{"id":35663,"date":"2020-09-17T00:18:24","date_gmt":"2020-09-16T16:18:24","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=35663"},"modified":"2020-09-08T15:10:07","modified_gmt":"2020-09-08T07:10:07","slug":"%e8%b6%85%e6%b5%81%e9%ab%94%e5%8f%8d%e6%87%89%e5%99%a8-%e6%8d%95%e6%8d%89%e5%96%ae%e4%b8%80%e5%8e%9f%e5%ad%90%e5%8f%8d%e6%87%89","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=35663","title":{"rendered":"\u8d85\u6d41\u9ad4\u53cd\u61c9\u5668\u2014\u2014\u6355\u6349\u55ae\u4e00\u539f\u5b50\u53cd\u61c9"},"content":{"rendered":"<p><span style=\"color: #333399;\"><strong>\u4ee5\u8d85\u6d41\u76f8\u7684\u6db2\u6c26\u4f5c\u70ba\u5948\u7c73\u7b49\u7d1a\u7684\u53cd\u61c9\u5668\uff0c\u79d1\u5b78\u5bb6\u6355\u6349\u5230\u55ae\u4e00\u91d1\u539f\u5b50\u8207\u4e8c\u5143\u9187\u751f\u6210\u7684\u51e1\u5fb7\u74e6\u7c07\u5408\u7269\uff0c\u5728\u8cea\u8b5c\u5100\u53ca\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8ad6\u7684\u8f14\u52a9\u4e0b\uff0c\u5316\u5b78\u5bb6\u5011\u5f97\u4ee5\u89e3\u6790\u55ae\u9846\u91d1\u539f\u5b50\u5982\u4f55\u5206\u89e3\u4e8c\u5143\u9187\u3002<\/strong><\/span><\/p>\n<figure id=\"attachment_35666\" aria-describedby=\"caption-attachment-35666\" style=\"width: 450px\" class=\"wp-caption alignleft\"><img fetchpriority=\"high\" decoding=\"async\" class=\"wp-image-35666\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2020\/09\/splashing-164963_640.jpg\" alt=\"\" width=\"450\" height=\"298\" srcset=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2020\/09\/splashing-164963_640.jpg 640w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2020\/09\/splashing-164963_640-300x199.jpg 300w\" sizes=\"(max-width: 450px) 100vw, 450px\" \/><figcaption id=\"caption-attachment-35666\" class=\"wp-caption-text\">\u5716\u7247\u51fa\u8655@pixabay<\/figcaption><\/figure>\n<p><strong>\u64b0\u6587\uff0f\u912d\u7433\u6f54<\/strong><\/p>\n<p>\u5927\u591a\u6578\u91d1\u5c6c\u539f\u5b50\u7684\u50ac\u5316\u5291\uff0c\u91d1\u5c6c\u539f\u5b50\u90fd\u6703\u5438\u9644\u5728\u5176\u4ed6\u56fa\u9ad4\u8868\u9762\uff0c\u5982\u92c1\u6216\u77fd\u7684\u6c27\u5316\u7269\u3002\u56e0\u70ba\u6709\u76f8\u5c0d\u5927\u7684\u8868\u9762\u7a4d\u6bd4\u9ad4\u7a4d\u503c\uff08surface-to-volume 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atom\uff09\u50ac\u5316\u4e8c\u5143\u9187\u5206\u89e3\u7684\u53cd\u61c9\uff0c\u7814\u7a76\u7d50\u679c\u88ab\u520a\u767b\u65bc\u5316\u5b78\u79d1\u5b78 \uff08Chemical Science\uff09\u3002\u5728\u9019\u500b\u53cd\u61c9\u4e2d\uff0c\u91d1\u539f\u5b50\u8207\u4e8c\u5143\u9187\u4e4b\u9593\u50c5\u50c5\u4ee5\u51e1\u5fb7\u74e6\u5f15\u529b\u727d\u5f15\uff0c\u6392\u9664\u4e86\u56fa\u614b\u8868\u9762\u53ef\u80fd\u9020\u6210\u7684\u5f71\u97ff\u3002<\/p>\n<p>\u8d85\u6d41\u9ad4\u6307\u7684\u662f\u4e00\u7a2e\u7279\u6b8a\u7684\u7269\u8cea\u578b\u614b\uff0c\u5177\u6709\u7121\u9ecf\u6027\u3001\u96f6\u71b5\u5ea6\u53ca\u7121\u9650\u5927\u7684\u71b1\u50b3\u5c0e\u7387\u7b49\u6027\u8cea\u3002\u6c26-4\u5728\u4f4e\u65bc2.2 K\uff08\u2212271\u00b0C\uff09\u7684\u74b0\u5883\u4e0b\uff0c\u5c31\u6703\u8b8a\u6210\u8d85\u6d41\u9ad4\u3002\u7576\u539f\u5b50\u6eb6\u5728\u8d85\u6d41\u76f8\u7684\u6db2\u6c26-4\u6642\uff0c\u53ef\u4ee5\u64c1\u6709\u8207\u6c23\u614b\u6642\u76f8\u540c\uff0c\u5b8c\u5168\u7684\u65cb\u8f49\u81ea\u7531\u5ea6\u3002\u56e0\u6b64\uff0c\u8d85\u6d41\u76f8\u7684\u6db2\u6c26-4\u53ef\u88ab\u7528\u505a\u91cf\u5b50\u6eb6\u5291\uff08quantum solvent\uff09\uff0c\u7814\u7a76\u539f\u5b50\u6216\u5206\u5b50\u65bc\u6c23\u614b\u4e0b\u7684\u52d5\u529b\u5b78\uff0c\u537b\u4e0d\u9700\u8981\u771f\u7684\u5c07\u7269\u8cea\u6c23\u5316\u3002\u7576\u591a\u65bc\u4e00\u500b\u539f\u5b50\u6216\u5206\u5b50\u6eb6\u65bc\u8d85\u6d41\u9ad4\u6642\uff0c\u539f\u5b50\u6216\u5206\u5b50\u6703\u50be\u5411\u751f\u6210\u5718\u7c07\u3002\u5229\u7528\u8d85\u6d41\u9ad4\u7684\u7279\u6027\uff0c\u7814\u7a76\u5718\u968a\u5f97\u4ee5\u5256\u6790\uff0c\u91d1\u5c6c\u539f\u5b50\u5728\u50ac\u5316\u53cd\u61c9\u4e2d\uff0c\u5c0d\u5206\u5b50\u7522\u751f\u7684\u76f4\u63a5\u5f71\u97ff\u662f\u4ec0\u9ebc\u3002<\/p>\n<p>\u900f\u904e\u7cbe\u78ba\u7684\u6eab\u5ea6\u63a7\u5236\uff0c\u8207\u8cea\u8b5c\u5100\u7684\u76e3\u6e2c\uff0c\u5316\u5b78\u5bb6\u5011\u53ef\u4ee5\u7cbe\u6e96\u63a7\u5236\u6bcf\u4e00\u6ef4\u6db2\u614b\u6c26\u7684\u5948\u7c73\u6db2\u73e0\uff08nanodroplets\uff09\u4e2d\u53ea\u542b\u6709\u4e00\u500b\u91d1\u539f\u5b50<sup> [\u8a3b\u3127]<\/sup>\u3002\u5948\u7c73\u6db2\u73e0\u7d93\u904e\u96fb\u96e2\u5316\uff08electron ionization\uff09\u5f8c\uff0c\u7576\u4e2d\u76841,6-\u5df1\u4e8c\u9187\uff081,6-Hexanediol\uff09\u5206\u5b50\u6703\u65b7\u88c2\u6210\u967d\u96e2\u5b50\u788e\u7247\uff0c\u5229\u7528\u8cea\u8b5c\u5206\u6790\u9019\u4e9b\u788e\u7247\u7d44\u6210\uff0c\u4ed6\u5011\u767c\u73fe\u7576\u5948\u7c73\u6db2\u73e0\u542b\u6709\u91d1\u539f\u5b50\u6642\uff0c\u53cd\u61c9\u50be\u5411\u4e3b\u8981\u751f\u6210\u78b3\u3001\u6c2b\u7684\u7522\u7269\uff08C<sub>2<\/sub>H<sub>4<\/sub><sup>+<\/sup>\uff09\u3002\u82e5\u5948\u7c73\u6db2\u73e0\u53ea\u542b\u67091,6-\u5df1\u4e8c\u9187\uff0c\u7522\u7269\u5247\u4ee5\u542b\u6709\u6c27\u539f\u5b50\u7684\u6709\u6a5f\u967d\u96e2\u5b50\uff08HCO<sup>+<\/sup>\u3001CH<sub>2<\/sub>OH<sup>+<\/sup>\uff09\u70ba\u4e3b\u3002<\/p>\n<p>\u5229\u7528\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8ad6\uff08DFT calculation, density functional theory calculation\uff09\uff0c\u79d1\u5b78\u5bb6\u5011\u53ef\u4ee5\u8a55\u4f30\u5728\u91d1\u539f\u5b50\u82071,6-\u5df1\u4e8c\u9187\u4f5c\u7528\u904e\u7a0b\u4e2d\uff0c\u5206\u5b50\u5167\u9375\u80fd\u7522\u751f\u7684\u8b8a\u5316\u3002\u7814\u7a76\u5718\u968a\u767c\u73fe\uff0c\u7576\u91d1\u82071,6-\u5df1\u4e8c\u9187\u751f\u6210\u5e36\u6b63\u96fb\u7684\u7c07\u5408\u7269\u6642\uff0c\u76f8\u8f03\u65bc\u55ae\u4e00\u76841,6-\u5df1\u4e8c\u9187\u5206\u5b50\uff0c\u5176\u7c07\u5408\u7269\u5167\u78b3\uff0d\u78b3\u9375\uff08C-C bond\uff09\u7684\u9375\u80fd\u8b8a\u5f37\uff0c\u78b3\uff0d\u6c27\u9375\uff08C-O bond\uff09\u7684\u9375\u80fd\u537b\u4e0b\u964d\u8a31\u591a\u3002\u56e0\u70ba\u78b3\uff0d\u6c27\u9375\u8b8a\u5f97\u8106\u5f31\uff0c\u5728\u89e3\u96e2\uff08dissociation\uff09\u7684\u904e\u7a0b\u4e2d\uff0c\u6703\u7387\u5148\u65b7\u88c2\u3002\u9019\u4f50\u8b49\u4e86\u70ba\u4f55\u8cea\u8b5c\u4e0a\u542b\u6709\u91d1\u539f\u5b50\u7684\u6a23\u54c1\uff0c\u7522\u7269\u4ee5\u53ea\u542b\u78b3\u3001\u6c2b\u7684\u967d\u96e2\u5b50\u70ba\u4e3b\u3002<\/p>\n<p>\u5c0d\u65bc\u4e00\u500b\u5316\u5b78\u53cd\u61c9\u7684\u9078\u64c7\u6027\u4f86\u8aaa\uff0c\u7279\u5b9a\u5316\u5b78\u9375\u7684\u65b7\u88c2\uff0c\u53ef\u80fd\u662f\u5f71\u97ff\u9078\u64c7\u6027\u6700\u91cd\u8981\u7684\u95dc\u9375\u3002\u50ac\u5316\u5291\u7684\u5b58\u5728\u5f80\u5f80\u53d6\u6c7a\u65bc\uff0c\u91d1\u5c6c\u539f\u5b50\u662f\u5426\u80fd\u5f71\u97ff\u904e\u6e21\u614b\u7684\u9375\u80fd\uff0c\u9032\u4e00\u6b65\u5f71\u97ff\u53cd\u61c9\u9032\u884c\u7684\u8def\u5f91\u3002\u5206\u5b50\u5c64\u7d1a\u7684\u7814\u7a76\uff0c\u53ef\u4ee5\u5e6b\u52a9\u79d1\u5b78\u5bb6\u5011\u4e86\u89e3\u4e00\u500b\u91d1\u5c6c\u539f\u5b50\u7684\u6d3b\u6027\u9650\u5236\uff0c\u77e5\u9053\u91d1\u5c6c\u539f\u5b50\u80fd\u6d3b\u5316\u54ea\u4e9b\u5316\u5b78\u9375\uff0c\u6709\u52a9\u65bc\u8a2d\u8a08\u4e0d\u540c\u7684\u50ac\u5316\u5291\uff0c\u4e26\u8abf\u63a7\u5176\u6027\u8cea\u3002<\/p>\n<p><strong>&nbsp;<\/strong><\/p>\n<p><strong>\u539f\u6587\u51fa\u8655\uff1a<\/strong>ChemistyWorld: August 13, 2020, <a href=\"https:\/\/www.chemistryworld.com\/news\/superfluid-helium-nanoreactor-takes-single-atom-catalysis-understanding-to-the-next-level\/4012264.article\">Superfluid helium nanoreactor takes single atom catalysis understanding to the next level<\/a><\/p>\n<p><strong>\u53c3\u8003\u8cc7\u6599\uff1a<\/strong><\/p>\n<ol>\n<li>Ion-molecule reactions catalyzed by a single gold atom <em> Sci.<\/em> <strong>2020<\/strong>, <em>11<\/em>, 8502-8505 doi: <a href=\"https:\/\/doi.org\/10.1039\/D0SC03523H\">doi.org\/10.1039\/D0SC03523H<\/a><\/li>\n<li>\u7dad\u57fa\u767e\u79d1\uff1a<a href=\"https:\/\/en.wikipedia.org\/wiki\/Superfluidity\">Superfluidity<\/a><\/li>\n<li>\u7dad\u57fa\u767e\u79d1\uff1a<a href=\"https:\/\/en.wikipedia.org\/wiki\/Quantum_solvent\">Quantum Solvent<\/a><\/li>\n<\/ol>\n<p>&nbsp;<\/p>\n<p><strong>\u8a3b\u89e3\uff1a<\/strong><\/p>\n<p>[\u8a3b1]\u5728\u8a08\u7b97\u6bcf\u4e00\u6ef4\u5948\u7c73\u6db2\u73e0\u4e2d\u542b\u6709\u7684\u91d1\u539f\u5b50\u6578\u76ee\u6642\uff0c\u7814\u7a76\u5718\u968a\u4f7f\u7528\u4e86\u5e15\u677e\u5206\u5e03\uff08Poisson distribution\uff09\u9032\u884c\u7d71\u8a08\u3002\u5e15\u677e\u5206\u5e03\u6307\u7684\u662f\u55ae\u4f4d\u6642\u9593\u5167\u96a8\u6a5f\u4e8b\u4ef6\u767c\u751f\u6b21\u6578\u7684\u6a5f\u7387\u5206\u5e03\u3002\u516c\u5f0f\u70ba<strong>P<sub>k<\/sub>(z)=z<sup>k<\/sup>e<sup>-z<\/sup>\/k!<\/strong>\u3002\u6839\u64da\u9019\u500b\u516c\u5f0f\uff0c\u5718\u968a\u5f97\u4ee5\u8a08\u7b97\uff0c\u5728\u6db2\u73e0\u5674\u7051\u904e\u7a0b\u4e2d\u7d04\u670937%\u7684\u6db2\u6c26\u73e0\u4e0d\u542b\u6709\u91d1\u539f\u5b50\uff0c37%\u542b\u6709\u4e00\u9846\u91d1\u539f\u5b50\uff0c18%\u542b\u6709\u5169\u9846\u91d1\u539f\u5b50\uff0c\u53ca8%\u7684\u6db2\u6c26\u73e0\u542b\u6709\u5169\u9846\u4ee5\u4e0a\u7684\u91d1\u539f\u5b50\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u4ee5\u8d85\u6d41\u76f8\u7684\u6db2\u6c26\u4f5c\u70ba\u5948\u7c73\u7b49\u7d1a\u7684\u53cd\u61c9\u5668\uff0c\u79d1\u5b78\u5bb6\u6355\u6349\u5230\u55ae\u4e00\u91d1\u539f\u5b50\u8207\u4e8c\u5143\u9187\u751f\u6210\u7684\u51e1\u5fb7\u74e6\u7c07\u5408\u7269\uff0c\u5728\u8cea\u8b5c\u5100\u53ca\u5bc6\u5ea6\u6cdb\u51fd\u7406\u8ad6\u7684\u8f14\u52a9\u4e0b\uff0c\u5316\u5b78\u5bb6\u5011\u5f97\u4ee5\u89e3\u6790\u55ae\u9846\u91d1\u539f\u5b50\u5982\u4f55\u5206\u89e3\u4e8c\u5143\u9187\u3002<\/p>\n","protected":false},"author":20,"featured_media":35666,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[32,3293],"tags":[4717,4716,3815,2140],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2020\/09\/splashing-164963_640.jpg","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/35663"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=35663"}],"version-history":[{"count":2,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/35663\/revisions"}],"predecessor-version":[{"id":35668,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/35663\/revisions\/35668"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/35666"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=35663"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=35663"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=35663"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}