{"id":30054,"date":"2018-01-02T00:37:18","date_gmt":"2018-01-01T16:37:18","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=30054"},"modified":"2018-08-29T17:05:50","modified_gmt":"2018-08-29T09:05:50","slug":"%e6%99%ba%e6%85%a7%e5%a4%aa%e9%99%bd%e8%83%bd%e7%aa%97%e6%88%b6","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=30054","title":{"rendered":"\u667a\u6167\u592a\u967d\u80fd\u7a97\u6236"},"content":{"rendered":"

\u25a0\u7f8e\u570b\u570b\u5bb6\u518d\u751f\u80fd\u6e90\u5be6\u9a57\u5ba4\u7814\u767c\u51fa\u5e73\u6642\u662f\u7a97\u6236\uff0c\u7167\u5230\u592a\u967d\u5c31\u8b8a\u96fb\u6c60\u7684\u65b0\u7a4e\u6750\u6599\u3002<\/strong><\/span><\/p>\n

\"\"
(Photo by Dennis Schroeder\/NREL)<\/figcaption><\/figure>\n

\u64b0\u6587\uff5c\u65b9\u7a0b\u6bc5<\/strong><\/p>\n

\u9047\u71b1\u8b8a\u8272(Thermochromism)\u662f\u4e00\u5b58\u5728\u65bc\u67d0\u4e9b\u6750\u6599\u7684\u7269\u7406\u73fe\u8c61\u3002\u6750\u6599\u5728\u4e0d\u540c\u6eab\u58d3\u6703\u4ee5\u4e0d\u540c\u76f8(phase)\u5b58\u5728\uff0c\u4e0d\u540c\u76f8\u7684\u5149\u5b78\u6027\u8cea\u5404\u6709\u4e0d\u540c\uff0c\u9047\u71b1\u8b8a\u8272\u7684\u6750\u6599\u5c0d\u5149\u7684\u7a7f\u900f\u53ca\u53cd\u5c04\u7387\u6703\u56e0\u70ba\u6eab\u5ea6\u6539\u8b8a\u800c\u8ddf\u8457\u6539\u8b8a\u3002\u7f8e\u570b\u570b\u5bb6\u518d\u751f\u80fd\u6e90\u5be6\u9a57\u5ba4(National Renewable Energy Laboratory,NREL)\u5229\u7528\u9019\u500b\u73fe\u8c61\u7814\u767c\u51fa\u4e00\u7a2e\u667a\u6167\u7a97\u6236\uff0c\u7a97\u6236\u672c\u8eab\u70ba\u900f\u660e\u7121\u8272\uff0c\u4f46\u7576\u592a\u967d\u5149\u7167\u5c04\u4f7f\u6eab\u5ea6\u4e0a\u5347\u6642\uff0c\u8868\u9762\u7684\u7279\u6b8a\u5857\u6599\u6703\u8b8a\u5f97\u4e0d\u900f\u660e\uff0c\u4e14\u53ef\u4ee5\u767c\u96fb\uff0c\u80fd\u5e6b\u52a9\u8abf\u7bc0\u5efa\u7bc9\u7269\u5ba4\u5167\u6eab\u5ea6\u53ca\u7bc0\u80fd\u6e1b\u78b3\u3002\u9019\u9805\u7814\u7a76\u6210\u679c\u767c\u8868\u65bc\u300a\u81ea\u7136\u2027\u901a\u8a0a\u300b\u671f\u520a (Nature Communications<\/em>) \u4e0a\u3002<\/p>\n

\u7814\u7a76\u5718\u968a\u4f7f\u7528\u7684\u6750\u6599\u70ba\u9223\u9226\u7926\u7d50\u69cb\u7684\u925b\u9e75\u5316\u7269(Lead halide perovskites)\uff0c\u7c21\u5f0f\u70ba APX3<\/sub>(A\u901a\u5e38\u70ba\u6709\u6a5f\u7269\u6216\u9e7c\u91d1\u65cf\u3001Pb\u70ba\u925b\u3001X\u70ba\u9e75\u5316\u7269)\u3002\u9223\u9226\u7926\u7d50\u69cb\u5e38\u7528\u65bc\u592a\u967d\u80fd\u767c\u96fb\uff0c\u6211\u5011\u66fe\u5728\uff1c\u5149\u53ef\u4ee5\u6cbb\u7652\u6750\u6599<\/a>\uff1f\uff1e\u4e00\u6587\u4e2d\u4ecb\u7d39\u3002\u7814\u7a76\u5718\u968a\u6240\u4f7f\u7528\u7684\u5316\u5408\u7269\u70ba(CH3<\/sub>NH3<\/sub>PbI3<\/sub>\u2022xCH3<\/sub>NH2<\/sub>)\uff0c\u9019\u500b\u5316\u5408\u7269\u672c\u8eab\u900f\u660e\u7121\u8272\uff0c\u4e4b\u6240\u4ee5\u88ab\u62ff\u4f86\u7528\u65bc\u7814\u767c\u667a\u6167\u7a97\u6236\u662f\u7531\u65bc\u7576\u592a\u967d\u7167\u5c04\u800c\u5c0e\u81f4\u5176\u6eab\u5ea6\u4e0a\u5347\u6642\uff0cxCH3<\/sub>NH2\u00a0<\/sub>\u6703\u5f9e\u5316\u5408\u7269\u5206\u96e2\uff0c\u7576 CH3<\/sub>NH2<\/sub> \u96e2\u958b\u5f8c\uff0cCH3<\/sub>NH3<\/sub>PbI3\u00a0<\/sub>\u8b8a\u5f97\u4e0d\u900f\u5149\uff0c\u4e0d\u900f\u5149\u4ee3\u8868\u5149\u88ab\u6750\u6599\u5438\u6536\uff0c\u7d93\u904e\u96fb\u5b78\u8a2d\u8a08\u5f8c\uff0c\u53ef\u4ee5\u505a\u70ba\u592a\u967d\u80fd\u96fb\u6c60\u3002<\/p>\n

\u6574\u500b\u53cd\u61c9\u5f0f\u70ba\uff1a\"\"<\/p>\n

\u7b49\u865f\u5de6\u908a\u900f\u5149\uff0c\u6eab\u5ea6\u5347\u9ad8\u53cd\u61c9\u5f80\u53f3\u908a\u8d70\uff0c\u7b49\u865f\u53f3\u908a\u7684\u5316\u5408\u7269\u4e0d\u900f\u5149\u3002CH3<\/sub>NH3<\/sub>PbI3<\/sub>\u2022xCH3<\/sub>NH2\u00a0<\/sub>\u7684\u900f\u5149\u7387\u5927\u7d04\u70ba68%\uff0c\u8ddf\u4e00\u822c\u73bb\u7483 90% \u5de6\u53f3\u7684\u7a7f\u900f\u5ea6\u6bd4\u9084\u662f\u7565\u4f4e\uff1bCH3<\/sub>NH3<\/sub>PbI3\u00a0<\/sub>\u7a7f\u900f\u5ea6\u53ea\u6709 3%\uff0c\u505a\u70ba\u592a\u967d\u80fd\u96fb\u6c60\u5176\u767c\u96fb\u6548\u7387\u5927\u7d04\u70ba11.3%\uff0c\u96d6\u7136\u6578\u5b57\u4e0a\u770b\u8d77\u4f86\u5f88\u4f4e\uff0c\u4f46\u5373\u4fbf\u5e02\u552e\u77fd\u6676\u592a\u967d\u80fd\u96fb\u6c60\u6548\u7387\u4e5f\u4e0d\u8d85\u904e 30%\uff0c\u4ee5\u5be6\u9a57\u5ba4\u7814\u767c\u65b0\u578b\u592a\u967d\u80fd\u96fb\u6c60\u7684\u6a19\u6e96\u4f86\u770b\uff0c11.3% \u5df2\u662f\u975e\u5e38\u597d\u7684\u6210\u679c\u3002\u6574\u500b\u4eae\u6697\u8f49\u63db\u904e\u7a0b\u5c11\u65bc3\u5206\u9418\u3002\u7814\u7a76\u5718\u968a\u7684\u5be6\u9a57\u5f71\u7247\u8acb\u9ede\u6b64<\/a>\u3002<\/p>\n

\u8ad6\u6587\u4f5c\u8005 Lance Wheeler \u8868\u793a\uff1a\u300c\u4f8b\u7528\u9047\u71b1\u8b8a\u8272\u7684\u6280\u8853\u61c9\u7528\u975e\u5e38\u591a\uff0c\u4f46\u4e26\u6c92\u6709\u4eba\u5c07\u9019\u500b\u73fe\u8c61\u7528\u65bc\u767c\u96fb\u3002\u300d\u300c\u53ef\u8b8a\u63db\u7684\u592a\u967d\u80fd\u96fb\u6c60\u7a97\u6236\u5373\u662f\u5229\u7528\u5316\u5408\u7269\u5206\u89e3\u7684\u53ef\u9006\u53cd\u61c9\u505a\u6210\u3002\u300d\u96d6\u7136\u9019\u9805\u6280\u8853\u76f8\u7576\u6709\u8da3\u4e14\u5275\u65b0\uff0c\u4f46\u76ee\u524d\u6750\u6599\u58fd\u547d\u50c5\u80fd\u652f\u649020\u6b21\u5de6\u53f3\u7684\u4eae\u6697\u8b8a\u5316\uff0c\u8981\u80fd\u9032\u4e00\u6b65\u61c9\u7528\u9084\u9700\u8981\u66f4\u591a\u7684\u7814\u7a76\u3002<\/p>\n

\u7814\u7a76\u5718\u968a\u4e5f\u4e0d\u53ea\u6eff\u8db3\u65bc\u8ad6\u6587\u767c\u8868\uff0c\u53bb\u5e74\u4ed6\u5011\u53c3\u52a0\u4e86\u70ba\u671f\u5169\u500b\u6708\u7684 Energy I-Corps \u8a08\u756b\u3002\u9019\u9805\u8a08\u756b\u65e8\u5728\u9023\u7d50\u696d\u754c\u8207\u5b78\u754c\uff0c\u70ba\u7f8e\u570b\u80fd\u6e90\u90e8(Department of Energy's Building Technologies Office)\u6240\u8209\u8fa6\uff0c\u7814\u7a76\u5718\u968a\u6703\u63a5\u53d7\u4f86\u81ea\u696d\u754c\u7684\u6307\u5c0e\uff0c\u63a2\u7d22\u8a72\u9805\u6280\u8853\u7684\u6f5b\u5728\u5ba2\u6236\u53ca\u9700\u6c42\u3002Lance Wheeler \u4e5f\u8868\u793a\u9019\u9805\u79d1\u6280\u5c07\u4f86\u53ef\u61c9\u7528\u65bc\u8eca\u8f1b\u6216\u5efa\u7bc9\u7269\uff0c\u767c\u51fa\u7684\u96fb\u80fd\u53ef\u4ee5\u5c0d\u624b\u6a5f\u6216\u662f\u6a5f\u8f09\u96fb\u5b50\u8a2d\u5099\uff0c\u4f8b\u5982\uff1a\u98a8\u6247\u3001\u964d\u96e8\u5075\u6e2c\u6216\u662f\u958b\u95dc\u7a97\u6236\u7684\u99ac\u9054\u7b49\u7b49\u9032\u884c\u5145\u96fb\u3002<\/p>\n

 <\/p>\n

\u539f\u59cb\u8ad6\u6587\uff1a<\/strong>Moore, David T., Elisa M. Miller, Jeffrey L. Blackburn, Lance M. Wheeler, Nathan R. Neale, Noah J. Stanton, Rachelle Ihly, and Robert C. Tenent. \"Switchable photovoltaic windows enabled by reversible photothermal complex dissociation from methylammonium lead iodide.\"\u00a0Nature Communications<\/em>\u00a08, no. 1 (2017): 1722.<\/p>\n

\u53c3\u8003\u8cc7\u6599\uff1a<\/strong><\/p>\n

    \n
  1. NREL Develops Switchable Solar Window<\/a><\/li>\n
  2. Energy I-Corps<\/a><\/li>\n<\/ol>\n

    --<\/strong>
    \n\u4f5c\u8005\uff1a\u65b9\u7a0b\u6bc5 \u79d1\u6559\u4e2d\u5fc3\u7279\u7d04\u5beb\u624b\uff0c\u5f9e\u4e8b\u79d1\u666e\u6587\u7ae0\u5beb\u4f5c\u3002<\/strong><\/span><\/p>\n

     <\/p>\n

    \"\u52a0\u5165\u597d\u53cb\"<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

    \u25a0\u9047\u71b1\u8b8a\u8272(Thermochromism)\u662f\u4e00\u5b58\u5728\u65bc\u67d0\u4e9b\u6750\u6599\u7684\u7269\u7406\u73fe\u8c61\u3002\u6750\u6599\u5728\u4e0d\u540c\u6eab\u58d3\u6703\u4ee5\u4e0d\u540c\u76f8\u5b58\u5728\uff0c\u4e0d\u540c\u76f8\u7684\u5149\u5b78\u6027\u8cea\u5404\u6709\u4e0d\u540c\uff0c\u9047\u71b1\u8b8a\u8272\u7684\u6750\u6599\u5c0d\u5149\u7684\u7a7f\u900f\u53ca\u53cd\u5c04\u7387\u6703\u56e0\u70ba\u6eab\u5ea6\u6539\u8b8a\u800c\u8ddf\u8457\u6539\u8b8a\u3002\u7f8e\u570b\u570b\u5bb6\u518d\u751f\u80fd\u6e90\u5be6\u9a57\u5ba4\u5229\u7528\u9019\u500b\u73fe\u8c61\u7814\u767c\u51fa\u4e00\u7a2e\u667a\u6167\u7a97\u6236\uff0c\u7a97\u6236\u672c\u8eab\u70ba\u900f\u660e\u7121\u8272\uff0c\u4f46\u7576\u592a\u967d\u5149\u7167\u5c04\u4f7f\u6eab\u5ea6\u4e0a\u5347\u6642\uff0c\u8868\u9762\u7684\u7279\u6b8a\u5857\u6599\u6703\u8b8a\u5f97\u4e0d\u900f\u660e\uff0c\u4e14\u53ef\u4ee5\u767c\u96fb\uff0c\u80fd\u5e6b\u52a9\u8abf\u7bc0\u5efa\u7bc9\u7269\u5ba4\u5167\u6eab\u5ea6\u53ca\u7bc0\u80fd\u6e1b\u78b3\u3002<\/p>\n","protected":false},"author":20,"featured_media":30056,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[1023,3293],"tags":[3690,1269,2441,1317],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2017\/12\/20171127-wheeler-48095.jpg","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/30054"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=30054"}],"version-history":[{"count":3,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/30054\/revisions"}],"predecessor-version":[{"id":31938,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/30054\/revisions\/31938"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/30056"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=30054"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=30054"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=30054"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}