{"id":42825,"date":"2023-08-15T18:00:34","date_gmt":"2023-08-15T10:00:34","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=42825"},"modified":"2023-08-14T15:03:14","modified_gmt":"2023-08-14T07:03:14","slug":"%e7%9f%b3%e5%a2%a8%e7%83%af%e8%88%87%e5%ae%83%e7%9a%84%e5%a5%bd%e6%9c%8b%e5%8f%8b-%e5%85%ad%e8%a7%92%e7%a1%bc%e6%b0%ae","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=42825","title":{"rendered":"\u77f3\u58a8\u70ef\u8207\u5b83\u7684\u597d\u670b\u53cb\u2014\u2014\u516d\u89d2\u787c\u6c2e"},"content":{"rendered":"

\u767d\u77f3\u58a8\u7a00 (h-BN) \u4f5c\u70ba\u77f3\u58a8\u7a00\u7684\u597d\u670b\u53cb\uff0c\u4e0d\u53ea\u8207\u77f3\u58a8\u7a00\u6709\u76f8\u4f3c\u7684\u7279\u6027\uff0c\u9084\u80fd\u4f7f\u77f3\u58a8\u7a00\u6709\u66f4\u5353\u8d8a\u7684\u8868\u73fe\u3002h-BN\u5177\u6709\u9ad8\u786c\u5ea6\u3001\u9ad8\u5f48\u6027\u548c\u9ad8\u5c0e\u71b1\u6027\uff0c\u4e26\u64c1\u6709\u512a\u7570\u7684\u5316\u5b78\u7a69\u5b9a\u6027\u548c\u6297\u6c27\u5316\u80fd\u529b\u3002h-BN\u7d55\u7de3\u7684\u7279\u6027\u53ef\u4f5c\u70ba\u539f\u5b50\u7d1a\u7684\u80fd\u969c\uff0c\u88ab\u8996\u70ba\u61c9\u7528\u65bc\u91cf\u5b50\u7a7f\u96a7\u5143\u4ef6\u7684\u7406\u60f3\u6750\u6599\u3002\u6b64\u5916\uff0c\u5b83\u5728\u96fb\u5b50\u5143\u4ef6\u88fd\u9020\u4e2d\u53ef\u4f5c\u70ba\u5805\u56fa\u7684\u4fdd\u8b77\u5c64\uff0c\u9632\u6b62\u4fb5\u8755\u3002\u4f5c\u70ba\u77f3\u58a8\u7a00\u7684\u57fa\u677f\u6750\u6599\uff0ch-BN\u7684\u7d50\u69cb\u8207\u77f3\u58a8\u7a00\u76f8\u4f3c\u4e14\u8868\u9762\u5e73\u5766\uff0c\u80fd\u63d0\u5347\u77f3\u58a8\u7a00\u7684\u5c0e\u96fb\u6027\u9054\u4e09\u500d\u4e4b\u591a\u3002\u7136\u800c\uff0c\u88fd\u5099\u9ad8\u54c1\u8cea\u7684h-BN\u9700\u8981\u5728\u9ad8\u6eab\u548c\u9ad8\u771f\u7a7a\u7684\u74b0\u5883\u4e0b\uff0c\u79d1\u5b78\u5bb6\u5011\u6b63\u81f4\u529b\u65bc\u958b\u767c\u65b0\u7684\u88fd\u7a0b\u65b9\u6cd5\u4ee5\u5be6\u73fe\u5546\u696d\u5316\u751f\u7522\u3002<\/strong><\/span><\/p>\n

\u64b0\u6587\uff5c\u9ec3\u9f0e\u921e<\/strong><\/p>\n

\u77f3\u58a8\u7a00 (graphene) \u88ab\u8996\u70ba\u672c\u4e16\u7d00\u6700\u5922\u5e7b\u7684\u6750\u6599\u4e4b\u4e00\uff0c\u5b83\u6253\u958b\u4e86\u5948\u7c73\u79d1\u6280\u5168\u65b0\u7684\u8996\u91ce\uff0c\u5b83\u5177\u6709\u9ad8\u786c\u5ea6\u3001\u9ad8\u5f48\u6027\u3001\u9ad8\u5c0e\u96fb\u6027\u548c\u9ad8\u5c0e\u71b1\u6027\u7684\u7279\u6027\uff0c\u4e14\u50c5\u5177\u4e00\u5c64\u539f\u5b50\u5c64\u7684\u539a\u5ea6\uff0c\u53c8\u88ab\u7a31\u70ba\u4e8c\u7dad\u6750\u6599\uff0c\u53ef\u4ee5\u9032\u4e00\u6b65\u5fae\u7e2e\u5143\u4ef6\u3002\u5148\u524d\u7684\u6587\u7ae0\u300a\u5e02\u9762\u4e0a\u7684\u77f3\u58a8\u70ef\u7522\u54c1\uff0c\u771f\u7684\u6709\u90a3\u9ebc\u53b2\u5bb3\u55ce\uff1f<\/a>\u300b\u4ecb\u7d39\u4e86\u77f3\u58a8\u70ef\u7684\u7279\u6027\u548c\u88fd\u5099\u904e\u7a0b\uff0c\u4ee5\u53ca\u4e16\u754c\u5404\u570b\u5c0d\u77f3\u58a8\u70ef\u7814\u7a76\u7684\u71b1\u70c8\u95dc\u6ce8\u3002\u82e5\u4f60\u4e5f\u662f\u77f3\u58a8\u7a00\u7684\u7c89\u7d72\uff0c\u90a3\u9ebc\u4f60\u4e00\u5b9a\u8981\u8a8d\u8b58\u5b83\u7684\u597d\u670b\u53cb\u300c\u767d\u77f3\u58a8\u7a00\u300d(White graphene)\uff0c\u6b63\u5982\u559c\u6b61\u559d\u9ed1\u5496\u5561\u7684\u4eba\u4e5f\u6703\u77e5\u9053\u6709\u767d\u5496\u5561\uff0c\u4ed6\u5011\u90fd\u662f\u5496\u5561\uff0c\u53ea\u662f\u4e00\u500b\u6709\u52a0\u725b\u5976\u3002\u767d\u77f3\u58a8\u70ef\u8207\u77f3\u58a8\u70ef\u6709\u8a31\u591a\u76f8\u4f3c\u4e4b\u8655\uff0c\u4f46\u4e5f\u6709\u622a\u7136\u4e0d\u540c\u7684\u5730\u65b9\u3002<\/p>\n

 <\/p>\n

\"\"
\u57161\uff1a\u77f3\u58a8\u70ef\u662f\u5922\u5e7b\u7684\u6750\u6599\uff0c\u4f46\u7576\u5b83\u9047\u898b\u597d\u670b\u53cb\u787c\u6c2e\u6642\uff0c\u6bd4\u8d77\u666e\u901a\u670b\u53cb\u77fd\u6676\u5713\u518d\u4e00\u8d77\uff0c\u5c0e\u96fb\u5ea6\u53ef\u4ee5\u63d0\u9ad8\u4e09\u500d\uff01\u770b\u4f86\u7d50\u4ea4\u5230\u597d\u670b\u53cb\u5f88\u91cd\u8981\u5462\uff01\uff5c\u4f86\u6e90\uff1a\u4f5c\u8005\u63d0\u4f9b<\/figcaption><\/figure>\n

 <\/p>\n

 <\/h6>\n
\u77f3\u58a8\u70ef\u7684\u597d\u670b\u53cb\u2014\u2014\u516d\u65b9\u787c\u6c2e<\/strong><\/span><\/h6>\n

\u767d\u77f3\u58a8\u7a00\uff0c\u6b63\u5f0f\u540d\u7a31\u70ba\u516d\u65b9\u787c\u6c2e (h-BN, Hexagonal boron nitride)\uff0c\u662f\u7531\u787c\u539f\u5b50 (Boron) \u548c\u6c2e\u539f\u5b50 (Nitride) \u4ee5\u516d\u89d2\u8702\u5de2\u7d50\u69cb\u7d44\u6210\u3002\u787c\u6c2e\u8207\u77f3\u58a8\u7684\u6392\u5217\u65b9\u5f0f\u76f8\u4f3c\uff0c\u4f46\u539f\u5b50\u9593\u8ddd\u7a0d\u6709\u4e0d\u540c\uff0c\u787c\u6c2e\u7684\u539f\u5b50\u9593\u8ddd\u70ba2.459\u57c3\uff0c\u800c\u77f3\u58a8\u7a00\u7684\u539f\u5b50\u9593\u8ddd\u5247\u70ba2.504\u57c3\uff1b\u6b64\u5916\uff0c\u787c\u6c2e\u548c\u77f3\u58a8\u7a00\u5c64\u8207\u5c64\u4e4b\u9593\u7684\u8ddd\u96e2\u5206\u5225\u70ba3.33\u57c3\u548c3.354\u57c3\u3002\u7531\u65bc\u787c\u6c2e\u7684\u7d50\u69cb\u8207\u77f3\u58a8\u7a00\u975e\u5e38\u76f8\u4f3c\uff0c\u56e0\u6b64\u5b83\u53c8\u6709\u4e86\u300c\u767d\u77f3\u58a8\u7a00\u300d\u7684\u7a31\u865f\u3002\uff08\u57c3 (\u00c5) \u662f\u4e00\u500b\u5e38\u7528\u7684\u9577\u5ea6\u55ae\u4f4d\uff0c1\u57c3\u4ee3\u886810-10\u516c\u5c3a\uff0c\u7528\u65bc\u63cf\u8ff0\u539f\u5b50\u9593\u7684\u8ddd\u96e2\u3002\uff09<\/p>\n

\u73fe\u5728\u8b93\u6211\u5011\u4f86\u77ad\u89e3\u4e00\u4e0b\u787c\u6c2e\u5728\u9032\u5165\u5948\u7c73\u79d1\u6280\u4e4b\u524d\u7684\u89d2\u8272\u3002\u5728\u5de5\u696d\u61c9\u7528\u4e2d\uff0c\u6a5f\u81fa\u7684\u904b\u4f5c\u6703\u5c0e\u81f4\u74b0\u5883\u6eab\u5ea6\u63d0\u5347\uff0c\u751a\u81f3\u9700\u8981\u5728\u9ad8\u6eab\u74b0\u5883\u4e0b\u9032\u884c\u5404\u7a2e\u5de5\u85dd\u3002\u787c\u6c2e\u662f\u4e00\u7a2e\u5728\u9ad8\u6eab\u4e0b\u4fdd\u6301\u5176\u60f0\u6027\u7684\u7269\u8cea\uff0c\u4e14\u787c\u6c2e\u7684\u5c64\u8207\u5c64\u4e4b\u9593\u7684\u9023\u7d50\u529b\u76f8\u5c0d\u8f03\u5f31\uff0c\u5bb9\u6613\u525d\u843d\uff0c\u56e0\u6b64\u5e38\u88ab\u7528\u4f5c\u6f64\u6ed1\u5291\u3002\u9664\u6b64\u4e4b\u5916\uff0c\u787c\u6c2e\u9084\u5177\u6709\u6975\u5f37\u7684\u6297\u6c27\u5316\u80fd\u529b\u548c\u512a\u7570\u7684\u5316\u5b78\u7a69\u5b9a\u6027\uff0c\u9019\u4f7f\u5f97\u5b83\u6210\u70ba\u4e00\u7a2e\u5e38\u898b\u7684\u5de5\u696d\u5857\u5c64\u3002\u7c21\u8a00\u4e4b\uff0c\u787c\u6c2e\u662f\u4e00\u7a2e\u5e38\u88ab\u61c9\u7528\u65bc\u5de5\u696d\u8a2d\u5099\u4f86\u514d\u65bc\u640d\u58de\u53ca\u8150\u8755\u7684\u6750\u6599\u3002<\/p>\n

\"\"
\u57162\uff1a\u77f3\u58a8\u8207\u787c\u6c2e\u7684\u6676\u683c\u8ddd\u96e2\u53ca\u5c64\u8207\u5c64\u4e4b\u9593\u7684\u9593\u8ddd\uff5c\u4f86\u6e90\uff1a\u4f5c\u8005\u63d0\u4f9b<\/figcaption><\/figure>\n

 <\/p>\n

\u8d85\u5f37\u5c0e\u9ad4\u77f3\u58a8\u70ef\u7684\u597d\u670b\u53cb\u662f\u8d85\u5f37\u7d55\u7de3\u9ad4\u7684\u516d\u89d2\u787c\u6c2e<\/span><\/strong><\/h6>\n

\u6b63\u5982\u6211\u5011\u5c07\u77f3\u58a8\u5c64\u5c64\u5206\u96e2\u800c\u5f97\u5230\u55ae\u5c64\u539f\u5b50\u5c64\u77f3\u58a8\u7a00\u4e00\u6a23\uff0c\u82e5\u6211\u5011\u5c07\u787c\u6c2e\u5c64\u5c64\u5206\u96e2\uff0c\u4e5f\u7d42\u5c07\u5f97\u5230\u5176\u55ae\u5c64\u539f\u5b50\u5c64\uff0c\u4ee5\u4e0b\u6211\u5011\u4ee5h-BN\u4f86\u8868\u793a\u787c\u6c2e\u7684\u4e8c\u7dad\u72c0\u614b\u3002h-BN\u548c\u77f3\u58a8\u7a00\u5177\u6709\u8a31\u591a\u76f8\u540c\u7684\u7279\u6027\uff0c\u4f8b\u5982\u9ad8\u786c\u5ea6\u3001\u9ad8\u5f48\u6027\u548c\u512a\u7570\u7684\u5c0e\u71b1\u6027\uff0c\u7136\u800c\u5b83\u5011\u6700\u5927\u7684\u4e0d\u540c\u4e4b\u8655\u5728\u65bc\u96fb\u6027\u3002h-BN\u662f\u4e00\u7a2e\u96fb\u7684\u7d55\u7de3\u9ad4\uff0c\u5177\u67096.07\u96fb\u5b50\u4f0f\u7279\u7684\u80fd\u9699\uff1b\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u4f5c\u70ba\u5c0e\u9ad4\u7684\u77f3\u58a8\u7a00\u5177\u6709\u96f6\u80fd\u9699\uff0c\u662f\u4e00\u7a2e\u51fa\u8272\u7684\u5c0e\u9ad4\u3002\u6b63\u56e0\u5982\u6b64\uff0c\u79d1\u5b78\u5bb6\u5c07h-BN\u8996\u70ba\u69cb\u6210\u539f\u5b50\u7d1a\u80fd\u969c\u7684\u7406\u60f3\u6750\u6599\uff0c\u671f\u671b\u5c07\u5176\u61c9\u7528\u65bc\u91cf\u5b50\u7a7f\u96a7\u5143\u4ef6\u4e2d\uff0c\u6b32\u77ad\u89e3\u8a73\u60c5\uff0c\u53ef\u53c3\u8003\u300a\u7a7f\u7246\u8d85\u80fd\u529b\uff1f\u91cf\u5b50\u7269\u7406\u7684\u7a7f\u96a7\u6548\u61c9<\/a>\u300b\u3002<\/p>\n

\u53e6\u4e00\u500b\u8207\u77f3\u58a8\u7a00\u4e0d\u540c\u7684\u5730\u65b9\u662f\uff0ch-BN\u4e2d\u7684\u539f\u5b50\u5f7c\u6b64\u4ee5\u96e2\u5b50\u9375\u9023\u7d50\uff0c\u800c\u77f3\u58a8\u7a00\u5247\u662f\u4ee5\u5171\u50f9\u9375\u9023\u7d50\u3002\u5728h-BN\u4e2d\uff0c\u6c2e\u539f\u5b50\u5931\u53bb\u96fb\u5b50\uff0c\u787c\u539f\u5b50\u7372\u5f97\u96fb\u5b50\uff0c\u5f62\u6210\u96e2\u5b50\u9375\uff0c\u9019\u7a2e\u6b63\u8ca0\u96e2\u5b50\u7684\u5438\u5f15\u589e\u5f37\u4e86h-BN\u539f\u5b50\u4e4b\u9593\u7684\u9375\u7d50\u529b\uff0c\u4f7f\u5176\u6bd4\u77f3\u58a8\u7a00\u5177\u6709\u66f4\u5f37\u7684\u9375\u7d50\u529b\u3002\u56e0\u6b64\uff0ch-BN\u53ef\u4ee5\u4f5c\u70ba\u975e\u5e38\u5805\u56fa\u7684\u4fdd\u8b77\u5c64\uff0c\u5728\u96fb\u5b50\u5143\u4ef6\u7684\u88fd\u9020\u904e\u7a0b\u4e2d\uff0c\u4fdd\u8b77\u6750\u6599\u514d\u53d7\u5230\u5176\u4ed6\u5316\u5b78\u85e5\u54c1\u7684\u4fb5\u8755\u3002<\/p>\n

\"\"
\u57163\uff1a\u5c07h-BN\u8986\u84cb\u5728\u7269\u9ad4\u8868\u9762\u589e\u5f37\u5176\u6297\u8150\u8755\u6027\u793a\u610f\u5716\uff0ch-BN\u4ee5\u516d\u89d2\u8702\u5de2\u7684\u5f62\u72c0\u5206\u5e03\uff5c\u4f86\u6e90\uff1aMicrosoft Bing AI\u751f\u6210<\/figcaption><\/figure>\n

 <\/p>\n

\u7576\u77f3\u58a8\u70ef\u8207\u597d\u670b\u53cbh-BN\u5728\u4e00\u8d77\u6642<\/strong><\/span><\/h6>\n

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h-BN\u7684\u88fd\u5099\u65b9\u6cd5\u4e3b\u8981\u662f\u5229\u7528\u5316\u5b78\u6c23\u76f8\u6c89\u7a4d\u6cd5 (Chemical Vapor Deposition, CVD)\uff0c\u4e26\u4ee5\u6c28\u787c\u70f7(NH3-BH3) \u4f5c\u70ba\u7269\u8cea\u4f86\u6e90\uff0c\u9019\u7a2e\u65b9\u6cd5\u8207\u77f3\u58a8\u7a00\u7684\u88fd\u5099\u65b9\u6cd5\u76f8\u4f3c\u3002\u7136\u800c\uff0c\u70ba\u4e86\u7372\u5f97\u9ad8\u54c1\u8cea\u7684h-BN\uff0c\u9700\u8981\u5728\u9ad8\u6eab\uff08\u8d85\u904e1000 \u00b0C\uff09\u548c\u9ad8\u771f\u7a7a\u7684\u74b0\u5883\u4e0b\u9032\u884c\u3002\u5982\u679c\u8981\u5927\u91cf\u88fd\u9020\u9ad8\u54c1\u8cea\u7684h-BN\u4ee5\u5be6\u73fe\u5546\u696d\u5316\uff0c\u5c31\u9700\u8981\u958b\u767c\u51fa\u80fd\u5920\u5728\u8f03\u4f4e\u7684\u6eab\u5ea6\u548c\u4f4e\u771f\u7a7a\u74b0\u5883\u4e2d\u91cf\u7522\u7684\u65b0\u88fd\u7a0b\u65b9\u6cd5\uff0c\u70ba\u4e86\u514b\u670d\u9019\u500b\u6311\u6230\uff0c\u79d1\u5b78\u5bb6\u5011\u6b63\u5728\u52aa\u529b\u5c0b\u6c42\u7a81\u7834\u3002\u76f8\u4fe1\u7576\u4eba\u5011\u5c0d\u65bc\u4e8c\u7dad\u6750\u6599\u53c8\u6709\u66f4\u591a\u7684\u8a8d\u8b58\u6642\uff0c\u900f\u904e\u4e0d\u540c\u7684\u6750\u6599\u7d44\u5408\uff0c\u5c07\u6703\u5e36\u9818\u5948\u7c73\u79d1\u6280\u66f4\u4e0a\u4e00\u5c64\u6a13\uff01<\/p>\n

 <\/p>\n

\n

\u53c3\u8003\u6587\u737b<\/strong><\/p>\n

    \n
  1. A. Gupta & T. Sakthivel & S. Seal, 2015, \u201cRecent development in 2D materials beyond graphene.\u201d, Progress in Materials Science<\/em>, 73, 44\u2013126.<\/a><\/li>\n
  2. C. R. Dean & A. F. Young & I. Meric & C. Lee & L. Wang & S. Sorgenfrei & K. Watanabe & T. Taniguchi & P. Kim & K. L. Shepard & J. Hone, 2010, \u201cBoron nitride substrates for high-quality graphene electronics.\u201d, Nature Nanotechnology<\/em>, 5(10), 722\u2013726.<\/a><\/li>\n
  3. K. H. Lee & H. Shin & J. Lee & I. Lee & G. Kim & J. Choi & S. Kim, 2012, \u201cLarge-Scale synthesis of High-Quality hexagonal boron nitride nanosheets for Large-Area graphene electronics.\u201d, Nano Letters<\/em>, 12(2), 714\u2013718.<\/a><\/li>\n<\/ol>\n

     <\/p>\n

    \n

    📖 \u5ef6\u4f38\u95b1\u8b80\uff1a\u300a\u5e02\u9762\u4e0a\u7684\u77f3\u58a8\u70ef\u7522\u54c1\uff0c\u771f\u7684\u6709\u90a3\u9ebc\u53b2\u5bb3\u55ce\uff1f<\/a>\u300b\u3001\u300a\u7a7f\u7246\u8d85\u80fd\u529b\uff1f\u91cf\u5b50\u7269\u7406\u7684\u7a7f\u96a7\u6548\u61c9<\/a>\u300b<\/p>\n","protected":false},"excerpt":{"rendered":"

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