{"id":34101,"date":"2019-06-03T00:39:15","date_gmt":"2019-06-02T16:39:15","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=34101"},"modified":"2019-07-26T15:34:02","modified_gmt":"2019-07-26T07:34:02","slug":"%e5%a6%82%e4%bd%95%e6%8a%8a%e5%a4%aa%e9%99%bd%e8%83%bd%e5%ad%98%e8%b5%b7%e4%be%86","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=34101","title":{"rendered":"\u5982\u4f55\u628a\u592a\u967d\u80fd\u5b58\u8d77\u4f86"},"content":{"rendered":"

\u64b0\u6587\uff5c\u8607\u5efa\u7ff0<\/strong><\/p>\n

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\u25cf\u592a\u967d\u80fd\u96fb\u6c60\u7684\u539f\u7406<\/strong><\/span><\/p>\n

\"\"
\u5716\u4e00 \u592a\u967d\u80fd\u96fb\u6c60\u7684\u7d50\u69cb\u5716(\u4f86\u6e90: \u592a\u967d\u80fd\u96fb\u6c60@wiki)<\/figcaption><\/figure>\n

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\u25cf\u7528\u5316\u5b78\u80fd\u7684\u5f62\u5f0f\u628a\u592a\u967d\u80fd\u7559\u4e0b\u4f86<\/strong><\/span><\/p>\n

\u8981\u60f3\u628a\u592a\u967d\u80fd\u7559\u4e0b\u4f86\uff0c\u6709\u500b\u76f4\u89ba\u7684\u60f3\u6cd5\u662f\u642d\u914d\u96fb\u6c60\u7684\u4f7f\u7528\uff0c\u8f03\u5927\u578b\u7684\u4f8b\u5b50\u662f\u7279\u65af\u62c9\u5728\u590f\u5a01\u5937\u8003\u827e\u5cf6(Kauai Island)\u4e0a\u5efa\u7f6e\u7684\u7cfb\u7d71[2]<\/sup>\u7b49\uff0c\u671f\u5f85\u80fd\u5c07\u767d\u5929\u591a\u767c\u7684\u96fb\u529b\u5132\u5b58\u8d77\u4f86\uff0c\u4ee5\u61c9\u5c0d\u508d\u665a\u4e94\u9ede\u5230\u665a\u9593\u5341\u9ede\u9019\u4e00\u6ce2\u7528\u96fb\u9ad8\u5cf0\u3002<\/p>\n

\"\"
\u5716\u4e8c (a)\u4e19\u9187\u7684\u540c\u5206\u7570\u69cb\u7269: (I)1-\u4e19\u9187\u548c(II)2-\u4e19\u9187(II) (b) NBD1\u8207QC1 (\u4f86\u6e90: (a) [3], (b) [4])<\/figcaption><\/figure>\n

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\u7814\u7a76\u5718\u968a\u76ee\u524d\u627e\u5230\u7684\u89e3\u65b9\u662f\u964d\u51b0\u7247\u4e8c\u70ef(norbornadiene, NBD)\u548c\u56db\u74b0\u5e9a\u7696(quadricyclane, QC)\u9019\u7d44\u7570\u69cb\u7269\u7684\u884d\u751f\u7269NBD1\u4ee5\u53caQC1\uff0c\u5438\u6536\u592a\u967d\u5149\u7684NBD1\u5f8c\u6703\u7570\u69cb\u5316\u70ba\u6bd4\u8f03\u9ad8\u80fd\u7684QC1\uff0c\u7576\u9700\u8981\u80fd\u91cf\u7684\u6642\u5019\u518d\u628aQC1\u7570\u69cb\u5316\u56deNBD1\u540c\u6642\u4ee5\u71b1\u80fd\u7684\u5f62\u5f0f\u91cb\u653e\u51fa\u5132\u5b58\u7684\u80fd\u91cf\uff0c\u5982\u5716\u4e8c(b)\u3002\u9019\u500b\u7d44\u5408\u4e0d\u50c5\u64c1\u6709\u4e0d\u932f\u7684\u80fd\u91cf\u5bc6\u5ea6\uff0c\u4e5f\u6709\u9ad8\u6eb6\u89e3\u5ea6\u53ef\u4ee5\u6db2\u9ad4\u7684\u5f62\u614b\u51fa\u73fe\u4f7f\u5f97\u5728\u7cfb\u7d71\u7684\u8a2d\u8a08\u4e0a\u6709\u8f03\u591a\u7684\u5f48\u6027\uff0c\u53e6\u5916QC1\u5728\u651d\u6c0f25\u5ea6\u7684\u5132\u5b58\u74b0\u5883\u4e0b\u534a\u8870\u671f\u9577\u905430\u5929\uff0c\u9664\u975e\u4f60\u5728\u53ef\u80fd\u5e7e\u500b\u6708\u90fd\u4e0d\u898b\u65e5\u5149\u7684\u9ad8\u7def\u5ea6\u5730\u5340\uff0c\u5426\u5247\u9019\u500b\u534a\u8870\u671f\u61c9\u8a72\u8db3\u4ee5\u61c9\u4ed8\u65e5\u5e38\u751f\u6d3b\u7684\u9700\u6c42\u3002<\/p>\n

\u25cf\u7cfb\u7d71\u7684\u904b\u4f5c\u8207\u5f8c\u7e8c\u6700\u4f73\u5316\u7684\u65b9\u5411<\/strong><\/span><\/p>\n

\"\"
\u5716\u4e09 MOST\u793a\u610f\u5716(\u4f86\u6e90:[4])<\/figcaption><\/figure>\n

\u6574\u5408\u524d\u8ff0\u6982\u5ff5\u7684\u9019\u6574\u500b\u7cfb\u7d71\u88ab\u7a31\u4f5c\u592a\u967d\u80fd\u5206\u5b50\u84c4\u71b1\u7cfb\u7d71(molecular solar thermal energy storage, MOST)\uff0c\u7cfb\u7d71\u904b\u4f5c\u5982\u5716\u4e09\u6240\u793a\uff0c\u7576\u592a\u967d\u5149\u7167\u5c04\u5230\u6db2\u614b\u7684NBD1\u6eb6\u6db2\u6642\uff0c\u6703\u7522\u751fQC1\u7684\u6eb6\u6db2\uff0c\u5c31\u53ef\u4ee5\u52a0\u4ee5\u5132\u5b58\uff0c\u7b49\u5230\u9700\u8981\u6642\u518d\u8b93QC1\u6d41\u7d93\u7279\u5b9a\u7684\u50ac\u5316\u5291\u52a0\u901f\u8f49\u8b8a\u56deNBD1\uff0c\u91cb\u653e\u7684\u80fd\u91cf\u80fd\u5920\u7528\u4f86\u52a0\u71b1\u6c34(\u76ee\u524d\u7684\u6210\u679c\u53ef\u4ee5\u8b93\u651d\u6c0f20\u5ea6\u7684\u6c34\u6eab\u5ea6\u5347\u9ad8\u81f383\u5ea6)\u3002<\/p>\n

\u76f8\u6bd4\u65bc\u4e00\u822c\u592a\u967d\u80fd\u96fb\u6c60\u662f\u76f4\u63a5\u7531\u5149\u80fd\u8f49\u63db\u70ba\u96fb\u80fd\uff0cMOST\u7684\u904b\u4f5c\u5247\u9808\u7d93\u7531\u5149\u80fd\u3001\u5316\u5b78\u80fd\u3001\u71b1\u80fd\u3001\u96fb\u80fd\u7684\u4f9d\u5e8f\u8f49\u63db\uff0c\u66f4\u591a\u9053\u7684\u8f49\u63db\u7a0b\u5e8f\uff0c\u4ee3\u8868\u5728\u904e\u7a0b\u4e2d\u53ef\u80fd\u6703\u640d\u5931\u66f4\u591a\u7684\u80fd\u91cf\uff0c\u4e0d\u904e\u597d\u8655\u5982\u540c\u524d\u8ff0\uff0c\u53ef\u4ee5\u5c07\u4e0d\u7a69\u5b9a\u7684\u592a\u967d\u80fd\u5132\u5b58\u4e0b\u4f86\u3002\u96d6\u7136\u5c31\u76ee\u524d\u7684\u7d50\u679c\u986f\u793a\uff0c\u4f7f\u6c34\u63d0\u5347\u7684\u6eab\u5ea6\u80fd\u4e0d\u80fd\u7522\u751f\u8db3\u5920\u7684\u84b8\u6c23\u63a8\u52d5\u767c\u96fb\u6a5f\u9084\u662f\u500b\u503c\u5f97\u89c0\u5bdf\u7684\u8b70\u984c\uff0c\u4f46\u662f\u5728\u4ee5\u6696\u6c23\u70ba\u5927\u5b97\u7528\u96fb\u9700\u6c42\u7684\u6b50\u9678\u5730\u5340\uff0c\u9019\u7a2e\u65b9\u5f0f\u6216\u8a31\u80fd\u70ba\u5bb6\u6236\u7528\u96fb\u4f86\u6e90\u63d0\u4f9b\u53e6\u4e00\u7a2e\u60f3\u50cf\uff0c\u800c\u5f8c\u7e8c\u7814\u7a76\u5718\u968a\u4e5f\u5c07\u7e7c\u7e8c\u7814\u7a76\u6700\u4f73\u5316\u7684\u65b9\u5f0f\uff0c\u6bd4\u5982\u63d0\u5347\u6750\u6599\u80fd\u5920\u5438\u6536\u7684\u983b\u7387\u7bc4\u570d\u7b49\uff0c\u671f\u5f85\u80fd\u63d0\u5347\u9019\u985e\u7cfb\u7d71\u7684\u6548\u7387\u3002<\/p>\n

 <\/strong><\/p>\n

\u53c3\u8003\u8cc7\u6599\uff1a
\n<\/strong>[1] \u6dfa\u8ac7\u592a\u967d\u80fd\u96fb\u6c60\u7684\u539f\u7406\u8207\u61c9\u7528, https:\/\/ee.ntu.edu.tw\/upload\/hischool\/doc\/2014.04.pdf<\/a>
\n[2] Hawaiian Island Powered by Solar Energy after Dark, https:\/\/www.tesla.com\/sites\/default\/files\/pdfs\/en_US\/Tesla_KIUC-Case%20Study-2017.pdf<\/a>[3] Isomer, https:\/\/en.wikipedia.org\/wiki\/Isomer<\/a>
\n[4] Kasper Moth-Poulsen et al.,\u201cMacroscopic Heat Release in a Molecular Solar Thermal Energy Storage System,\u201dEnergy Environ. Sci., vol. 12, no. 1, pp. 187\u2013193, 2019.<\/p>\n

--<\/strong>
\n\u4f5c\u8005\uff1a\u8607\u5efa\u7ff0\uff0c\u76ee\u524d\u5c31\u8b80\u65bc\u53f0\u7063\u5927\u5b78\u96fb\u4fe1\u6240\u78a9\u58eb\u73ed\uff0c\u671f\u5f85\u80fd\u900f\u904e\u81ea\u5df1\u7684\u4e00\u9ede\u5fc3\u529b\uff0c \u5c07\u5404\u9818\u57df\u7684\u6709\u8da3\u767c\u73fe\u5206\u4eab\u7d66\u5927\u5bb6\u3002<\/strong><\/p>\n

\"\u52a0\u5165\u597d\u53cb\"<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

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