{"id":35892,"date":"2020-12-18T00:45:28","date_gmt":"2020-12-17T16:45:28","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=35892"},"modified":"2021-06-09T11:08:26","modified_gmt":"2021-06-09T03:08:26","slug":"%e8%b3%a6%e4%ba%88%e5%a1%91%e8%86%a0%e8%a2%8b%e6%96%b0%e7%94%9f%e5%91%bd","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=35892","title":{"rendered":"\u8ce6\u4e88\u5851\u81a0\u888b\u65b0\u751f\u547d"},"content":{"rendered":"

\u7576\u793e\u6703\u5927\u773e\u9010\u6f38\u610f\u8b58\u5230\u5851\u81a0\u5783\u573e\u9020\u6210\u7684\u5065\u5eb7\u8207\u74b0\u5883\u554f\u984c\uff0c\u56de\u6536\u3001\u6e1b\u7528\u5851\u81a0\u88fd\u54c1\u6210\u4e86\u7576\u524d\u7684\u91cd\u8981\u8b70\u984c\u3002\u5982\u4f55\u66f4\u7d93\u6fdf\u3001\u66f4\u74b0\u4fdd\u5730\u518d\u5229\u7528\u9019\u4e9b\u5851\u81a0\u5ee2\u68c4\u7269\uff0c\u662f\u79d1\u5b78\u5bb6\u5011\u4e00\u76f4\u60f3\u89e3\u6c7a\u7684\u554f\u984c\u3002\u73fe\u5728\uff0c\u79d1\u5b78\u5bb6\u5011\u6709\u4e86\u65b0\u7684\u89e3\u7b54\uff1a\u5229\u7528\u9251\u50ac\u5316\u5291\uff0c\u53ef\u4ee5\u5c07\u805a\u4e59\u70ef\u88fd\u54c1\u5347\u7d1a\u518d\u9020\uff0c\u751f\u6210\u5177\u6709\u9ad8\u9644\u52a0\u50f9\u503c\u7684\u82b3\u9999\u70f4\u985e\u5316\u5408\u7269\u3002<\/strong><\/span><\/p>\n

\"\"
\u5716\u7247\u4f86\u6e90\uff1apxfuel<\/figcaption><\/figure>\n

\u64b0\u6587\uff0f<\/strong>\u912d\u7433\u6f54<\/strong><\/p>\n

\u805a\u4e59\u70ef\uff08PE\uff09\u662f\u751f\u6d3b\u4e2d\u5e38\u898b\u7684\u5851\u81a0\u539f\u6599\uff0c\u8209\u51e1\u8cfc\u7269\u7528\u7684\u5851\u81a0\u63d0\u888b\u3001\u5bf6\u7279\u74f6\u7684\u84cb\u5b50\u3001\u7259\u818f\u7684\u8edf\u7ba1\u90fd\u662f\u7531\u805a\u4e59\u70ef\u88fd\u6210\u3002\u5177\u6709\u5f48\u6027\u4e14\u96e3\u4ee5\u8150\u8755\u7684\u7279\u9ede\uff0c\u8ce6\u4e88\u805a\u4e59\u70ef\u5ee3\u6cdb\u7684\u7528\u9014\u3002\u6bcf\u5e74\u7522\u503c\u9ad8\u905420\u5104\u7f8e\u91d1\uff0c\u4f54\u5168\u7403\u5851\u6599\u5e02\u5834\u7684\u4e09\u5206\u4e4b\u4e00\u3002\u4f46\u5b89\u5b9a\u7684\u6027\u8cea\u540c\u6642\u4e5f\u662f\u4e00\u628a\u96d9\u9762\u5203\uff0c\u6d41\u5165\u81ea\u7136\u74b0\u5883\u7684\u805a\u4e59\u70ef\u88fd\u54c1\uff0c\u5e7e\u4e4e\u4e0d\u6703\u8207\u4efb\u4f55\u6771\u897f\u53cd\u61c9\uff0c\u9020\u6210\u56b4\u91cd\u7684\u6c61\u67d3\u554f\u984c\u3002<\/p>\n

\u9664\u4e86\u5c0b\u627e\u66ff\u4ee3\u6750\u6599\u6216\u958b\u767c\u5177\u6709\u751f\u7269\u5206\u89e3\u6027\u7684\u7522\u54c1\uff0c\u5982\u4f55\u8655\u7406\u5927\u91cf\u5df2\u7d93\u6d41\u5165\u5e02\u9762\u7684\u805a\u4e59\u70ef\u88fd\u54c1\u4ecd\u662f\u500b\u68d8\u624b\u7684\u8b70\u984c\u3002\u4eca\u5e74\u5341\u6708\uff0c\u79d1\u5b78\u5bb6\u5011\u70ba\u9019\u9805\u96e3\u984c\u63d0\u51fa\u4e86\u65b0\u7684\u89e3\u6c7a\u8fa6\u6cd5\uff1a\u5c07\u5ee2\u68c4\u7684\u805a\u4e59\u70ef\u8f49\u5316\u6210\u5177\u9577\u78b3\u93c8\u7684\u82b3\u9999\u70f4\u5316\u5408\u7269\uff0c\u9019\u4e9b\u82b3\u9999\u70f4\u5316\u5408\u7269\u53ef\u4ee5\u7528\u65bc\u88fd\u9020\u6709\u6a5f\u6eb6\u5291\u3001\u6f64\u6ed1\u6cb9\u6216\u662f\u6e05\u6f54\u5291\u3002\u7814\u7a76\u7684\u6210\u679c\u767c\u8868\u65bc\u570b\u969b\u671f\u520a Science<\/em>\u3002<\/p>\n

\u904e\u53bb\uff0c\u4f7f\u7528\u77f3\u5316\u539f\u6599\u88fd\u9020\u9577\u78b3\u93c8\u82b3\u9999\u70f4\u5316\u5408\u7269\u7684\u65b9\u6cd5\uff0c\u5f80\u5f80\u6d89\u53ca500\u52301000\u5ea6\u7684\u53cd\u61c9\u53ca\u591a\u500b\u53cd\u61c9\u6b65\u9a5f\u3002\u800c\u805a\u4e59\u70ef\u7684\u71b1\u88c2\u89e3\u5247\u9700\u8981400\u5ea6\u4ee5\u4e0a\u7684\u9ad8\u6eab\u53ca\u5927\u91cf\u7684\u6c2b\u6c23\uff0c\u800c\u4e14\u5f80\u5f80\u53ea\u80fd\u751f\u6210\u96e3\u4ee5\u518d\u61c9\u7528\u7684\u6c23\u614b\u70f7\u57fa\u5316\u5408\u7269\u53ca\u7126\u70ad\uff08char\uff09\u3002<\/p>\n

\u52a0\u5dde\u5927\u5b78\u8056\u82ad\u82ad\u62c9\u5206\u6821\u7684\u7814\u7a76\u5718\u968a\u6240\u63d0\u51fa\u7684\u65b9\u6cd5\uff0c\u4f7f\u7528\u5d4c\u6709\u9251\u5948\u7c73\u7c92\u5b50\u7684\u6c27\u5316\u92c1\u4f5c\u70ba\u53cd\u61c9\u7684\u50ac\u5316\u5291\uff0c\u5728280\u5ea6\u672a\u63d0\u4f9b\u6c2b\u6c23\u7684\u74b0\u5883\u4e0b\uff0c\u53cd\u61c924\u523036\u5c0f\u6642\uff0c\u53ef\u4ee5\u6210\u529f\u5c07\u805a\u4e59\u70ef\u8f49\u5316\u70ba\u82b3\u9999\u70f4\u5316\u5408\u7269\u3002\u9019\u500b\u53cd\u61c9\u53ef\u4ee5\u5728\u55ae\u4e00\u500b\u53cd\u61c9\u5bb9\u5668\u4e2d\u4e00\u6b21\u6027\u7684\u5b8c\u6210\uff08one-pot reaction\uff09\u3002\u82b3\u9999\u70f4\u7684\u7522\u7269\u5e73\u5747\u5177\u670930\u500b\u78b3\uff0c\u5927\u90e8\u5206\u662f\u5177\u6709\u76f4\u93c8\u70f7\u57fa\u7684\u82ef\u96d9\u53d6\u4ee3\u5316\u5408\u7269\u3002<\/p>\n

\u9019\u500b\u53cd\u61c9\u7684\u6210\u529f\uff0c\u8207\u80cc\u5f8c\u6d89\u53ca\u7684\u71b1\u529b\u5b78\u6709\u8457\u5bc6\u5207\u7684\u95dc\u4fc2\u3002\u70f7\u70f4\u985e\u7684\u53cd\u61c9\u7269\u751f\u6210\u82b3\u9999\u70f4\u5316\u5408\u7269\uff0c\u9700\u8981\u7d93\u904e\u82b3\u69cb\u53cd\u61c9\uff08aromatization\uff09\uff0c\u82b3\u69cb\u53cd\u61c9\u662f\u4e00\u500b\u5438\u71b1\u53cd\u61c9\uff0c\u4e26\u6703\u4f34\u96a8\u5927\u91cf\u7684\u6c2b\u6c23\u751f\u6210\u3002\u805a\u4e59\u70ef\u7684\u6c2b\u89e3\u53cd\u61c9\uff08hydrogenolysis\uff09\uff0c\u540c\u6642\u6d89\u53ca\u78b3-\u78b3\u9375\u7684\u65b7\u88c2\u53ca\u78b3-\u6c2b\u9375\u7684\u5f62\u6210\uff0c\u9664\u4e86\u662f\u653e\u71b1\u53cd\u61c9\u9084\u9700\u8981\u5927\u91cf\u7684\u6c2b\u6c23\u53c3\u8207\u3002\u56e0\u6b64\uff0c\u9019\u500b\u7814\u7a76\u4e2d\uff0c\u76f8\u4f34\u767c\u751f\uff08tandem reaction\uff09\u7684\u82b3\u69cb\u53cd\u61c9\u8207\u6c2b\u89e3\u53cd\u61c9\u6d3d\u597d\u5f4c\u88dc\u4e86\u96d9\u65b9\u7684\u9700\u6c42\u3002<\/p>\n

\u79d1\u5b78\u5bb6\u5011\u85c9\u7531\u8abf\u63a7\u53cd\u61c9\u7684\u6eab\u5ea6\uff0c\u53ef\u4ee5\u4f7f\u53cd\u61c9\u7684\u8f49\u5316\u7387\u8207\u751f\u6210\u82b3\u9999\u70f4\u7522\u7269\u7684\u9078\u64c7\u6027\u9054\u5230\u6700\u4f73\u5316\u3002\u4ed6\u5011\u4e5f\u6ce8\u610f\u5230\uff0c\u5728\u53cd\u61c9\u4e2d\u82b3\u9999\u70f4\u7522\u7269\u53ca\u8d77\u59cb\u7269\uff0c\u53ef\u80fd\u9032\u884c\u74b0\u5316\u53cd\u61c9\u91cb\u51fa\u984d\u5916\u7684\u6c2b\u6c23\uff0c\u904e\u591a\u7684\u6c2b\u6c23\u6703\u5c0e\u81f4\u7522\u7269\u88ab\u6c2b\u5316\uff0c\u9032\u800c\u7522\u751f\u8a31\u591a\u96e3\u4ee5\u518d\u5229\u7528\u7684\u70f7\u57fa\u7522\u7269\u3002\u672a\u4f86\uff0c\u5c0d\u65bc\u53cd\u61c9\u7684\u6311\u6230\u5728\u65bc\u8abf\u7bc0\u53cd\u61c9\u4e2d\u7684\u6c2b\u6c23\u542b\u91cf\u53ca\u58d3\u529b\uff1a\u6c2b\u6c23\u592a\u591a\u6703\u4fc3\u4f7f\u7522\u7269\u6c2b\u5316\uff0c\u6c2b\u6c23\u592a\u5c11\u5247\u53ef\u80fd\u7121\u6cd5\u5c07\u805a\u4e59\u70ef\u6c2b\u89e3\u3002<\/p>\n

\"\"
\u4e0a\u5716\u70ba\u7c21\u5316\u5f8c\u7684\u53cd\u61c9\u793a\u610f\u5716\uff0c\u5176\u4e2d\u6c2b\u89e3\u8207\u6c2b\u5316\u53cd\u61c9\u90fd\u9700\u8981\u6c2b\u6c23\u53c3\u8207\uff0c\u82b3\u69cb\u53ca\u74b0\u5316\u53cd\u61c9\u5247\u6703\u91cb\u51fa\u6c2b\u6c23\u3002<\/figcaption><\/figure>\n

\u7814\u7a76\u5718\u968a\u4e5f\u6e2c\u8a66\u53cd\u61c9\u7684\u50ac\u5316\u5291\u662f\u5426\u53ef\u4ee5\u5faa\u74b0\u518d\u5229\u7528\uff0c\u4f7f\u7528\u540c\u4e00\u7d44\u50ac\u5316\u5291\uff0c\u6bcf\u6b21\u53cd\u61c96\u500b\u5c0f\u6642\uff0c\u6e2c\u8a66\u4e09\u8f2a\u5faa\u74b0\u4e0b\u7522\u7387\u7684\u8b8a\u5316\u3002\u4ed6\u5011\u767c\u73fe\u7522\u7387\u5728\u7b2c\u4e8c\u6b21\u5faa\u74b0\u6642\u4e0b\u964d\u4e8615%\uff0c\u4f46\u5728\u7b2c\u4e8c\u8f2a\u53ca\u7b2c\u4e09\u8f2a\u7684\u6e2c\u8a66\u4e2d\uff0c\u805a\u4e59\u70ef\u7684\u7522\u7387\u90fd\u572855\uff05\u3002\u6b64\u5916\uff0c\u7814\u7a76\u5718\u968a\u4e5f\u5c07\u4ed6\u5011\u7684\u65b9\u6cd5\u61c9\u7528\u5728\u5e02\u552e\u7684\u805a\u4e59\u70ef\u7522\u54c1\uff0c\u4ed6\u5011\u767c\u73fe\u7121\u8ad6\u662f\u4f4e\u5bc6\u5ea6\u805a\u4e59\u70ef\uff08LDPE\uff09\u7684\u5851\u81a0\u888b\u6216\u662f\u9ad8\u5bc6\u5ea6\u805a\u4e59\u70ef\uff08HDPE\uff09\u7684\u74f6\u84cb\uff0c\u90fd\u53ef\u4ee5\u6210\u529f\u7528\u4ee5\u5408\u6210\u6db2\u614b\/\u81d8\u72c0\u7684\u82b3\u9999\u70f4\u7522\u7269\u3002<\/p>\n

\u73fe\u4eca\uff0c\u805a\u4e59\u70ef\u7684\u539f\u6599\u4e3b\u8981\u662f\u77f3\u6cb9\u8b0e\uff0c\u82b3\u9999\u70f4\u5316\u5408\u7269\u7684\u539f\u6599\u4e5f\u662f\u77f3\u6cb9\u8b0e\uff0c\u76f8\u8f03\u65bc\u77f3\u6cb9\u958b\u63a1\u4f34\u96a8\u7684\u74b0\u5883\u6210\u672c\uff0c\u4ee5\u56de\u6536\u7684\u805a\u4e59\u70ef\u4f5c\u70ba\u539f\u6599\uff0c\u5f9e\u74b0\u4fdd\u53ca\u6c38\u7e8c\u7684\u89d2\u5ea6\u662f\u53ef\u884c\u4e14\u503c\u5f97\u5617\u8a66\u7684\u3002\u672a\u4f86\uff0c\u9019\u4e9b\u6a19\u793a\u74b0\u4fdd\u6a19\u8a8c2\uff08HDPE\uff09\u82074\uff08LDPE\uff09\u7684\u5851\u81a0\u7522\u54c1\u56de\u6536\u5f8c\uff0c\u6216\u8a31\u6703\u4ee5\u622a\u7136\u4e0d\u540c\u7684\u65b9\u5f0f\u518d\u51fa\u73fe\u5728\u6211\u5011\u7684\u751f\u6d3b\u7576\u4e2d\u3002<\/p>\n

 <\/strong><\/p>\n

\u53c3\u8003\u8cc7\u6599\uff1a<\/strong><\/p>\n

    \n
  1. Polyethylene Upcycling to Long-Chain Alkylaromatics by Tandem Hydrogenolysis\/Aromatization. Science<\/em> 2020<\/strong>, 370<\/em>, 437-441 doi: doi.org\/10.1126\/science.abc5441<\/a><\/li>\n
  2. University of California, Santa Barbara<\/a>: October 20, 2020, Closing the Plastic Loop<\/a><\/li>\n
  3. Creating Value from Plastic Waste. Science<\/em> 2020<\/strong>, 370<\/em>, 400-401 doi: doi.org\/10.1126\/science.abe3873<\/a><\/li>\n<\/ol>\n","protected":false},"excerpt":{"rendered":"

    \u7576\u793e\u6703\u5927\u773e\u9010\u6f38\u610f\u8b58\u5230\u5851\u81a0\u5783\u573e\u9020\u6210\u7684\u5065\u5eb7\u8207\u74b0\u5883\u554f\u984c\uff0c\u56de\u6536\u3001\u6e1b\u7528\u5851\u81a0\u88fd\u54c1\u6210\u4e86\u7576\u524d\u7684\u91cd\u8981\u8b70\u984c\u3002\u5982\u4f55\u66f4\u7d93\u6fdf\u3001\u66f4\u74b0\u4fdd\u5730\u518d\u5229\u7528\u9019\u4e9b\u5851\u81a0\u5ee2\u68c4\u7269\uff0c\u662f\u79d1\u5b78\u5bb6\u5011\u4e00\u76f4\u60f3\u89e3\u6c7a\u7684\u554f\u984c\u3002\u73fe\u5728\uff0c\u79d1\u5b78\u5bb6\u5011\u6709\u4e86\u65b0\u7684\u89e3\u7b54\uff1a\u5229\u7528\u9251\u50ac\u5316\u5291\uff0c\u53ef\u4ee5\u5c07\u805a\u4e59\u70ef\u88fd\u54c1\u5347\u7d1a\u518d\u9020\uff0c\u751f\u6210\u5177\u6709\u9ad8\u9644\u52a0\u50f9\u503c\u7684\u82b3\u9999\u70f4\u985e\u5316\u5408\u7269\u3002<\/p>\n","protected":false},"author":20,"featured_media":35906,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[32,3293,2977],"tags":[4779,4778,4780,2815,4781],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2020\/11\/01-2.jpg","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/35892"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=35892"}],"version-history":[{"count":1,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/35892\/revisions"}],"predecessor-version":[{"id":35908,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/35892\/revisions\/35908"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/35906"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=35892"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=35892"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=35892"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}