{"id":30591,"date":"2018-03-27T00:57:07","date_gmt":"2018-03-26T16:57:07","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=30591"},"modified":"2018-07-29T19:10:49","modified_gmt":"2018-07-29T11:10:49","slug":"%e8%a7%a3%e6%b1%ba%e9%8b%b0%e9%9b%bb%e6%b1%a0%e4%bd%8e%e6%ba%ab%e7%84%a1%e6%b3%95%e9%81%8b%e4%bd%9c%e7%9a%84%e5%95%8f%e9%a1%8c","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=30591","title":{"rendered":"\u89e3\u6c7a\u92f0\u96fb\u6c60\u4f4e\u6eab\u7121\u6cd5\u904b\u4f5c\u7684\u554f\u984c"},"content":{"rendered":"<p><span style=\"color: #333399;\"><strong>\u25a0\u4e2d\u570b\u5fa9\u65e6\u5927\u5b78\u5316\u5b78\u7cfb\u7814\u7a76\u5718\u968a\u5229\u7528\u5225\u65bc\u50b3\u7d71\u92f0\u96fb\u6c60\u7684\u6750\u6599\uff0c\u8b93\u96fb\u6c60\u5728-70\u00b0C\u4e5f\u80fd\u4f7f\u7528\u3002<\/strong><\/span><\/p>\n<figure id=\"attachment_30593\" aria-describedby=\"caption-attachment-30593\" style=\"width: 450px\" class=\"wp-caption alignleft\"><img fetchpriority=\"high\" decoding=\"async\" class=\"wp-image-30593\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2018\/03\/320.jpg\" alt=\"\" width=\"450\" height=\"312\" \/><figcaption id=\"caption-attachment-30593\" class=\"wp-caption-text\">\u5716\u7247\u4f86\u6e90\uff1aCell Press (http:\/\/www.cell.com\/joule\/abstract\/S2542-4351(18)30045-X)<\/figcaption><\/figure>\n<p><strong>\u64b0\u6587\uff5c\u65b9\u7a0b\u6bc5<\/strong><\/p>\n<p>\u92f0\u96fb\u6c60\u662f\u76ee\u524d\u6700\u5ee3\u6cdb\u904b\u7528\u65bc\u5404\u985e\u96fb\u5b50\u7522\u54c1\u7684\u96fb\u6c60\u3002\u6211\u5011\u66fe\u5728\uff1c<a href=\"http:\/\/case.ntu.edu.tw\/blog\/?p=19261\" target=\"_blank\" rel=\"noopener noreferrer\">\u5f9e\u624b\u6a5f\u5230\u96fb\u52d5\u8eca\uff1a\u7121\u8655\u4e0d\u898b\u7684\u92f0\u96fb\u6c60<\/a>\uff1e\u4e00\u6587\u4e2d\u4ecb\u7d39\u92f0\u96fb\u6c60\u7684\u5de5\u4f5c\u539f\u7406\u53ca\u76ee\u524d\u6280\u8853\u4e0a\u9700\u8981\u514b\u670d\u7684\u554f\u984c\uff0c\u5728\u8af8\u591a\u6027\u8cea\u53ca\u61c9\u7528\u4e2d\uff0c\u300c\u5de5\u4f5c\u6eab\u5ea6\u300d\u662f\u4e00\u4e0d\u53ef\u5ffd\u7565\u7684\u56e0\u5b50\u3002\u5982\u679c\u5e36\u8457\u667a\u6167\u578b\u624b\u6a5f\u5230\u6bd4\u8f03\u5bd2\u51b7\u7684\u570b\u5bb6\uff0c\u4f8b\u5982\u65e5\u672c\u6216\u52a0\u62ff\u5927\uff0c\u4f60\u6703\u767c\u73fe\u96fb\u6c60\u4e00\u4e0b\u5c31\u6c92\u96fb\uff0c\u6216\u662f\u624d\u525b\u5145\u6eff\u96fb\u5c31\u4e0d\u80fd\u7528\u4e86\uff0c\u9019\u8aaa\u660e\u4e86\u92f0\u96fb\u6c60\u7684\u5145\u653e\u96fb\u6a5f\u5236\u5728\u4f4e\u6eab\u6642\u4e26\u4e0d\u7406\u60f3\u3002\u96fb\u6c60\u5931\u9748\u7684\u539f\u56e0\u8087\u56e0\u65bc\u5176\u96fb\u8377\u79fb\u52d5\u7684\u65b9\u5f0f\uff0c\u92f0\u96fb\u6c60\u662f\u5229\u7528\u92f0\u5728\u96fb\u89e3\u8cea\u4e4b\u4e2d\u79fb\u52d5\u4e26\u4e14\u5d4c\u5165\u6216\u96e2\u958b\u9670\u967d\u6975\u6750\u6599\u3002<\/p>\n<p><!--more--><\/p>\n<p>\u5176\u7c21\u55ae\u7684\u653e\u96fb\u53cd\u61c9\u5982\u4e0b\uff1a<\/p>\n<p><img decoding=\"async\" class=\"aligncenter size-full wp-image-30592\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2018\/03\/220.png\" alt=\"\" width=\"387\" height=\"91\" \/><\/p>\n<p>\u92f0\u96fb\u6c60\u7684\u597d\u58de\u53d6\u6c7a\u65bc\u92f0\u672c\u8eab\u7684\u79fb\u52d5\u80fd\u529b\u53ca\u5176\u5d4c\u5165\u96fb\u6975\u7684\u96e3\u6613\u5ea6\uff0c\u4e00\u822c\u4f86\u8aaa\uff0c\u4f4e\u6eab\u6642\u92f0\u7684\u79fb\u52d5\u529b\u6703\u4e0b\u964d\uff0c\u9472\u5d4c\u5165\u96fb\u6975\u7684\u80fd\u529b\u4e5f\u6703\u8b8a\u5dee\u3002\u7576\u6eab\u5ea6\u964d\u5230\u651d\u6c0f-20\u00b0C\uff0c\u96fb\u6c60\u7684\u6548\u80fd\u53ea\u5269\u4e0b50%\uff1b-40\u00b0C\u96fb\u6c60\u6548\u80fd\u5c31\u50c5\u526912%\u3002\u96d6\u7136-20\u00b0C\u3001-40\u00b0C\u5c0d\u53f0\u7063\u4eba\u4f86\u8aaa\u4e0d\u592a\u6703\u9047\u5230\uff0c\u4f46\u5c0d\u9ad8\u7def\u5ea6\u570b\u5bb6\u537b\u662f\u771f\u5be6\u6703\u51fa\u73fe\u5728\u751f\u6d3b\u4e2d\u7684\uff0c\u66f4\u9051\u8ad6\u5c07\u92f0\u96fb\u6c60\u61c9\u7528\u65bc\u6975\u5730\u6216\u5916\u592a\u7a7a\u9019\u985e\u96aa\u60e1\u74b0\u5883\u4e86\u3002<\/p>\n<p>\u4f86\u81ea\u4e2d\u570b\u5fa9\u65e6\u5927\u5b78\u5316\u5b78\u7cfb\u7684\u590f\u6c38\u59da\u6559\u6388\u7684\u5be6\u9a57\u5ba4\u63d0\u51fa\u4e86\u4e00\u9805\u89e3\u6c7a\u65b9\u6848\u3002\u4ed6\u5011\u5c07\u96fb\u89e3\u6db2\u8ddf\u96fb\u6975\u6750\u6599\u901a\u901a\u63db\u6210\u7194\u9ede\u5f88\u4f4e\u7684\u6750\u6599\uff0c\u8b93\u96fb\u6c60\u5728\u4f4e\u6eab\u6642\u4f9d\u820a\u80fd\u5de5\u4f5c\uff0c\u9019\u9805\u7814\u7a76\u88ab\u767c\u8868\u5728\u00a0<em>Joule\u00a0<\/em>\u671f\u520a\u4e0a\u3002<\/p>\n<p>\u7814\u7a76\u5718\u968a\u5e7e\u4e4e\u628a\u6574\u500b\u96fb\u6c60\u7684\u6750\u6599\u90fd\u63db\u6389\u3002\u9670\u6975\u5f9e\u4e00\u822c\u7684\u904e\u5ea6\u91d1\u5c6c\u6c27\u5316\u7269\u7684\u9e7d\u985e\uff0c\u4f8b\u5982\uff1a\u9237\u9178\u92f0\u3001\u78f7\u9178\u9435\u92f0\u6216\u6c27\u5316\u9333\u92f0\u63db\u6210\u9ad8\u5206\u5b50\u6750\u6599PTPAn (polytriphenylamine)\uff1b\u967d\u6975\u5f9e\u77f3\u58a8\u63db\u6210PNTCDA (1,4,5,8-naphthalenetetracarboxylic dianhydride (NTCDA)-derived polyimide)\uff1b\u96fb\u89e3\u6db2\u5247\u7528LiTFSI (lithium bis (trifluoromethanesulfonyl) imide)\uff0c\u5176\u53ef\u89e3\u96e2\u70ba(Li<sup>+<\/sup>\u53caTFSI<sup>-<\/sup>)\u3002<\/p>\n<p>\u50b3\u7d71\u7684\u92f0\u96fb\u6c60\u662f\u85c9\u7531\u92f0\u9472\u5d4c\u5165\u9670\u6975\u53ca\u967d\u6975\u4e2d\uff0c\u9019\u904e\u7a0b\u53ef\u4ee5\u8996\u70ba\u6eb6\u89e3\u8ddf\u812b\u6eb6(solvation\/desolvation)\uff0c\u60f3\u7576\u7136\u723e\uff0c\u4f4e\u6eab\u4e0b\u6eb6\u89e3\u5ea6\u4f4e\uff0c\u9472\u5d4c\u7684\u6548\u7387\u4f4e\uff0c\u96fb\u6c60\u8868\u73fe\u81ea\u7136\u5c31\u5dee\u3002\u56e0\u6b64\u8981\u89e3\u6c7a\u9019\u500b\u554f\u984c\uff0c\u92f0\u96fb\u6c60\u8207\u96fb\u6975\u7684\u7d50\u5408\u5c31\u5fc5\u9808\u900f\u904e\u4e0d\u4e00\u6a23\u7684\u6a5f\u5236\u3002\u9019\u9805\u7814\u7a76\u4e2d\uff0c\u967d\u6975\u7684PNTCDA\u4e0a\u6709\u78b3\u6c27\u96d9\u9375(C=O)<sub>n<\/sub>\uff0c\u7576\u92f0\u51fa\u73fe\u6642\u6703\u5c07\u5176\u70ef\u9187\u5316\u6210\u70ba(C-O-Li)\u00ad<sub>n\u00ad<\/sub>\uff1b\u9670\u6975\u7684\u6a5f\u5236\u5c31\u66f4\u7279\u6b8a\uff0c\u6839\u672c\u4e0d\u9760\u92f0\uff0c\u800c\u662f\u9760\u96fb\u89e3\u8cea\u7684\u9670\u96e2\u5b50TFSI<sup>-<\/sup>\u8207PTPAn\u9032\u884c\u5438\u9644\u8207\u812b\u9644\u53cd\u61c9\u3002<\/p>\n<p>\u7e3d\u6b78\u4f86\u8aaa\uff0c\u7814\u7a76\u5718\u968a\u5148\u5c07\u96fb\u6c60\u7684\u7d44\u6210\u6750\u6599\u63db\u6210\u7194\u9ede\u8f03\u4f4e\uff0c\u80fd\u627f\u53d7\u4f4e\u6eab\u7684\u6750\u6599\u3002\u540c\u6642\u4e5f\u5c07\u92f0\u96fb\u6c60\u5145\u653e\u96fb\u7684\u6a5f\u5236\u63db\u6210\u4f4e\u6eab\u4e0b\u66f4\u6709\u6548\u7387\u7684\u65b9\u5f0f\uff0c\u9019\u500b\u65b0\u8a2d\u8a08\u8b93\u96fb\u6c60\u5728-70\u00b0C\u4e5f\u80fd\u4fdd\u6709\u5ba4\u6eab\u6548\u80fd\u768470%\uff0c\u76f8\u8f03\u65bc\u50b3\u7d71\u92f0\u96fb\u6c60\u662f\u6975\u5177\u7a81\u7834\u6027\u7684\u7814\u7a76\uff0c\u5c0d\u5c07\u4f86\u6975\u5730\u6216\u662f\u5916\u592a\u7a7a\u7684\u7814\u7a76\u6216\u61c9\u7528\u662f\u4e00\u5927\u798f\u97f3\u3002\u4f46\u8a71\u96d6\u5982\u6b64\uff0c\u65b0\u96fb\u6c60\u5728\u5ba4\u6eab\u7684\u7684\u6548\u80fd\u8ddf\u50b3\u7d71\u92f0\u96fb\u6c60\u76f8\u6bd4\u9084\u5dee\u4e0a\u4e00\u5927\u622a\uff0c\u8ddd\u96e2\u5be6\u969b\u61c9\u7528\u9084\u6709\u4e0d\u5c11\u7684\u7a7a\u9593\u503c\u5f97\u52aa\u529b\u3002<\/p>\n<p>\u590f\u6559\u6388\u8868\u793a\uff1a\u300c\u50b3\u7d71\u7684\u904e\u5ea6\u91d1\u5c6c\u6c27\u5316\u7269\u7684\u9e7d\u985e\u76f8\u6bd4\uff0c\u6709\u6a5f\u7269\u7d44\u6210\u7684\u96fb\u6975\u6709\u8457\u91cf\u591a\u3001\u4fbf\u5b9c\u4e14\u74b0\u4fdd\u7684\u512a\u9ede\u3002\u300d\u590f\u6559\u6388\u4f30\u8a08\u5176\u6750\u6599\u6210\u672c\u53ea\u6709\u50b3\u7d71\u92f0\u96fb\u6c60\u7684\u4e09\u5206\u4e4b\u4e00\u3002<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u539f\u59cb\u8ad6\u6587\uff1a<\/strong>Xiaoli Dong, Zhaowei Guo, Ziyang Guo, Yonggang Wang, Yongyao Xia. <strong>Organic Batteries Operated at \u221270\u00b0C.<\/strong><em> Joule<\/em>, 2018; DOI: 10.1016\/j.joule.2018.01.017<\/p>\n<p><strong>\u53c3\u8003\u8cc7\u6599\uff1a<\/strong><\/p>\n<ol>\n<li>http:\/\/www.cell.com\/joule\/abstract\/S2542-4351(18)30045-X<\/li>\n<li>Cell Press. \"<a href=\"https:\/\/www.sciencedaily.com\/releases\/2018\/02\/180228131132.htm\" target=\"_blank\" rel=\"noopener noreferrer\">A lithium battery that operates at -70 degrees Celsius, a record low<\/a>.\" ScienceDaily. ScienceDaily, 28 February 2018.<\/li>\n<\/ol>\n<p><strong>--<\/strong><br \/>\n<strong>\u4f5c\u8005\uff1a\u65b9\u7a0b\u6bc5 \u79d1\u6559\u4e2d\u5fc3\u7279\u7d04\u5beb\u624b\uff0c\u5f9e\u4e8b\u79d1\u666e\u6587\u7ae0\u5beb\u4f5c\u3002<\/strong><\/p>\n<p>&nbsp;<\/p>\n<p><a href=\"https:\/\/line.me\/R\/ti\/p\/%40fcx6182w\" target=\"_blank\" rel=\"noopener noreferrer\"><img decoding=\"async\" class=\"alignnone\" src=\"https:\/\/scdn.line-apps.com\/n\/line_add_friends\/btn\/zh-Hant.png\" alt=\"\u52a0\u5165\u597d\u53cb\" width=\"212\" height=\"36\" border=\"0\" \/><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u25a0\u4e2d\u570b\u5fa9\u65e6\u5927\u5b78\u5316\u5b78\u7cfb\u7814\u7a76\u5718\u968a\u5229\u7528\u5225\u65bc\u50b3\u7d71\u92f0\u96fb\u6c60\u7684\u6750\u6599\uff0c\u8b93\u96fb\u6c60\u5728-70\u00b0C\u4e5f\u80fd\u4f7f\u7528\u3002<\/p>\n","protected":false},"author":20,"featured_media":30593,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1023,3293],"tags":[1442],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2018\/03\/320.jpg","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/30591"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=30591"}],"version-history":[{"count":3,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/30591\/revisions"}],"predecessor-version":[{"id":31961,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/30591\/revisions\/31961"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/30593"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=30591"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=30591"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=30591"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}