{"id":28135,"date":"2017-06-20T00:06:39","date_gmt":"2017-06-19T16:06:39","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=28135"},"modified":"2018-07-29T09:44:57","modified_gmt":"2018-07-29T01:44:57","slug":"%e6%9c%89%e6%a9%9f%e5%88%86%e5%ad%90%e9%8f%88%e4%b8%8a%e7%9a%84%e9%8e%b3%e5%8e%9f%e5%ad%90%e6%90%ac%e9%81%8b%e5%b7%a5","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=28135","title":{"rendered":"\u6709\u6a5f\u5206\u5b50\u93c8\u4e0a\u7684\u93b3\u539f\u5b50\u642c\u904b\u5de5"},"content":{"rendered":"<p><span style=\"color: #333399;\"><strong>\u25a0\u6709\u6a5f\u5316\u5408\u7269\u5728\u751f\u6d3b\u4e2d\u904d\u8655\u53ef\u898b\uff0c\u8209\u51e1\u5851\u81a0\u888b\u3001\u6f64\u6ed1\u6cb9\u548c\u6e05\u6f54\u5291\u7b49\uff0c\u90fd\u662f\u6709\u6a5f\u5316\u5b78\u5de5\u7a0b\u7684\u7522\u7269\u3002\u7522\u751f\u7d14\u5ea6\u9ad8\u7684\u6709\u6a5f\u7522\u7269\u662f\u5316\u5de5\u88fd\u7a0b\u7684\u76ee\u6a19\u4e5f\u662f\u6311\u6230\u3002\u9577\u4e45\u4ee5\u4f86\uff0c\u5e38\u898b\u7684\u7d14\u5316\u65b9\u6cd5\u662f\u5206\u993e\u6cd5\uff0c\u900f\u904e\u7269\u7406\u6027\u8cea\u5206\u96e2\u4e0d\u540c\u7684\u5316\u5408\u7269\uff0c\u9019\u500b\u904e\u7a0b\u7de9\u6162\u4e14\u6210\u672c\u9ad8\u3002\u5982\u679c\u6709\u4e00\u7a2e\u53cd\u61c9\uff0c\u80fd\u628a\u7d50\u69cb\u4e0d\u540c\u7684\u6709\u6a5f\u7269\uff0c\u901a\u901a\u8b8a\u6210\u76f8\u540c\u7684\u76ee\u6a19\u7522\u7269\uff0c\u90a3\u8a72\u6709\u591a\u597d\uff1f<\/strong><\/span><\/p>\n<figure id=\"attachment_28136\" aria-describedby=\"caption-attachment-28136\" style=\"width: 450px\" class=\"wp-caption alignleft\"><img fetchpriority=\"high\" decoding=\"async\" class=\"wp-image-28136\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2017\/05\/front-1.jpg\" alt=\"\" width=\"450\" height=\"312\" srcset=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2017\/05\/front-1.jpg 980w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2017\/05\/front-1-600x416.jpg 600w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2017\/05\/front-1-800x555.jpg 800w\" sizes=\"(max-width: 450px) 100vw, 450px\" \/><figcaption id=\"caption-attachment-28136\" class=\"wp-caption-text\">\u793a\u610f\u5716\u3002\u900f\u904e\u93b3\u539f\u5b50\uff0c\u5316\u5b78\u53cd\u61c9\u7684\u4f4d\u7f6e\u88ab\u642c\u904b\u5230\u6709\u6a5f\u5206\u5b50\u93c8\u4e0a\u7684\u7279\u5b9a\u4f4d\u7f6e\u3002(source: MartinLab, 3dciencia)<\/figcaption><\/figure>\n<p><strong>\u64b0\u6587\uff5c<\/strong>\u9673\u5955\u5ef7<\/p>\n<p>\u78b3\u6c34\u5316\u5408\u7269\u662f\u4e00\u7fa4\u4e3b\u8981\u7531\u78b3\u3001\u6c2b\u548c\u6c27\u5143\u7d20\u6240\u69cb\u6210\u7684\u5206\u5b50\u7684\u901a\u7a31\uff0c\u5728\u5927\u81ea\u7136\u3001\u4eba\u9ad4\u548c\u5de5\u696d\u4e2d\u90fd\u80fd\u770b\u898b\u5176\u8e64\u5f71\u3002\u5176\u4e2d\u5206\u5b50\u7d50\u69cb\u5177\u6709\u78b3\u78b3\u96d9\u9375\uff08C=C\uff09\u7684\u300c\u70ef\u985e\u300d\u662f\u77f3\u6cb9\u7684\u526f\u7522\u7269\uff0c\u7522\u91cf\u975e\u5e38\u8c50\u5bcc\u3002\u5b83\u80fd\u5feb\u901f\u4e14\u7c21\u55ae\u5730\u8f49\u63db\u6210\u8a31\u591a\u5177\u6709\u50f9\u503c\u7684\u5316\u5408\u7269\uff0c\u5f9e\u5851\u81a0\u88fd\u9020\u5230\u85e5\u7269\u5316\u5b78\u90fd\u548c\u5b83\u6709\u95dc\uff0c\u5728\u77f3\u5316\u5de5\u696d\u4e2d\u662f\u975e\u5e38\u91cd\u8981\u7684\u539f\u6599\uff0c\u4eba\u985e\u4f7f\u7528\u5b83\u5df2\u8d85\u904e\u767e\u5e74\u3002\u7531\u70ef\u985e\u88fd\u6210\u7684\u4e00\u7a2e\u4e2d\u9593\u7522\u7269\u662f\u8102\u80aa\u9178\uff0c\u5176\u7d50\u69cb\u5982\u5716\u4e00\u6240\u793a\uff0c\u7531\u4e00\u4e32\u78b3\u93c8\u548c\u7fa7\u57fa\uff08-COOH\uff09\u7d44\u6210\u3002\u5b83\u80fd\u88ab\u88fd\u6210\u5851\u81a0\u3001\u6a61\u81a0\u3001\u80a5\u7682\u548c\u67d3\u6599\u7b49\u3002\u8102\u80aa\u9178\u88ab\u9810\u6e2c\u5230\u4e862023\u5e74\uff0c\u5e02\u5834\u92b7\u552e\u984d\u5c07\u9ad8\u905420\u5104\u7f8e\u5143\uff08\u7d04600\u5104\u53f0\u5e63\uff09\u3002<!--more--><\/p>\n<figure id=\"attachment_28137\" aria-describedby=\"caption-attachment-28137\" style=\"width: 700px\" class=\"wp-caption aligncenter\"><img decoding=\"async\" class=\"wp-image-28137\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2017\/05\/fig1-1.png\" alt=\"\" width=\"700\" height=\"138\" \/><figcaption id=\"caption-attachment-28137\" class=\"wp-caption-text\">\u5716\u4e00\u3001\u8102\u80aa\u9178\u3002\u5b83\u5177\u6709\u4e00\u500b\u9577\u9577\u7684\u78b3\u93c8\u548c\u4e00\u500b\u7fa7\u57fa\u3002<\/figcaption><\/figure>\n<p><span style=\"color: #008080;\"><strong>\u25cf\u91d1\u5c6c\u50ac\u5316\u589e\u52a0\u7522\u7387<\/strong><\/span><\/p>\n<p>\u8a2d\u8a08\u6709\u6a5f\u5316\u5b78\u53cd\u61c9\u662f\u5316\u5b78\u5de5\u7a0b\u6700\u5927\u7684\u6311\u6230\u4e4b\u4e00\u3002\u91dd\u5c0d\u7279\u5b9a\u7684\u5316\u5b78\u53cd\u61c9\u548c\u76ee\u6a19\u7522\u7269\uff0c\u53cd\u61c9\u7269\u4ecd\u6709\u53ef\u80fd\u900f\u904e\u5176\u4ed6\u9014\u5f91\u7522\u751f\u4e0d\u76f8\u5e72\u7684\u7522\u7269\uff0c\u964d\u4f4e\u53cd\u61c9\u6548\u7387\u3002\u5c0d\u65bc\u5206\u5b50\u91cf\u5c0f\u7684\u8102\u80aa\u9178\uff0c\u907f\u514d\u4e0d\u826f\u53cd\u61c9\u7684\u65b9\u6cd5\u4e4b\u4e00\u662f\u91d1\u5c6c\u50ac\u5316\uff1a\u5c07\u539f\u6599\u548c\u4e8c\u6c27\u5316\u78b3\u9084\u6709\u6c34\u6c23\u5747\u52fb\u6df7\u5408\uff0c\u518d\u900f\u904e\u91d1\u5c6c\u50ac\u5316\u52a0\u901f\u53cd\u61c9\uff0c\u80fd\u6709\u6548\u5730\u964d\u4f4e\u4e0d\u826f\u53cd\u61c9\u7684\u6548\u7387\u3002\u4f8b\u5982\uff1a\u918b\u9178\u662f\u4ee5\u4e59\u70ef\u70ba\u539f\u6599\u3001\u93b3\u91d1\u5c6c\u70ba\u50ac\u5316\u5291\uff0c\u900f\u904e\u4e0a\u8ff0\u7684\u7fa7\u9178\u5316\u4f5c\u7528(hydrocarboxylation)\u6240\u88fd\u6210\u7684\u3002\u503c\u5f97\u4e00\u63d0\u7684\uff0c\u93b3\u91d1\u5c6c\u662f\u81ea\u7136\u754c\u4e2d\u542b\u91cf\u975e\u5e38\u9ad8\u7684\u7269\u8cea\uff0c\u6bd4\u8d77\u73cd\u8cb4\u91d1\u5c6c\u4f8b\u5982\u9251\u91d1\u5c6c\uff0c\u6210\u672c\u4f4e\u4e0a\u8a31\u591a\uff0c\u6548\u679c\u537b\u76f8\u7576\u512a\u826f\uff0c\u662f\u975e\u5e38\u597d\u7684\u50ac\u5316\u5291\u3002<\/p>\n<p>\u7136\u800c\uff0c\u6709\u6a5f\u5316\u5408\u7269\u6709\u4e00\u500b\u7279\u6027\uff1a\u76f8\u540c\u7684\u5206\u5b50\u5316\u5b78\u5f0f\u53ef\u4ee5\u6709\u7121\u6578\u7a2e\u4e0d\u540c\u7684\u5316\u5408\u7269\uff0c\u6709\u6642\u5019\u662f\u78b3\u9577\u93c8\u7684\u5f62\u72c0\u4e0d\u4e00\u6a23\uff08\u5716\u4e8c\u5de6\uff09\u3001\u6709\u6642\u5019\u662f\u5b98\u80fd\u57fa\u63a5\u5728\u4e0d\u540c\u5730\u65b9(\u5716\u4e8c\u4e2d)\u3001\u6709\u6642\u5019\u751a\u81f3\u5b98\u80fd\u57fa\u5b8c\u5168\u4e0d\u540c\uff08\u5716\u4e8c\u53f3 \uff09\u3002\u5b83\u5011\u5177\u6709\u4e0d\u540c\u7684\u5316\u5b78\u6027\u8cea\uff0c\u82e5\u9032\u884c\u5316\u5b78\u52a0\u5de5\uff0c\u6703\u8f49\u5316\u6210\u975e\u5e38\u4e0d\u540c\u7684\u7522\u7269\u3002\u5f9e\u77f3\u6cb9\u4e2d\u63d0\u7149\u51fa\u4f86\u7684\u70ef\u985e\u901a\u5e38\u90fd\u662f\u6578\u7a2e\u4e0d\u540c\u5316\u5408\u7269\u7684\u6df7\u5408\u9ad4\u3002\u5118\u7ba1\u93b3\u91d1\u5c6c\u5c0d\u65bc\u7d14\u5ea6\u9ad8\u7684\u55ae\u4e00\u539f\u6599\u6548\u679c\u5f88\u597d\uff0c\u5c0d\u65bc\u672c\u8eab\u5c31\u5177\u6709\u591a\u7a2e\u5316\u5408\u7269\u7684\u539f\u6599\u9084\u662f\u6c92\u8f12\uff0c\u4ecd\u5fc5\u9808\u900f\u904e\u8907\u96dc\u7684\u5206\u993e\u7a0b\u5e8f\u5c07\u5b83\u5011\u5206\u96e2\uff0c\u6210\u672c\u76f8\u7576\u6602\u8cb4\u3002<\/p>\n<figure id=\"attachment_28138\" aria-describedby=\"caption-attachment-28138\" style=\"width: 700px\" class=\"wp-caption aligncenter\"><img decoding=\"async\" class=\"wp-image-28138\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2017\/05\/fig2-1.png\" alt=\"\" width=\"700\" height=\"502\" \/><figcaption id=\"caption-attachment-28138\" class=\"wp-caption-text\">\u5716\u4e8c\u3001\u6709\u6a5f\u7570\u69cb\u7269<\/figcaption><\/figure>\n<p><span style=\"color: #008080;\"><strong>\u25cf\u9577\u93c8\u4e0a\u8d70\u52d5\u7684\u93b3\u539f\u5b50\u642c\u904b\u53cd\u61c9\u4f4d\u7f6e<\/strong><\/span><\/p>\n<p>\u8fd1\u65e5\uff0c\u897f\u73ed\u7259\u79d1\u5b78\u5bb6\u767c\u660e\u4e00\u7a2e\u5316\u5de5\u88fd\u7a0b\uff0c\u80fd\u5c07\u591a\u500b\u5316\u5408\u7269\u6df7\u96dc\u7684\u539f\u6599\uff0c\u6709\u6548\u5730\u8f49\u63db\u6210\u55ae\u4e00\u7a2e\u7522\u7269(\u5716\u4e09a)\u3002\u5982\u5716\u4e09\uff0c\u9019\u500b\u88fd\u7a0b\u5171\u6709\u4e09\u500b\u6b65\u9a5f\u3002\u9996\u5148\uff0c\u5c07\u7d50\u69cb\u4e0d\u540c\u7684\u70ef\u985e\u539f\u6599\u548c\u6c2b\u6eb4\u9178\uff08HBr\uff09\u4f5c\u7528\u3002\u6c2b\u6eb4\u9178\u6703\u6253\u65b7\u70ef\u985e\u7684\u96d9\u9375\uff0c\u4e26\u5728\u539f\u672c\u7684C=C\u8655\u63a5\u4e0a\u4e00\u500b\u6c2b\u539f\u5b50\u548c\u4e00\u500b\u6eb4\u539f\u5b50\uff08\u5716\u4e09b\uff09\u3002\u63a5\u8457\uff0c\u5c07\u6eb4\u8655\u7406\u904e\u5f8c\u7684\u539f\u6599\u901a\u904e\u93b3\u91d1\u5c6c\uff0c\u78b3\u6eb4\u9375\u7d50\uff08C-Br\uff09\u66ab\u6642\u5730\u88ab\u7f6e\u63db\u6210\u78b3\u93b3\u9375\u7d50\uff08C-Ni\uff09\u3002\u7531\u65bc\u93b3\u91d1\u5c6c\u7684\u50ac\u5316\u53ca\u5468\u906d\u5145\u6eff\u78b3\u6c34\u5316\u5408\u7269\uff0c\u4f7f\u5f97\u78b3\u93b3\u9375\u7d50\u8b8a\u5f97\u4e0d\u7a69\u5b9a\u3002\u78b3\u93b3\u9375\u7d50\u53ef\u4ee5\u5728\u78b3\u93c8\u4e0a\u79fb\u52d5\uff0c\u76f4\u5230\u5b83\u5230\u9054\u5206\u5b50\u7684\u672b\u7aef\u624d\u6703\u7a69\u5b9a\uff08\u5716\u4e09c, d\uff09\u3002\u6700\u5f8c\uff0c\u901a\u5165\u4e8c\u6c27\u5316\u78b3\u6c23\u9ad4\uff0c\u78b3\u93b3\u9375\u7d50\u88ab\u8f49\u63db\u6210\u7fa7\u57fa(-COOH)\uff0c\u4f7f\u5206\u5b50\u8b8a\u6210\u8102\u80aa\u9178\uff08\u5716\u4e09e\uff09\u3002\u9019\u500b\u88fd\u7a0b\u6709\u4e00\u500b\u975e\u5e38\u68d2\u7684\u6027\u8cea\uff1a\u7121\u8ad6\u4e00\u958b\u59cb\u539f\u6599\u7684\u96d9\u9375\u5728\u54ea\u88e1\uff0c\u90fd\u6703\u56e0\u70ba\u78b3\u93b3\u9375\u7d50\u7684\u79fb\u52d5\uff0c\u7522\u751f\u7d50\u69cb\u76f8\u540c\u7684\u8102\u80aa\u9178\uff01<\/p>\n<p><figure id=\"attachment_28139\" aria-describedby=\"caption-attachment-28139\" style=\"width: 700px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-28139\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2017\/05\/fig3-1.png\" alt=\"\" width=\"700\" height=\"417\" \/><figcaption id=\"caption-attachment-28139\" class=\"wp-caption-text\">\u5716\u4e09\u3001\u8102\u80aa\u9178\u88fd\u7a0b\u3002[\u53c3]<\/figcaption><\/figure>\u5728\u6574\u500b\u88fd\u7a0b\u4e2d\u6700\u95dc\u9375\u7684\u4e00\u6b65\u662f\u93b3\u539f\u5b50\u7684\u79fb\u52d5\u3002\u7531\u65bc\u9031\u906d\u7684\u5316\u5b78\u74b0\u5883\u4f7f\u7136\uff0c\u78b3\u93b3\u9375\u7d50\u6709\u6642\u6703\u66ab\u6642\u88ab\u6253\u65b7\uff0c\u78b3\u539f\u5b50\u548c\u9694\u58c1\u78b3\u539f\u5b50\u91cd\u65b0\u5f62\u6210\u96d9\u9375\uff0c\u800c\u93b3\u539f\u5b50\u5247\u548c\u9644\u8fd1\u7684\u6c2b\u539f\u5b50\u7d50\u5408\uff08\u5716\u4e09c\uff09\u3002\u9019\u500b\u93b3\u6c2b\u4e2d\u9593\u7522\u7269\u5176\u5be6\u4e0d\u592a\u7a69\u5b9a\uff0c\u93b3\u539f\u5b50\u4e00\u6709\u6a5f\u6703\u5c31\u548c\u9694\u58c1\u7684\u78b3\u539f\u5b50\u91cd\u65b0\u5f62\u6210\u78b3\u93b3\u9375\u7d50\uff0c\u6574\u500b\u904e\u7a0b\u5c31\u597d\u50cf\u78b3\u93b3\u9375\u7d50\u88ab\u642c\u904b\u5230\u9694\u58c1\u4e00\u6a23\u3002\u5c31\u9019\u6a23\uff0c\u78b3\u93b3\u9375\u7d50\u5728\u78b3\u93c8\u4e0a\u9762\u4f86\u56de\u904a\u8d70\uff0c\u76f4\u5230\u5b83\u5230\u9054\u5206\u5b50\u672b\u68a2\u3002\u7d93\u904e\u9019\u500b\u904e\u7a0b\uff0c\u539f\u6599\u4e2d\u7684\u6240\u6709\u5b98\u80fd\u57fa\u90fd\u88ab\u96c6\u4e2d\u5230\u672b\u7aef\uff0c\u4f7f\u6211\u5011\u80fd\u628a\u4e0d\u540c\u7d50\u69cb\u88fd\u9020\u6210\u4e00\u6a21\u4e00\u6a23\u7684\u8102\u80aa\u9178\u3002<\/p>\n<p>\u4e0a\u8ff0\u662f\u900f\u904e\u79fb\u52d5\u5b98\u80fd\u57fa\u5230\u672b\u7aef\u7684\u65b9\u6cd5\u88fd\u9020\u8102\u80aa\u9178\u3002\u7531\u65bc\u539f\u6599\u7684\u78b3\u93c8\u5169\u7aef\u662f\u4e00\u6a23\u7684\uff0c\u8102\u80aa\u9178\u63a5\u5728\u54ea\u4e00\u5074\u4e26\u4e0d\u91cd\u8981\u3002\u4f46\u5982\u679c\u539f\u6599\u7684\u78b3\u93c8\u672c\u8eab\u5c31\u5177\u6709\u4e0d\u540c\u7684\u5b98\u80fd\u57fa\u5728\u5169\u7aef\uff0c\u5229\u7528\u4e0a\u8ff0\u7684\u65b9\u6cd5\u4ecd\u6703\u88fd\u9020\u51fa\u5169\u7a2e\u4e0d\u540c\u7684\u8102\u80aa\u9178\u3002\u56e0\u61c9\u6b64\u554f\u984c\uff0c\u79d1\u5b78\u5bb6\u767c\u660e\u4e00\u7a2e\u65b9\u6cd5\u53ef\u4ee5\u6c7a\u5b9a\u7fa7\u57fa\u8981\u63a5\u5728\u78b3\u93c8\u7684\u54ea\u4e00\u7aef\u3002\u5982\u5716\u56db\u6240\u793a\uff0c\u5982\u679c\u5c07\u6eab\u5ea6\u63a7\u5236\u572842\u201350 \u00b0C\uff0c\u78b3\u93b3\u9375\u7d50\u50be\u5411\u65bc\u5f85\u5728\u5de6\u908a\u3002\u53cd\u4e4b\uff0c\u5982\u679c\u5c07\u6eab\u5ea6\u7dad\u6301\u5728\u7d0410 -25\u00b0C\uff0c\u78b3\u93b3\u9375\u7d50\u559c\u6b61\u5f85\u5728\u53f3\u908a\u3002\u5982\u6b64\u4e00\u4f86\uff0c\u6211\u5011\u900f\u904e\u9078\u64c7\u6eab\u5ea6\uff0c\u53ef\u4ee5\u9078\u64c7\u8981\u7522\u751f\u54ea\u4e00\u7a2e\u8102\u80aa\u9178\u3002<\/p>\n<p><figure id=\"attachment_28140\" aria-describedby=\"caption-attachment-28140\" style=\"width: 700px\" class=\"wp-caption aligncenter\"><img loading=\"lazy\" decoding=\"async\" class=\"wp-image-28140\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2017\/05\/fig4-1.png\" alt=\"\" width=\"700\" height=\"150\" \/><figcaption id=\"caption-attachment-28140\" class=\"wp-caption-text\">\u5716\u56db\u3001\u5b8c\u5168\u76f8\u540c\u7684\u5316\u5b78\u74b0\u5883\u4e0b\uff0c\u7531\u6eab\u5ea6\u63a7\u5236\u53cd\u61c9\u3002\u5728\u9ad8\u6eab\u6642(42\u00b0C)\uff0c\u7fa7\u57fa\u63a5\u5728\u5de6\u5074\u3002\u5728\u4f4e\u6eab\u6642(10\u00b0C)\uff0c\u7fa7\u57fa\u63a5\u5728\u53f3\u5074\u3002[\u53c3]<\/figcaption><\/figure>\u5728\u5316\u5b78\u5de5\u696d\u4e2d\uff0c\u8a31\u591a\u6709\u6a5f\u6750\u6599\u3001\u805a\u5408\u7269\u7684\u539f\u6599\u53ca\u5408\u6210\u53cd\u61c9\u6210\u672c\u5176\u5be6\u975e\u5e38\u4f4e\u5ec9\uff0c\u82b1\u8cbb\u9ad8\u7684\u5730\u65b9\u5728\u65bc\u7d14\u5316\u3002\u79d1\u5b78\u5bb6\u63d0\u51fa\u7684\u9019\u500b\u88fd\u7a0b\uff0c\u5c55\u793a\u4e86\u5982\u4f55\u8ff4\u907f\u7d14\u5316\u7684\u6b65\u9a5f\uff0c\u88fd\u4f5c\u55ae\u4e00\u54c1\u7a2e\u7684\u8102\u80aa\u9178\u3002\u9664\u4e86\u7528\u4e8c\u6c27\u5316\u78b3\u88fd\u6210\u6709\u6a5f\u9178\u5916\uff0c\u5982\u679c\u9084\u80fd\u7528\u4e0d\u540c\u53cd\u61c9\u7269\u88fd\u6210\u66f4\u5ee3\u6cdb\u7684\u5b98\u80fd\u57fa\uff0c\u76f8\u4fe1\u5b83\u6703\u6380\u8d77\u98a8\u66b4\uff0c\u5fb9\u5e95\u6539\u8b8a\u5316\u5b78\u5de5\u696d\u7684\u6a19\u6e96\uff01<\/p>\n<p>&nbsp;<\/p>\n<p><strong>\u53c3\u8003\u8cc7\u6599\uff1a<\/strong>Francisco Juli\u00e1-Hern\u00e1ndez, Remote carboxylation of halogenated aliphatic hydrocarbons with carbon dioxide, <em>Nature <\/em>545, 84\u201388 (2017)<\/p>\n<p>--<br \/>\n<span style=\"color: #333399;\"><strong>\u4f5c\u8005\uff1a\u9673\u5955\u5ef7\uff0c\u53f0\u5927\u7269\u7406\u7cfb\u5b78\u58eb\uff0c\u53f2\u4e39\u4f5b\u5927\u5b78\u61c9\u7528\u7269\u7406\u7cfb\u535a\u58eb\u73ed\u5c31\u8b80\u4e2d\u3002<wbr \/>\u5c0d\u5404\u9818\u57df\u7684\u79d1\u5b78\u90fd\u975e\u5e38\u597d\u5947\uff0c\u6b61\u8fce\u4e92\u76f8\u4ea4\u6d41\u3002<\/strong><\/span><\/p>\n<p>&nbsp;<\/p>\n<p><a href=\"https:\/\/line.me\/R\/ti\/p\/%40fcx6182w\" target=\"_blank\" rel=\"noopener noreferrer\"><img loading=\"lazy\" decoding=\"async\" class=\"alignnone\" src=\"https:\/\/scdn.line-apps.com\/n\/line_add_friends\/btn\/zh-Hant.png\" alt=\"\u52a0\u5165\u597d\u53cb\" width=\"212\" height=\"36\" border=\"0\" \/><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u25a0\u6709\u6a5f\u5316\u5408\u7269\u5728\u751f\u6d3b\u4e2d\u904d\u8655\u53ef\u898b\uff0c\u8209\u51e1\u5851\u81a0\u888b\u3001\u6f64\u6ed1\u6cb9\u548c\u6e05\u6f54\u5291\u7b49\uff0c\u90fd\u662f\u6709\u6a5f\u5316\u5b78\u5de5\u7a0b\u7684\u7522\u7269\u3002\u7522\u751f\u7d14\u5ea6\u9ad8\u7684\u6709\u6a5f\u7522\u7269\u662f\u5316\u5de5\u88fd\u7a0b\u7684\u76ee\u6a19\u4e5f\u662f\u6311\u6230\u3002\u9577\u4e45\u4ee5\u4f86\uff0c\u5e38\u898b\u7684\u7d14\u5316\u65b9\u6cd5\u662f\u5206\u993e\u6cd5\uff0c\u900f\u904e\u7269\u7406\u6027\u8cea\u5206\u96e2\u4e0d\u540c\u7684\u5316\u5408\u7269\uff0c\u9019\u500b\u904e\u7a0b\u7de9\u6162\u4e14\u6210\u672c\u9ad8\u3002\u5982\u679c\u6709\u4e00\u7a2e\u53cd\u61c9\uff0c\u80fd\u628a\u7d50\u69cb\u4e0d\u540c\u7684\u6709\u6a5f\u7269\uff0c\u901a\u901a\u8b8a\u6210\u76f8\u540c\u7684\u76ee\u6a19\u7522\u7269\uff0c\u90a3\u8a72\u6709\u591a\u597d\uff1f<\/p>\n","protected":false},"author":20,"featured_media":28136,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[32,1023,3293],"tags":[808,3417,3416,923],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2017\/05\/front-1.jpg","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/28135"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=28135"}],"version-history":[{"count":2,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/28135\/revisions"}],"predecessor-version":[{"id":31775,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/28135\/revisions\/31775"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/28136"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=28135"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=28135"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=28135"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}