c\u800c\u975e\u5b9a\u57df\u5316\u03c0\uff0a\u8ecc\u57df\u70baLUMO\u3002\u800c\u5169\u8005\u7684\u80fd\u968e\u5dee\uff0c\u88ab\u8a8d\u70ba\u662f\u6709\u6a5f\u5c0e\u96fb\u6750\u6599\u7684\u80fd\u9699\uff0c\u800c\u901a\u5e38\u80fd\u9699\u503c\u7d04\u70ba1~4 eV\u3002\u4e00\u822c\u800c\u8a00\uff0c\u5ef6\u9577\u6709\u6a5f\u5206\u5b50\u5171\u8edb\u78b3\u93c8\u9577\u5ea6\uff0c\u53ef\u964d\u4f4e\u80fd\u9699\u503c\u3002<\/p>\n<p>\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\u4ecd\u7136\u6709\u8a31\u591a\u767c\u5c55\u7a7a\u9593\uff0c\u4f8b\u5982\u85c9\u7531\u6709\u6a5f\u5206\u5b50\u8a2d\u8a08\uff0c\u7814\u7a76\u51fa\u66f4\u9069\u5408\u7684\u611f\u5149\u5c64\u6750\u6599\uff0c\u4f7f\u5176\u80fd\u66f4\u5145\u5206\u5229\u7528\u5230\u592a\u967d\u5149\u80fd\u4e2d\u5404\u7a2e\u5149\u6ce2\u6bb5\u7684\u80fd\u91cf\uff1b\u767c\u5c55\u51fa\u4f7f\u8f09\u5b50\u79fb\u52d5\u7387\u66f4\u5feb\u7684\u6750\u6599\uff0c\u4f7f\u5176\u96fb\u5b50-\u96fb\u6d1e\u5c0d\u5206\u96e2\u7684\u6548\u7387\u80fd\u63d0\u5347\uff1b\u6539\u5584\u5143\u4ef6\u7684\u5149\u5438\u6536\u7387\uff0c\u4f7f\u5176\u8f49\u63db\u6548\u7387\u5927\u5e45\u63d0\u5347\u3002<\/p>\n<p><strong>\u53c3\u8003\u6587\u737b<\/strong><br \/>\n<a href=\"http:\/\/www.itrc.org.tw\/Publication\/Newsletter\/no95\/p12.php\" target=\"_blank\" rel=\"noopener\">http:\/\/www.itrc.org.tw\/Publication\/Newsletter\/no95\/p12.php<\/a><br \/>\n<a href=\"http:\/\/en.wikipedia.org\/wiki\/Organic_solar_cell\" target=\"_blank\" rel=\"noopener\">http:\/\/en.wikipedia.org\/wiki\/Organic_solar_cell<\/a><br \/>\nChem. Rev. 2009, 109, 5868\u20135923<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u6709\u6a5f\u592a\u967d\u80fd\u96fb\u6c60\uff08Organic Sola<\/p>\n","protected":false},"author":20,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[7113,7119,7121,7114,7112,7118],"tags":[1269,7120,1096],"aioseo_notices":[],"jetpack_featured_media_url":"","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/44251"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=44251"}],"version-history":[{"count":0,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/44251\/revisions"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=44251"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=44251"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=44251"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}