{"id":43829,"date":"2009-07-26T15:49:25","date_gmt":"2009-07-26T07:49:25","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=43829"},"modified":"2024-03-04T16:02:59","modified_gmt":"2024-03-04T08:02:59","slug":"%e7%8e%bb%e7%92%83%ef%bc%88glass%ef%bc%89%ef%bc%88%e4%b8%80%ef%bc%89","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=43829","title":{"rendered":"\u73bb\u7483 (Glass)\uff08\u4e00\uff09"},"content":{"rendered":"<p><strong>\u64b0\u6587\uff5c\u81fa\u5317\u5e02\u7acb\u7b2c\u4e00\u5973\u5b50\u9ad8\u7d1a\u4e2d\u5b78\u5316\u5b78\u79d1 \u4f55\u93ae\u63da \u8001\u5e2b<\/strong><\/p>\n<p><strong>\u8cac\u4efb\u7de8\u8f2f\uff5c\u570b\u7acb\u81fa\u7063\u5e2b\u7bc4\u5927\u5b78\u5316\u5b78\u7cfb \u8449\u540d\u5009 \u6559\u6388<\/strong><\/p>\n<figure id=\"attachment_43830\" aria-describedby=\"caption-attachment-43830\" style=\"width: 800px\" class=\"wp-caption aligncenter\"><img fetchpriority=\"high\" decoding=\"async\" class=\"wp-image-43830 size-large\" src=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/03\/\u73bb\u7483-1024x576.jpg\" alt=\"\" width=\"800\" height=\"450\" srcset=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/03\/\u73bb\u7483-1024x576.jpg 1024w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/03\/\u73bb\u7483-300x169.jpg 300w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/03\/\u73bb\u7483-768x432.jpg 768w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/03\/\u73bb\u7483-1536x864.jpg 1536w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/03\/\u73bb\u7483-2048x1152.jpg 2048w\" sizes=\"(max-width: 800px) 100vw, 800px\" \/><figcaption id=\"caption-attachment-43830\" class=\"wp-caption-text\">\u4f86\u6e90\uff1aMotionElements<\/figcaption><\/figure>\n<p>\u73bb\u7483\u901a\u5e38\u662f\u4ee5\u77f3\u82f1\u7802\u3001\u7d14\u9e7c\u3001\u9577\u77f3\u53ca\u77f3\u7070\u77f3\u70ba\u4e3b\u8981\u539f\u6599\uff0c\u5728\u9ad8\u6eab\u7210\u5167\u7194\u878d\uff0c\u767c\u751f\u8907\u96dc\u7684\u7269\u7406\u8b8a\u5316\u3001\u5316\u5b78\u53cd\u61c9\u5f8c\uff0c\u5f62\u6210\u7121\u6a5f\u6c27\u5316\u7269\u7684\u7194\u878d\u6df7\u5408\u7269\uff0c\u5982\u6c27\u5316\u77fd\u3001\u6c27\u5316\u92c1\u3001\u6c27\u5316\u9240\/\u6c27\u5316\u9209\u3001\u6c27\u5316\u787c\u7b49\uff0c\u9ad8\u6eab\u7194\u5316\u6210\u6c27\u5316\u7269\u7684\u9023\u7e8c\u7db2\u7d61\u7d50\u69cb\uff0c\u51b7\u537b\u904e\u7a0b\u4e2d\u9ecf\u5ea6\u9010\u6f38\u589e\u5927\u4e26\u786c\u5316\u5f62\u6210\u975e\u7d50\u6676\u77fd\u9178\u9e7d\u985e\u7684\u7121\u6a5f\u975e\u91d1\u5c6c\u6750\u6599\uff0c\u5b83\u5011\u4e26\u6c92\u6709\u7279\u6709\u7684\u56fa\u5b9a\u7684\u7d44\u6210\uff0c\u975e\u7d50\u6676\u6027\u662f\u5176\u5340\u5225\u65bc\u9676\u74f7\u3001\u6c34\u6ce5\u6750\u6599\u6700\u986f\u8457\u7684\u7d50\u69cb\u7279\u5fb5\u3002<\/p>\n<p>\u4e0d\u540c\u7a2e\u985e\u7684\u73bb\u7483\uff0c\u5176\u5316\u5b78\u6210\u5206\u5404\u4e0d\u76f8\u540c\uff0c\u4f46\u542b\u91cf\u6700\u9ad8\u7684\u9084\u662f\u975e\u6676\u4e8c\u6c27\u5316\u77fd\uff0c\u4e00\u822c\u70ba50%\uff5e80%\uff0c\u5728\u77f3\u82f1\u73bb\u7483\u4e2d\u66f4\u9ad8\u905498%\u4ee5\u4e0a\u3002SiO<sub>2<\/sub>\u5728\u73bb\u7483\u4e2d\u69cb\u6210\u9aa8\u67b6\uff0c\u8ce6\u4e88\u73bb\u7483\u826f\u597d\u7684\u5316\u5b78\u7a69\u5b9a\u6027\u3001\u71b1\u7a69\u5b9a\u6027\u3001\u900f\u660e\u6027\u3001\u8f03\u9ad8\u7684\u8edf\u5316\u6eab\u5ea6\u3001\u786c\u5ea6\u548c\u6a5f\u68b0\u5f37\u5ea6\u3002\u4f46\u542b\u91cf\u589e\u5927\u6642\uff0c\u7194\u878d\u6eab\u5ea6\u5347\u9ad8\uff0c\u73bb\u7483\u6db2\u9ecf\u5ea6\u589e\u5927\u3002SiO<sub>4<\/sub><sup>4-<\/sup>\u56db\u9762\u9ad4\u7d50\u69cb\u70ba\u5176\u57fa\u672c\u69cb\u7bc9\u55ae\u5143\u3002\u666e\u901a\u73bb\u7483\u9084\u542b\u6709\u6c27\u5316\u9240\/\u6c27\u5316\u9209\u3001\u6c27\u5316\u9223\u7b49\u5176\u4ed6\u6c27\u5316\u7269\u3002<\/p>\n<p>\u73bb\u7483\u751f\u7522\u7684\u4e3b\u8981\u539f\u6599\u5206\u70ba\u73bb\u7483\u5f62\u6210\u9ad4\u3001\u73bb\u7483\u8abf\u6574\u7269\u548c\u73bb\u7483\u4e2d\u9593\u9ad4\uff0c\u5176\u9918\u70ba\u8f14\u52a9\u539f\u6599\u3002\u4e3b\u8981\u539f\u6599\u6307\u5f15\u5165\u73bb\u7483\u5f62\u6210\u7db2\u7d61\u7684\u6c27\u5316\u7269\u3001\u4e2d\u9593\u9ad4\u6c27\u5316\u7269\u548c\u7db2\u7d61\u5916\u6c27\u5316\u7269\uff1b\u8f14\u52a9\u539f\u6599\u5305\u62ec\u6f84\u6e05\u5291\u3001\u52a9\u7194\u5291\u3001\u4e73\u6fc1\u5291\u3001\u8457\u8272\u5291\u3001\u812b\u8272\u5291\u3001\u6c27\u5316\u5291\u548c\u9084\u539f\u5291\u7b49\u3002<\/p>\n<p>\u4e3b\u8981\u539f\u6599\u5177\u9ad4\u5305\u62ec\uff1a(1) \u5bcc\u542bSiO<sub>2<\/sub>\u7684\u5404\u7a2e\u7926\u7269\uff08\u77fd\u7802\u3001\u5ca9\u7802\u7b49\uff09\uff1b(2) \u7528\u4ee5\u5f15\u5165Al<sub>2<\/sub>O<sub>3<\/sub>\u7684\u9577\u77f3\u3001\u9ecf\u571f\u7b49\u7926\u7269\uff1b(3) \u7528\u4ee5\u5f15\u5165Na<sub>2<\/sub>O \/ K<sub>2<\/sub>O\u7d44\u5206\u7684\u7d14\u9e7c\u3001\u8292\u785d\u3001\u9240\u9e7c\u7b49\uff1b(4) \u7528\u4ee5\u5f15\u5165B<sub>2<\/sub>O<sub>3<\/sub>\u7d44\u5206\u7684\u787c\u9178\u3001\u787c\u7802\u53ca\u787c\u7926\u7269\uff1b(5) \u7528\u4ee5\u5f15\u5165CaO\u3001MgO\u7684\u5176\u4ed6\u7926\u7269\u7b49\u3002<\/p>\n<p>\u73bb\u7483\u7684\u7194\u88fd\u662f\u4e00\u500b\u975e\u5e38\u8907\u96dc\u7684\u904e\u7a0b\uff0c\u5b83\u5305\u542b\u4e00\u7cfb\u5217\u7684\u7269\u7406\u904e\u7a0b\uff08\u914d\u5408\u6599\u52a0\u71b1\u3001\u914d\u5408\u6599\u812b\u6c34\u3001\u7194\u5316\u3001\u6676\u76f8\u8f49\u8b8a\u3001\u63ee\u767c\u7b49\uff09\u3001\u5316\u5b78\u904e\u7a0b\uff08\u56fa\u76f8\u53cd\u61c9\u3001\u5316\u5408\u7269\u5206\u89e3\u3001\u77fd\u9178\u9e7d\u7684\u5f62\u6210\u7b49\uff09\u548c\u7269\u7406\u5316\u5b78\u904e\u7a0b\uff08\u5171\u7194\u9ad4\u7684\u751f\u6210\u3001\u56fa\u6eb6\u3001\u6db2\u9ad4\u9593\u6eb6\u89e3\u3001\u73bb\u7483\u6db2\u8207\u7210\u6c23\u548c\u6c23\u6ce1\u9593\u7684\u4f5c\u7528\u3001\u73bb\u7483\u6db2\u8207\u8010\u706b\u6750\u6599\u9593\u7684\u4f5c\u7528\u7b49\uff09\u3002\u6839\u64da\u539f\u6599\u5728\u904e\u7a0b\u4e2d\u7684\u4e0d\u540c\u8b8a\u5316\u53ef\u4ee5\u5c07\u73bb\u7483\u7684\u7194\u88fd\u904e\u7a0b\u5206\u70ba\u77fd\u9178\u9e7d\u5f62\u6210\u3001\u73bb\u7483\u5f62\u6210\u3001\u73bb\u7483\u6db2\u6f84\u6e05\u3001\u73bb\u7483\u6db2\u5747\u5316\u548c\u73bb\u7483\u6db2\u51b7\u537b\u7b49\u4e94\u500b\u968e\u6bb5\u3002<\/p>\n<p>\u77fd\u9178\u9e7d\u7684\u751f\u6210\u4e00\u822c\u5728\u7194\u88fd\u904e\u7a0b\u7684\u521d\u671f\u52a0\u71b1\u968e\u6bb5 (800\uff5e900 \u2103) \u9032\u884c\u3002\u914d\u5408\u6599\u4eba\u7aaf\u5f8c\uff0c\u5728\u9ad8\u6eab\u4e0b\u8fc5\u901f\u767c\u751f\u4e00\u7cfb\u5217\u7684\u8b8a\u5316\u904e\u7a0b\uff0c\u5305\u62ec\u812b\u6c34\u3001\u9e7d\u985e\u5206\u89e3\u3001\u6c23\u9ad4\u9038\u51fa\u3001\u591a\u6676\u8f49\u8b8a\u3001\u8907\u9e7d\u751f\u6210\u3001\u77fd\u9178\u9e7d\u751f\u6210\u7b49\uff0c\u6700\u7d42\u5f97\u5230\u6709\u77fd\u9178\u9e7d\u548c\u5269\u9918\u4e8c\u6c27\u5316\u77fd\u7d44\u6210\u7684\u4e0d\u900f\u660e\u71d2\u7d50\u7269\u3002\u5f62\u6210\u77fd\u9178\u9e7d\u7684\u4e3b\u8981\u5316\u5b78\u53cd\u61c9\u5982\u4e0b\uff1a<\/p>\n<ul>\n<li>Na<sub>2<\/sub>CO<sub>3<\/sub> + SiO<sub>2<\/sub> \u2192 Na<sub>2<\/sub>SiO<sub>3<\/sub> + CO<sub>2<\/sub> (1500 \u2103)<\/li>\n<li>Na<sub>2<\/sub>SiO<sub>3<\/sub> + xSiO<sub>2<\/sub>\u2192(Na<sub>2<\/sub>O)(SiO<sub>2<\/sub>)<sub>(x+1)<\/sub> (Na<sub>2<\/sub>SO<sub>4<\/sub>)<\/li>\n<\/ul>\n<p>\u812b\u8272\u8655\u7406\u662f\u73bb\u7483\u751f\u7522\u4e2d\u91cd\u8981\u7684\u4e00\u74b0\uff0c\u812b\u8272\u4e3b\u8981\u662f\u6307\u6e1b\u5f31\u9435\u5316\u5408\u7269\u5c0d\u73bb\u7483\u8457\u8272\u7684\u5f71\u97ff\uff0c\u4ee5\u63d0\u9ad8\u73bb\u7483\u7684\u900f\u660e\u5ea6\u3002\u5728\u73bb\u7483\u4e2d\uff0cFe<sup>2+<\/sup>\u4f7f\u73bb\u7483\u8457\u6210\u85cd\u7da0\u8272\uff0cFe<sup>3+<\/sup>\u4f7f\u73bb\u7483\u8457\u6210\u9ec3\u7da0\u8272\u3002\u5f9e\u53ef\u898b\u5149\u8b5c\u7bc4\u570d\u5167 (400\uff5e700 nm) \u55ae\u4f4d\u5438\u6536\u6307\u6578\u770b\uff0cFe<sup>2+<\/sup>\u70ba0.079\uff0cFe<sup>3+<\/sup>\u70ba0.007\uff0cFeO\u7684\u8457\u8272\u80fd\u529b\u8981\u6bd4Fe<sub>2<\/sub>O<sub>3<\/sub>\u9ad810\u500d\u5de6\u53f3\u3002\u5be6\u969b\u4e0a\uff0c\u5728\u73bb\u7483\u4e2d\u540c\u6642\u5b58\u5728\u4e0a\u8ff0\u5169\u7a2e\u6c27\u5316\u7269\uff0c\u5176\u8457\u8272\u5f37\u5ea6\u8207Fe<sup>2+<\/sup> \/ Fe<sup>3+<\/sup>\u6bd4\u503c\u6709\u95dc\u3002\u6839\u64da\u812b\u8272\u6a5f\u5236\uff0c\u9435\u5316\u5408\u7269\u7684\u812b\u8272\u53ef\u5206\u70ba\u5316\u5b78\u812b\u8272\u548c\u7269\u7406\u812b\u8272\u5169\u985e\u3002<\/p>\n<p>\u5316\u5b78\u812b\u8272\u5291\u2013\u80fd\u5728\u4f4e\u6eab\u6216\u9ad8\u6eab\u4e0b\u653e\u51fa\u6c27\u6c23\uff0c\u4f7f\u4f4e\u50f9\u9435\u6c27\u5316\u6210\u9ad8\u50f9\u9435\u7684\u7269\u8cea\u3002\u5e38\u7528\u7684\u5316\u5b78\u812b\u8272\u5291\u6709\u785d\u9178\u9e7d\u3001\u8edf\u9333\u7926\u3001\u6c27\u5316\u9230\u7b49\u3002\u6700\u5e38\u7528\u7684\u662f\u785d\u9178\u9209\uff0c\u4f46\u5176\u5206\u89e3\u6eab\u5ea6\u4f4e (380 \u2103)\uff0c\u5927\u90e8\u5206\u5728\u73bb\u7483\u5f62\u6210\u524d\u5df2\u9038\u51fa\uff0c\u5f71\u97ff\u4e86\u812b\u8272\u6548\u679c\u3002\u8f03\u5408\u7406\u7684\u65b9\u6cd5\u662f\u540c\u6642\u5f15\u5165\u785d\u9178\u9e7d\u8207As<sub>2<\/sub>O<sub>3<\/sub>\u3002\u6216Sb<sub>2<\/sub>O<sub>3<\/sub>\uff0c\u9019\u6a23\u4f4e\u6eab\u6642\u785d\u9178\u9e7d\u653e\u51fa\u7684\u6c27\u53ef\u5c07\u5b83\u5011\u6c27\u5316\u6210As<sub>2<\/sub>O<sub>5<\/sub>\u6216US\u201d&gt;Sb<sub>2<\/sub>O<sub>5<\/sub>\uff0c\u9ad8\u6eab\u6642As<sub>2<\/sub>O<sub>5<\/sub>\u6216Sb<sub>2<\/sub>O<sub>5<\/sub>\u5c07\u653e\u51fa\u6c27\u6c23\u4f7fFeO\u6c27\u5316\u6210Fe<sub>2<\/sub>O<sub>3<\/sub>\u3002<\/p>\n<p>\u7269\u7406\u812b\u8272\u5291\u2013\u5316\u5b78\u812b\u8272\u7684\u4f5c\u7528\u662f\u4f7f\u6709\u8272\u96e2\u5b50\u7684\u8457\u8272\u5f37\u5ea6\u6e1b\u5f31\uff0c\u4f46\u4e0d\u80fd\u4f7f\u4e4b\u6d88\u9664\u3002\u7269\u7406\u812b\u8272\u5247\u662f\u57fa\u65bc\u5f15\u5165\u9069\u7576\u7684\u8457\u8272\u5291\uff0c\u4f86\u4e2d\u548c\u539f\u4f86\u7684\u8272\u8abf\u3002\u5982\u9435\u96e2\u5b50\u4f7f\u73bb\u7483\u5448\u9ec3\u7da0\u8272\uff0c\u7576\u5f15\u5165\u80fd\u7522\u751f\u85cd\u7d2b\u8272\u7684\u6c27\u5316\u4e9e\u9237\u3001\u6c27\u5316\u4e9e\u93b3\u3001\u6c27\u5316\u9333\u548c\u6c27\u5316\u91f9\u6642\uff0c\u7531\u65bc\u85cd\u7d2b\u8272\u8207\u9ec3\u7da0\u8272\u4e92\u70ba\u88dc\u8272\uff0c\u56e0\u6b64\u80fd\u8d77\u5230\u660e\u986f\u7684\u812b\u8272\u6548\u679c\u3002\u7269\u7406\u812b\u8272\u7684\u7f3a\u9ede\u662f\u5149\u5438\u6536\u589e\u5927\uff0c\u5149\u7684\u7e3d\u900f\u904e\u7387\u4e0b\u964d\u3002\u56e0\u800c\uff0c\u7576\u73bb\u7483\u4e2d\u6c27\u5316\u9435\u542b\u91cf\u8f03\u4f4e\u6642\uff08\u901a\u5e38\u57280.06\uff05\uff5e0.07\uff05\u4ee5\u4e0b\uff09\uff0c\u7269\u7406\u812b\u8272\u7684\u6548\u679c\u8f03\u597d\u3002<\/p>\n<p>&nbsp;<\/p>\n<hr \/>\n<p>\u2728\u5ef6\u4f38\u95b1\u8b80\uff1a\u300a<a href=\"https:\/\/case.ntu.edu.tw\/blog\/?p=43831\" target=\"_blank\" rel=\"noopener\">\u73bb\u7483 (Glass)\uff08\u4e8c\uff09<\/a>\u300b<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u64b0\u6587\uff5c\u81fa\u5317\u5e02\u7acb\u7b2c\u4e00\u5973\u5b50\u9ad8\u7d1a\u4e2d\u5b78\u5316\u5b78\u79d1 \u4f55<\/p>\n","protected":false},"author":20,"featured_media":43830,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[32,3293,7011],"tags":[7013,429,413],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2024\/03\/\u73bb\u7483-scaled.jpg","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/43829"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=43829"}],"version-history":[{"count":3,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/43829\/revisions"}],"predecessor-version":[{"id":43836,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/43829\/revisions\/43836"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/43830"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=43829"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=43829"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=43829"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}