{"id":25753,"date":"2016-10-11T13:40:11","date_gmt":"2016-10-11T05:40:11","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=25753"},"modified":"2018-08-03T15:17:35","modified_gmt":"2018-08-03T07:17:35","slug":"%e6%9d%8e%e9%81%a0%e5%93%b2%e7%9a%84%e7%a7%91%e5%ad%b8%e6%8e%a2%e7%b4%a2%e4%ba%ba%e7%94%9f%ef%bc%9a%e3%80%8c%e6%87%89%e8%a9%b2%e6%b2%92%e5%95%8f%e9%a1%8c%e7%9a%84%ef%bc%81%e3%80%8d","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=25753","title":{"rendered":"\u3010\u674e\u9060\u54f2\u7372\u9812\u8afe\u8c9d\u723e\u5316\u5b78\u734e30\u9031\u5e74\u3011\u674e\u9060\u54f2\u7684\u79d1\u5b78\u63a2\u7d22\u4eba\u751f\uff1a\u300c\u61c9\u8a72\u6c92\u554f\u984c\u7684\uff01\u300d"},"content":{"rendered":"<figure id=\"attachment_25754\" aria-describedby=\"caption-attachment-25754\" style=\"width: 650px\" class=\"wp-caption aligncenter\"><img fetchpriority=\"high\" decoding=\"async\" class=\"wp-image-25754\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2016\/10\/Q5.jpg\" alt=\"\u5716\u4e00\" width=\"650\" height=\"490\" srcset=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2016\/10\/Q5.jpg 1301w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2016\/10\/Q5-800x603.jpg 800w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2016\/10\/Q5-600x452.jpg 600w\" sizes=\"(max-width: 650px) 100vw, 650px\" \/><figcaption id=\"caption-attachment-25754\" class=\"wp-caption-text\">\u5716\u4e00<\/figcaption><\/figure>\n<p><strong>\u539f\u6587\u4f5c\u8005\uff5c<\/strong>Dudley Herschbach<br \/>\n<strong>\u7ffb\u8b6f\uff5c<\/strong>\u5433\u5b9c\u606c<br \/>\n(\u539f\u6587\u520a\u767b\u65bc\uff1aJ. Phys. Chem. A 1997, 101, 6341-6344)<\/p>\n<p>\u5341\u5206\u69ae\u5e78\u80fd\u6709\u9019\u500b\u6a5f\u6703\u548c\u5927\u5bb6\u8ac7\u8ac7\u674e\u9060\u54f2\u3002\u5c0d\u65bc\u6211\u3001\u4ed6\u7684\u8a31\u591a\u5b78\u751f\u8207\u540c\u4e8b\u5011\u800c\u8a00\uff0c\u4ed6\u5be6\u5728\u662f\u500b\u300c\u6563\u767c\u7121\u6bd4\u7684\u4eba\u6027\u5149\u8f1d\u7684\u7f8e\u9e97\u4eba\u751f\u3001\u5c0d\u79d1\u5b78\u5168\u5fc3\u6295\u5165\uff0c\u7121\u79c1\u4e14\u5145\u6eff\u7406\u60f3\u300d\uff0c\u4e14\u5c0d\u6559\u80b2\u8207\u516c\u5171\u4e8b\u52d9\u7a4d\u6975\u5949\u737b\u7684\u4eba\uff01\u5f15\u865f\u88e1\u7684\u53e5\u5b50\u5f15\u7528\u81ea\u674e\u9060\u54f2\u672c\u4eba\u5c0d\u5c45\u79ae\u592b\u4eba(Madame Curie)\u7684\u63cf\u8ff0(\u6211\u53ea\u662f\u628a\u300c\u5979\u300d\u63db\u6210\u4e86\u300c\u4ed6\u300d\u800c\u5df2)\u3002\u5b69\u7ae5\u6642\u671f\uff0c\u674e\u9060\u54f2\u56e0\u70ba\u8b80\u4e86\u4f9d\u8299\u5c45\u79ae( Eve Curie)\u70ba\u5979\u6bcd\u89aa\u5c45\u79ae\u592b\u4eba\u6240\u64b0\u5beb\u7684\u50b3\u8a18\u800c\u6df1\u53d7\u611f\u52d5\uff0c\u6c7a\u5fc3\u65e5\u5f8c\u8981\u6210\u70ba\u4e00\u4f4d\u79d1\u5b78\u5bb6\u3002\u6211\u5e0c\u671b\uff0c\u5e74\u8f15\u4eba\u80fd\u5920\u5f9e\u674e\u9060\u54f2\u7cbe\u5f69\u4eba\u751f\u6545\u4e8b\u5f97\u5230\u555f\u767c\uff0c\u800c\u9078\u64c7\u79d1\u5b78\u70ba\u4eba\u751f\u5fd7\u696d\u3002<!--more--><\/p>\n<p>\u5728\u4e9e\u6d32\u50b3\u7d71\u88e1\uff0c\u516d\u5341\u6b72\u751f\u65e5\u5e38\u4e45\u4ee5\u4f86\u88ab\u8a8d\u70ba\u662f\u500b\u7279\u6b8a\u610f\u7fa9\u65e5\u5b50\u3002\u6b77\u7d93\u4e94\u8f2a\u5341\u4e8c\u500b\u5e74\u982d\u7684\u5faa\u74b0\uff0c\u9019\u5929\u662f\u6176\u8cc0\u751f\u547d\u7684\u5967\u5999\u8207\u548c\u8ae7\u7684\u65e5\u5b50\uff0c\u4e5f\u662f\u61c9\u9059\u656c\u7956\u5148\u53ca\u601d\u8003\u672a\u4f86\u7684\u65e5\u5b50\u3002\u7121\u53ef\u514d\u4fd7\u5730\uff0c\u65bc\u6b64\u6642\uff0c\u56de\u9867\u674e\u9060\u54f2\u7684\u904e\u5f80\u7684\u4eba\u751f\u6b77\u7a0b\uff0c\u4ed6\u7684\u65e9\u671f\u7684\u751f\u6d3b\u4e8b\u8de1\u5f88\u5bb9\u6613\u88ab\u63d0\u8d77\uff0c\u5305\u62ec\u4e00\u4e9b\u7279\u5225\u53db\u9006\u9802\u649e\u4e4b\u4e8b\uff0c\u5176\u4e2d\u6709\u4e9b\u662f\u547d\u4e2d\u6ce8\u5b9a\u7684\uff0c\u6709\u4e9b\u5247\u662f\u640f\u541b\u4e00\u7b11\u7684\u8da3\u4e8b\u3002\u800c\u9019\u4e9b\u4e8b\u8de1\u5c0d\u7167\u4ed6\u5f8c\u4f86\u7684\u5091\u51fa\u6210\u5c31\uff0c\u6709\u8a31\u591a\u771f\u53ef\u63d0\u4f9b\u5e74\u8f15\u79d1\u5b78\u5bb6\u5011\u4e00\u4e9b\u501f\u93e1\uff0c\u9019\u5c31\u5982\u78b0\u649e\u52d5\u529b\u5b78\u4e00\u6a23\uff0c\u901a\u5e38\u521d\u59cb\u689d\u4ef6\u8207\u5982\u4f55\u4f7f\u529b\u80fd\u767c\u751f\u78b0\u649e\u662f\u540c\u7b49\u7684\u91cd\u8981\u3002<\/p>\n<p>\u674e\u9060\u54f2\u662f\u53f0\u7063\u65b0\u7af9\u4eba\uff0c\u51fa\u751f\u65bc\u897f\u5143\u4e00\u4e5d\u4e09\u516d\u5e74\u5341\u4e00\u6708\u5341\u4e5d\u65e5\uff0c\u4e5d\u500b\u5b69\u5b50\u4e2d\u6392\u884c\u8001\u4e09\u3002\u7236\u89aa\u674e\u6fa4\u85e9\u662f\u8077\u696d\u85dd\u8853\u5bb6\uff0c\u6bcd\u89aa\u8521\u914d\u5247\u662f\u570b\u5c0f\u6559\u5e2b\u3002\u65bc\u5341\u516d\u4e16\u7d00\uff0c\u7956\u5148\u5f9e\u4e2d\u570b\u5927\u9678\u79fb\u5c45\u53f0\u7063\u3002\u674e\u9060\u54f2\u958b\u59cb\u4e0a\u5b78\u6642\uff0c\u53f0\u7063\u4ecd\u8655\u5728\u65e5\u672c\u7d71\u6cbb\u4e4b\u4e0b\uff0c\u7b2c\u4e8c\u6b21\u4e16\u754c\u5927\u6230\u671f\u9593\uff0c\u5168\u5bb6\u66fe\u7d93\u88ab\u8feb\u5f9e\u5e02\u5340\u907f\u5c45\u5230\u5c71\u5340\u4ee5\u8eb2\u958b\u540c\u76df\u570b\u7684\u8f5f\u70b8\uff0c\u8981\u5230\u6230\u722d\u7d50\u675f\u5f8c\u7684\u5c0f\u5b78\u4e09\u5e74\u7d1a\uff0c\u624d\u80fd\u6b63\u5e38\u5730\u4e0a\u4e0b\u5b78\u3002\u5728\u5c0f\u5b78\u5538\u66f8\u7684\u9019\u6bb5\u65e5\u5b50\u88e1\uff0c\u674e\u9060\u54f2\u975e\u5e38\u71b1\u8877\u65bc\u9ad4\u80b2\u6d3b\u52d5\uff0c\u66fe\u7372\u5f97\u5168\u7701\u5c0f\u5b78\u4e52\u4e53\u8cfd\u7684\u51a0\u8ecd\uff0c\u9084\u66fe\u662f\u58d8\u7403\u968a\u4e8c\u58d8\u624b(\u591a\u5e74\u4ee5\u5f8c\uff0c\u9084\u66fe\u88ab\u616b\u607f\u53bb\u6253\u8077\u696d\u68d2\u7403\u5462\uff01)\u3002\u800c\u9ad8\u4e2d\u6642\uff0c\u674e\u9060\u54f2\u662f\u6821\u5167\u7db2\u7403\u968a\u54e1\uff0c\u4e5f\u662f\u7ba1\u6a02\u5718\u88e1\u7684\u4f38\u7e2e\u5587\u53ed\u6a02\u624b\u3002\u5b78\u751f\u6642\u4ee3\uff0c\u674e\u9060\u54f2\u5411\u4f86\u90fd\u662f\u500b\u5c0d\u5468\u906d\u4e8b\u7269\u61f7\u62b1\u71b1\u5ff1\u7684\u5b78\u751f\uff0c\u5e38\u4e3b\u52d5\u6d89\u7375\u95b1\u8b80\u5404\u985e\u66f8\u7c4d\uff0c\u5305\u62ec\u6587\u5b78\u4f5c\u54c1\u3001\u793e\u6703\u79d1\u5b78\u3001\u81ea\u7136\u79d1\u5b78\u7b49\u7b49\u3002<\/p>\n<p>\u7531\u65bc\u9ad8\u4e2d\u6642\u7684\u6210\u7e3e\u512a\u7570\uff0c\u674e\u9060\u54f2\u5728\u4e00\u4e5d\u4e94\u4e94\u5e74\u4fdd\u9001\u9032\u5165\u570b\u7acb\u53f0\u7063\u5927\u5b78\u5c31\u8b80\u3002\u5927\u4e00\u4e0b\u5b78\u671f\u672b\u6c7a\u5b9a\u4e3b\u4fee\u5316\u5b78\uff0c\u65bc\u5316\u5b78\u7cfb\u6642\u7684\u5c08\u984c\u7814\u7a76\u662f\u7531\u912d\u83ef\u751f\u6559\u6388\u6307\u5c0e\u7684\u4f7f\u7528\u7d19\u96fb\u6cf3\u6cd5( 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Hamaguchi)\u6559\u6388\u7684\u6307\u5c0e\u4e0b\uff0c\u7814\u7a76\u984c\u76ee\u662f\u6e2c\u5b9a\u5c6c\u65bc\u6eab\u6cc9\u6c89\u6fb1\u7269\u4e2d\u7684\u4e00\u7a2e\u7926\u77f3(\u5317\u6295\u77f3)\u7684\u653e\u5c04\u7dda\u540c\u4f4d\u6578\u7684\u6210\u5206\uff0c\u65bc1961\u5e74\u7372\u5f97\u78a9\u58eb\u5b78\u4f4d\u5f8c\uff0c\u5728\u6821\u5167\uff0c\u64d4\u4efb\u738b\u4f01\u7965\u6559\u6388\u7684\u5be6\u9a57\u5ba4\u64d4\u4efb\u4e00\u5e74\u7684\u7814\u7a76\u52a9\u7406\uff0c\u4e3b\u8981\u5de5\u4f5c\u6750\u6599\u7d50\u69cb\u7684X\u5149\u9451\u5b9a\u3002<\/p>\n<p>1960\u5e74\uff0c\u6709\u4e00\u4f4d\u4f86\u81ea\u52a0\u5dde\u5927\u5b78\u67cf\u514b\u840a\u5206\u6821\u7684Kenneth Pitzer \u7684\u8a2a\u554f\u6559\u6388\u4f86\u53f0\u8209\u884c\u4e00\u7cfb\u5217\u6f14\u8b1b\uff0c\u9019\u662f\u674e\u9060\u54f2\u7b2c\u4e00\u6b21\u6709\u6a5f\u6703\u548c\u897f\u65b9\u7684\u5b78\u8005\u63a5\u89f8\u3002\u6703\u5f8c\uff0c\u7576\u6642\u53ea\u662f\u4e00\u5e74\u7d1a\u7814\u7a76\u751f\u7684\u674e\u9060\u54f2\u88ab\u6307\u6d3e\u5c07\u5176\u6f14\u8b1b\u5167\u5bb9\u9304\u97f3\u5e36\u807d\u8b6f\u6210\u4e2d\u6587\uff0c\u4ee5\u4fbf\u520a\u767b\u5728\u4e2d\u570b\u5316\u5b78\u6703\u8a8c( Journal of the Chinese Chemical Society )\u4e0a\uff0c\u9019\u5c0d\u7576\u6642\u82f1\u6587\u80fd\u529b\u4ecd\u662f\u666e\u666e\u901a\u901a\u7684\u674e\u9060\u54f2\u4f86\u8aaa\uff0c\u53ef\u8aaa\u662f\u4efd\u4e00\u4ef6\u82e6\u5dee\u4e8b\u3002\u674e\u9060\u54f2\u56de\u61b6\uff0c\u7576\u6642\u70ba\u4e86\u89e3\u8b6f\u67d0\u4e9b\u7279\u5b9a\u7684\u55ae\u5b57\u6216\u53e5\u5b50\uff0c\u4ed6\u9700\u4e0d\u65b7\u91cd\u8907\u64ad\u653e\u9304\u97f3\u5e36\uff0c\u751a\u81f3\u9304\u97f3\u5e36\u90fd\u88ab\u78e8\u640d\u65b7\u4e86\u3002\u7136\u800c\uff0c\u9019\u6a23\u8a9e\u8a00\u78e8\u7df4\uff0c\u674e\u9060\u54f2\u58d3\u6839\u5152\u6c92\u60f3\u5230\uff0c\u6709\u4e00\u5929\uff0c\u4ed6\u7684\u6f14\u8b1b\u5167\u5bb9\u88ab\u7ffb\u8b6f\u6210\u5404\u7a2e\u8a9e\u8a00\u3002<\/p>\n<p>1962\u5e74\uff0c\u674e\u9060\u54f2\u6c7a\u5b9a\u8d74\u7f8e\u570b\u7e7c\u7e8c\u6df1\u9020\u3002\u70ba\u6b64\uff0c\u4ed6\u66fe\u5c0b\u6c42\u53ef\u80fd\u7684\u5354\u52a9\u3002\u800c\u4ed6\u7576\u6642\u5728\u611b\u8377\u83ef\u5927\u5b78\u653b\u8b80\u751f\u7269\u5316\u5b78\u535a\u58eb\u5b78\u4f4d\u7684\u54e5\u54e5\u2014\u9060\u5ddd\uff0c\u70ba\u5f1f\u5f1f\u5beb\u4e86\u5c01\u4fe1\uff0c\u5411\u67cf\u514b\u840a\u52a0\u5dde\u5927\u5b78\u8a62\u554f\u674e\u9060\u54f2\u7533\u8acb\u6b64\u6240\u5927\u5b78\u6642\u88ab\u63a5\u53d7\u7684\u53ef\u80fd\u6027\u3002\u4e0d\u5e78\u7684\u662f\uff0c\u5728\u67cf\u514b\u840a\u5927\u5b78\u6821\u65b9\u7684\u56de\u4fe1\u4e2d\u5f37\u8abf\uff0c\u7576\u6642\u6821\u65b9\u6c92\u6709\u5916\u570b\u5b78\u751f\u7533\u8acb\u5165\u5b78\u7684\u8a55\u9451\u65b9\u5f0f\u3002\u674e\u9060\u54f2\u5728\u6e05\u83ef\u5927\u5b78\u7684\u6307\u5c0e\u6559\u6388\u738b\u6559\u6388\u7372\u6089\u6b64\u4e8b\u5f8c\uff0c\u7acb\u5373\u634e\u4fe1\u7d66\u5728\u67cf\u514b\u840a\u7684\u674e\u5967\u02d9\u5e03\u723e(Leo Brewer)\u6559\u6388\uff0c\u4fe1\u4e2d\u8868\u793a\uff0c\u81ea\u5df1\u8eab\u70ba\u52a0\u5dde\u7406\u5de5\u5b78\u9662(Caltech)\u7684\u535a\u58eb\u7562\u696d\u751f\uff0c\u4ed6\u80fd\u4fdd\u8b49\uff0c\u674e\u9060\u54f2\u7d55\u5c0d\u4e0d\u8f38\u4efb\u4f55\u4e00\u4f4d\u6bcd\u6821\u4e2d\u4ed6\u8a8d\u8b58\u7684\u7814\u7a76\u751f\u3002\u7531\u65bc\u738b\u6559\u6388\u8eab\u70ba\u79d1\u5b78\u5bb6\u7684\u597d\u8072\u671b\uff0c\u518d\u52a0\u4e0a\u4ed6\u51fa\u4e86\u540d\u80fd\u6167\u773c\u8b58\u82f1\u96c4\u7684\u80fd\u529b\uff0c\u5e03\u723e\u6559\u6388\u88ab\u8aaa\u670d\u800c\u505a\u4e86\u51c6\u4e88\u5165\u5b78\u7684\u6c7a\u5b9a\uff0c\u674e\u9060\u54f2\u4e5f\u5c31\u5982\u9858\u9032\u5165\u67cf\u514b\u840a\u6df1\u9020\u3002<\/p>\n<p><span style=\"color: #008080;\"><strong>\u67cf\u514b\u840a\u521d\u9732\u982d\u89d2<\/strong><\/span><\/p>\n<p>\u540c\u5e74\u79cb\u521d\uff0c\u674e\u9060\u54f2\u4f86\u5230\u6211\u7684\u8fa6\u516c\u5ba4\uff0c\u8a62\u554f\u80fd\u5426\u52a0\u5165\u6211\u7684\u7814\u7a76\u5718\u968a\uff0c\u7576\u6642\u6709\u4e9b\u6e9d\u901a\u4e0a\u7684\u8aa4\u6703\u8b93\u4ed6\u7121\u6cd5\u5982\u9858\uff0c\u6240\u5e78\uff0c\u6211\u5006\u4e4b\u9593\u7d42\u7a76\u6709\u4e86\u5341\u5206\u5713\u6eff\u7684\u7d50\u679c\u3002\u6211\u6536\u7814\u7a76\u751f\u7684\u6e96\u5247\u662f\u6211\u6b61\u8fce\u4efb\u4f55\u60f3\u548c\u6211\u4e00\u540c\u505a\u7814\u7a76\u7684\u5b78\u751f\uff0c\u524d\u63d0\u662f\u4ed6\u5011\u5c0d\u6211\u7684\u7814\u7a76\u5de5\u4f5c\u6709\u6e05\u695a\u7684\u6982\u5ff5\uff0c\u77e5\u9053\u56f0\u96e3\u9ede\u6240\u5728\uff0c\u4e14\u80fd\u63d0\u51fa\u53ef\u671f\u5f85\u7684\u89e3\u6c7a\u65b9\u6cd5\u3002\u9084\u6709\uff0c\u6211\u5e0c\u671b\u6211\u7684\u5b78\u751f\u80fd\u81ea\u5df1\u9078\u64c7\u7814\u7a76\u984c\u76ee\u3002\u6211\u6307\u5c0e\u5b78\u751f\u65b9\u6cd5\u662f\u63d0\u51fa\u89e3\u6c7a\u7814\u7a76\u4e0a\u554f\u984c\u7684\u5404\u7a2e\u53ef\u80fd\u6027\u4e26\u5206\u6790\u5176\u512a\u7f3a\u9ede\u7684\u8a55\u4f30\uff0c\u6211\u4e0d\u6703\u8981\u5b78\u751f\u300c\u61c9\u8a72\u300d\u600e\u9ebc\u505a\u3002\u6211\u901a\u5e38\u6703\u7fd2\u6163\u5730\u5411\u5b78\u751f\u8aaa\uff1a\u300c\u4f60\u6216\u8a31\u53ef\u4ee5\u8003\u616e\u2026\u2026\u300d\u7b49\u9019\u4e9b\u8a71\u3002\u7576\u6642\uff0c\u6211\u7684\u7814\u7a76\u5718\u968a\u96d6\u7136\u5c0d\u65bc\u70f7\u57fa\u7898(alkyl iodides)\u8207\u9e7c\u91d1\u5c6c\u539f\u5b50\u53cd\u61c9\u7684\u4ea4\u53c9\u5206\u5b50\u675f\u7814\u7a76\u6709\u4e0d\u932f\u7684\u7814\u7a76\u6210\u679c\uff0c\u4f46\u662f\u5c0d\u65bc\u5176\u4ed6\u9e75\u7d20\u5316\u5408\u7269\uff0c\u82b1\u4e86\u5f88\u591a\u6642\u9593\u4ecd\u7121\u6cd5\u514b\u670d\u8868\u9762\u96e2\u5b50\u5316\u5075\u6e2c\u5668(surface ionization detector)\u7684\u6c59\u67d3\u554f\u984c\uff0c\u7576\u6642\uff0c\u6211\u5c07\u9019\u4e9b\u4ee4\u6211\u5011\u56f0\u64fe\u7684\u4e8b\u544a\u8a34\u674e\u9060\u54f2\uff0c\u4e5f\u5efa\u8b70\u4ed6\u53ef\u4ee5\u8003\u616e\u9078\u64c7\u6bd4\u8f03\u7a69\u7576\u7684\u7814\u7a76\u984c\u76ee\uff0c\u5982\u5206\u5b50\u675f\u7684\u5fae\u6ce2\u5149\u8b5c\u800c\u4e0d\u662f\u505a\u53cd\u61c9\u7684\u7814\u7a76\uff0c\u4f46\u662f\u7576\u6642\u674e\u9060\u54f2\u8aa4\u89e3\u6211\u9019\u6a23\u7684\u5efa\u8b70\uff0c\u537b\u8f49\u800c\u9078\u64c7\u9032\u5165\u99ac\u4ea8(Bruce Mahan)\u6559\u6388\u7684\u7814\u7a76\u5718\u968a\u3002<\/p>\n<p>\u9694\u5e74\uff0c\u674e\u9060\u54f2\u9078\u4fee\u6211\u6240\u958b\u7684\u91cf\u5b50\u529b\u5b78\u8ab2\u7a0b\uff0c\u53ca\u53e6\u4e00\u9580\u6211\u65b0\u958b\u6709\u95dc\u5206\u5b50\u78b0\u649e\u7406\u8ad6(molecular collision theory)\u66f8\u5831\u8a0e\u8ad6\u8ab2\u7a0b\u3002\u7531\u65bc\uff0c\u5728\u90a3\u5e74\u79cb\u5b63\uff0c\u6211\u6e96\u5099\u8f49\u5f80\u54c8\u4f5b\u5927\u5b78\u4efb\u6559\uff0c\u6240\u4ee5\u9019\u4e9b\u8ab2\u53ef\u8aaa\u662f\u6211\u5728\u67cf\u514b\u840a\u6700\u5f8c\u4efb\u6559\u8ab2\u7a0b\u3002\u5728\u7576\u6642\uff0c\u6211\u6559\u7684\u91cf\u5b50\u529b\u5b78\u8ab2\u662f\u7b2c\u4e00\u6b21\u501f\u7528\u62c9\u8482\u83ab\u5927\u5ef3(Latimer Hall)\u5339\u8332\u79ae\u5802(Pitzer Auditorium)\u4e0a\u8ab2\uff0c\u7531\u65bc\u5c1a\u5728\u52d5\u5de5\uff0c\u6240\u4ee5\uff0c\u5ba4\u5167\u7167\u660e\u8a2d\u5099\u5c1a\u672a\u5efa\u7f6e\u5b8c\u6210\u3002\u6709\u4e00\u500b\u9060\u54f2\u89aa\u81ea\u544a\u8a34\u6211\u7684\u4ed6\u7684\u8a9e\u8a00\u5b78\u7fd2\u63d2\u66f2\u8207\u6b64\u6709\u95dc\uff0c\u7576\u6642\uff0c\u7531\u65bc\u6559\u5ba4\u71c8\u5149\u660f\u6697\uff0c\u9700\u5c07\u908a\u9580\u6253\u958b\uff0c\u6709\u4e00\u6b21\u525b\u597d\u770b\u5230\u5728\u5ba4\u5916\u5f98\u5f8a\u7684\u4e00\u96bb\u72d7\u5728\u5927\u6416\u5c3e\u5df4\uff0c\u6211\u6b63\u8b1b\u5230\u64fe\u52d5(perturbation)\u6b64\u8a5e\u5f59\u7684\u610f\u7fa9\uff0c\u7576\u6642\uff0c\u9060\u54f2\u5c0d\u6b64\u4e26\u4e0d\u5f88\u4e86\u89e3\uff0c\u7576\u6211\u6307\u8457\u5ba4\u5916\u7684\u90a3\u96bb\u72d7\u8aaa\u5b83\u7684\u5c3e\u5df4\u6b63\u64fe\u52d5\u4e2d\uff0c\u9060\u54f2\u5c31\u99ac\u4e0a\u6e05\u695a\u64fe\u52d5\u542b\u610f\u3002<\/p>\n<p>\u674e\u9060\u54f2\u7684\u535a\u58eb\u8ad6\u6587\u7814\u7a76\u662f\u6fc0\u767c\u614b\u9e7c\u91d1\u5c6c\u539f\u5b50\u5316\u5b78\u96e2\u5b50\u5316(chemionization)\u7684\u63a2\u8a0e\uff0c\u5728\u8207\u6307\u5c0e\u6559\u6388\u8f9b\u52e4\u52aa\u529b\u7814\u7a76\u4e0b\uff0c\u5f88\u5feb\u5c31\u6709\u76f8\u7576\u4e0d\u932f\u7684\u6210\u679c\u3002\u7279\u5225\u662f\u6709\u95dc\u65bc\u78ba\u8a8d\u7576\u96fb\u5b50\u5f9e\u4e00\u500b\u9e7c\u91d1\u5c6c\u4e8c\u805a\u9ad4\u5206\u5b50(alkali dimer molecule)\u79fb\u53bb\u5f8c\uff0c\u9375\u8ddd\u6703\u66f4\u9577\u4e14\u9375\u7d50\u66f4\u5f37\u7684\u7814\u7a76\u7d50\u679c\uff0c\u9019\u8207\u7576\u6642\u7684\u5206\u5b50\u8ecc\u9053\u7406\u8ad6(molecular orbital theory)\u8a8d\u70ba\u9375\u8ddd\u66f4\u9577\u4e14\u9375\u7d50\u66f4\u5f31\u7684\u7406\u8ad6\u63a8\u6e2c\uff0c\u6709\u76f8\u7576\u660e\u986f\u7684\u5dee\u7570\u3002\u7576\u6211\u77e5\u9053\u9019\u500b\u7814\u7a76\u6210\u679c\u6642\uff0c\u525b\u5de7\u6709\u6a5f\u6703\u78b0\u5230\u4e00\u500b\u76f8\u7576\u6709\u540d\u7406\u8ad6\u5316\u5b78\u5bb6\uff0c\u7576\u6642\u5728\u54c8\u4f5b\u5927\u5b78\u6709\u500b\u6f14\u8b1b\uff0c\u4e5f\u6b63\u5728\u5beb\u4e00\u672c\u63a2\u8a0e\u5206\u5b50\u8ecc\u57df\u7406\u8ad6\u7684\u5c08\u66f8\uff0c\u6211\u5411\u4ed6\u63d0\u8d77\u9060\u54f2\u6709\u95dc\u9e7c\u91d1\u5c6c\u4e8c\u805a\u9ad4\u7684\u7814\u7a76\u7d50\u679c\u6642\uff0c\u4ed6\u6839\u672c\u4e0d\u76f8\u4fe1\uff0c\u9084\u4fe1\u8a93\u65e6\u65e6\u7684\u8aaa\uff1a\u300c\u5982\u679c\u4f60\u6240\u8a00\u5c6c\u5be6\uff0c\u6211\u5c31\u5f9e\u6b64\u4e0d\u6559\u7406\u8ad6\u5316\u5b78(theoretical chemistry)\u65b9\u9762\u7684\u8ab2\uff01\u300d\u5f8c\u4f86\uff0c\u6211\u5bc4\u7d66\u4ed6\u9060\u54f2\u7814\u7a76\u76f8\u95dc\u8ad6\u6587\u7d66\u4ed6\u5f8c\uff0c\u4ed6\u4e5f\u771f\u7684\u6c92\u6709\u518d\u958b\u9019\u65b9\u9762\u7684\u8ab2\u7a0b\u3002<\/p>\n<p>\u674e\u9060\u54f2\u5728\u4ee5\u4e0d\u5230\u4e09\u5e74\u7684\u6642\u9593\u5167\u7372\u5f97\u535a\u58eb\u5b78\u4f4d\uff0c\u96a8\u5f8c\u7e7c\u7e8c\u5728\u99ac\u4ea8\u6559\u6388\u7684\u5be6\u9a57\u5ba4\u505a\u535a\u58eb\u5f8c\u7814\u7a76\u3002\u99ac\u4ea8\u6559\u6388\u60f3\u505a\u96e2\u5b50-\u5206\u5b50\u53cd\u61c9\u7684\u4ea4\u53c9\u5206\u5b50\u675f(crossed beam studies of ion-molecule reactions)\u7814\u7a76\uff0c\u56e0\u6b64\uff0c\u9060\u54f2\u8207Ron Gentry\u5c31\u4e00\u8d77\u5171\u540c\u9032\u884c\u8a2d\u8a08\u7d44\u88dd<\/p>\n<p>\u76f8\u95dc\u5100\u5668\u8a2d\u5099\uff0c\u5728\u4e0d\u5230\u4e00\u5e74\u7684\u6642\u9593\u88e1\uff0c\u4ed6\u5011\u5c31\u8a2d\u8a08\u7d44\u88dd\u5b8c\u6210\u5728\u7576\u6642\u53ef\u8aaa\u662f\u6700\u5148\u9032\u7684\u5100\u5668\uff0c\u5229\u7528\u6b64\u5100\u5668\u7372\u5f97 <span class='MathJax_Preview'><img src='https:\/\/case.ntu.edu.tw\/blog\/wp-content\/plugins\/latex\/cache\/tex_65f9c4da3a9d0013b9d7e4905cc8879a.gif' style='vertical-align: middle; border: none; padding-bottom:2px;' class='tex' alt=\"\" \/><\/span><script type='math\/tex'><\/script> \u53cd\u61c9\u7522\u7269\u7684\u901f\u5ea6\u8207\u89d2\u5206\u4f48\u7684\u5b8c\u6574\u7b49\u7dda\u5716(complete contour map)\u3002\u57281966\u5e74\uff0c\u9019\u9805\u7814\u7a76\u6210\u679c\u5177\u6709\u6307\u6a19\u6027\u7684\u610f\u7fa9\uff0c\u8d77\u52d5\u4e86\u5f8c\u4f86\u4e00\u500b\u6210\u679c\u76f8\u7576\u8c50\u78a9\u7684\u7814\u7a76\u8a08\u756b\u3002<\/p>\n<p>\u5728\u9019\u9805\u5de5\u4f5c\u904e\u7a0b\u4e2d\uff0c\u674e\u9060\u54f2\u52aa\u529b\u8b93\u81ea\u5df1\u80fd\u6210\u70ba\u51fa\u8272\u5be6\u9a57\u5de5\u4f5c\u8005\uff0c\u5728\u8207\u5728\u8f3b\u5c04\u5be6\u9a57\u5ba4(radiation lab)\u8a2d\u8a08\u5de5\u7a0b\u5e2b\u7684\u5e7e\u6b21\u4ea4\u8ac7\u4e2d\uff0c\u4fbf\u4e3b\u52d5\u8981\u6c42\u80fd\u5920\u6559\u4ed6\u5982\u4f55\u7e6a\u5716\u3001\u710a\u63a5\u9806\u5e8f\u3001\u87ba\u7d72\u5b54\u7684\u7cbe\u78ba\u5ea6\u7684\u78ba\u5b9a\u7b49\u7b49\uff0c\u7d93\u904e\u4e00\u661f\u671f\u7684\u5bc6\u96c6\u5b78\u7fd2\uff0c\u674e\u9060\u8457\u5c31\u5b8c\u5168\u5f04\u61c2\u4e86\u9019\u4e9b\u4e8b\uff0c\u5f9e\u6b64\u5f8c\uff0c\u5100\u5668\u8a2d\u8a08\u76f8\u95dc\u7684\u7e6a\u5716\u548c\u5143\u4ef6\u88fd\u4f5c\u3001\u7d44\u88dd\u5de5\u4f5c\uff0c\u4ed6\u90fd\u81ea\u5df1\u4e00\u624b\u5305\u8fa6\u3002\u6b64\u6642\uff0c\u9060\u54f2\u82f1\u6587\u80fd\u529b\u4e5f\u5927\u5e45\u63d0\u5347\uff0c\u9019\u8981\u6b78\u529f\u65bc\u99ac\u4ea8\u6559\u6388\u7684\u5805\u6301\uff0c\u56e0\u70ba\u4ed6\u8981\u6c42\u5b78\u751f\u8207\u4ed6\u6e9d\u901a\u5fc5\u9808\u4f7f\u7528\u5b8c\u6574\u7684\u82f1\u6587\u53e5\u5b50\uff0c\u7531\u65bc\u674e\u9060\u54f2\u5e38\u6709\u65b0\u7684\u7814\u7a76\u6210\u679c\u8981\u5831\u544a\uff0c\u800c\u4e14\u7814\u7a76\u5718\u968a\u4e0d\u5927\uff0c\u6240\u4ee5\uff0c\u9060\u54f2\u4e09\u5929\u5169\u982d\u88e1\u5f97\u5411\u5927\u5bb6\u505a\u82f1\u6587\u5831\u544a\uff0c\u7121\u5f62\u4e2d\u63d0\u6607\u4e86\u82f1\u6587\u80fd\u529b\u3002<\/p>\n<p><span style=\"color: #008080;\"><strong>\u773e\u4eba\u5e0c\u671b\u5bc4\u8a17\u7684\u54c8\u4f5b\u6b72\u6708<\/strong><\/span><\/p>\n<p>1967\u5e742\u6708\uff0c\u674e\u9060\u54f2\u4f86\u5230\u54c8\u4f5b\u52a0\u5165\u6211\u7684\u7814\u7a76\u5718\u968a\u7576\u535a\u58eb\u5f8c\u7814\u7a76\u54e1\uff0c\u591a\u5e74\u4ee5\u5f8c\uff0c\u6211\u624d\u77e5\u9053\uff0c\u4ed6\u4f86\u6b64\u7684\u4e3b\u8981\u76ee\u7684\u662f\u70ba\u4e86\u80fd\u7372\u5f97\u591a\u9ede\u7406\u8ad6\u5de5\u4f5c\u65b9\u9762\u7684\u7d93\u9a57\uff0c\u56e0\u70ba\u4ed6\u78ba\u4fe1\u81ea\u5df1\u5728\u5be6\u9a57\u64cd\u4f5c\u548c\u5100\u5668\u88fd\u9020\u65b9\u9762\u5df2\u7d93\u5341\u5206\u5afb\u719f\u3002\u4f46\u662f\u7576\u6642\u7684\u674e\u9060\u54f2\u537b\u4e0d\u597d\u610f\u601d\u544a\u8a34\u6211\u4ed6\u7684\u5fc3\u610f\uff0c\u5728\u6211\u5efa\u8b70\u4ed6\u505a\u5169\u9805\u5be6\u9a57\u5c08\u984c\u6642\uff0c\u4ed6\u4e5f\u50c5\u50c5\u9806\u5f9e\u800c\u6c92\u6709\u7570\u8b70\u3002\u5176\u4e2d\u4e00\u9805\u5c08\u984c\u662f\u6c2b\u539f\u5b50\u8207\u9e7c\u91d1\u5c6c\u4e8c\u805a\u9ad4\u5206\u5b50\u4ea4\u53c9\u675f\u7814\u7a76(a crossed beam study of reaction of hydrogen atoms with alkali dimer molecules)\uff0c\u4ed6\u548c\u53e6\u4e00\u4f4d\u78a9\u58eb\u751f\u7f85\u4f2f\u02d9\u9ad8\u767b(Robert Gordon)\u5171\u540c\u5408\u4f5c\u9032\u884c\u6b64\u5be6\u9a57\u3002\u9019\u9805\u5be6\u9a57\u4e26\u4e0d\u9700\u8981\u6253\u9020\u65b0\u7684\u5100\u5668\uff0c\u505a\u51fa\u7684\u6210\u679c\u4e5f\u4e00\u5982\u9810\u671f\u7b26\u5408\u674e\u9060\u54f2\u7576\u521d\u7684\u535a\u58eb\u8ad6\u6587\u8ad6\u9ede\uff0c\u662f\u4e8c\u805a\u9ad4\u8207\u5b83\u5011\u96e2\u5b50\u7279\u6b8a\u6027\u8cea\u6240\u5f15\u767c\u7684\u52d5\u614b\u884c\u70ba\u6700\u4f73\u793a\u4f8b\u3002\u4f46\u662f\uff0c\u674e\u9060\u54f2\u548c\u7f85\u4f2f\u5728\u505a\u5be6\u9a57\u6642\uff0c\u53c8\u505a\u4e86\u500b\u5192\u96aa\u7684\u5617\u8a66\u3002\u4ed6\u5011\u7528\u504f\u8f49\u96fb\u78c1\u9435\u60f3\u5f9e\u6bcd\u9ad4\u9e7c\u91d1\u5c6c\u539f\u5b50\u675f\u88e1\u628a\u4e00\u90e8\u4efd\u4e8c\u805a\u9ad4\u6790\u51fa\uff0c\u5728\u64cd\u4f5c\u7576\u4e2d\uff0c\u767c\u73fe\u7528\u4f86\u51b7\u537b\u78c1\u9435\u88dd\u6709\u51b7\u537b\u6c34\u7684\u7ba1\u5b50\u7a81\u7136\u6f0f\u6db2\uff0c\u4f7f\u5f97\u771f\u7a7a\u5ba4\u6ce8\u6eff\u4e86\u6c34\u3002\u7136\u800c\uff0c\u6e05\u7406\u5b8c\u5100\u5668\u5f8c\u5f8c\uff0c\u4ed6\u5011\u767c\u73fe\u5100\u5668\u7adf\u7136\u53cd\u800c\u66f4\u597d\u64cd\u4f5c\u4e86\uff01<\/p>\n<p>\u4ed6\u5011\u6709\u53e6\u4e00\u500b\u66f4\u4f01\u5716\u5fc3\u7684\u8a08\u756b\u60f3\u9032\u884c\uff0c\u5c31\u662f\u8a2d\u8a08\u7d44\u88dd\u4e00\u500b\u5c07\u7814\u7a76\u5718\u968a\u7684\u80fd\u529b\u5e36\u5165\u300c\u80fd\u8de8\u8d8a\u5f37\u9e7c\u6642\u4ee3\u300d\u7684\u5148\u9032\u6a5f\u5668\u3002\u65e9\u671f\uff0c\u5206\u5b50\u675f\u5316\u5b78\u53ea\u8457\u91cd\u65bc\u9e7c\u91d1\u5c6c\u53cd\u61c9\uff0c\u7576\u6642\uff0c\u5c0d\u975e\u9e7c\u91d1\u5c6c\u53cd\u61c9\u7684\u5206\u5b50\u675f\u7814\u7a76\uff0c\u5145\u65a5\u8457\u60b2\u89c0\u8ad6\u8abf\u3002\u5718\u968a\u88e1\u5118\u7ba1\u6709\u4e00\u4e9b\u9019\u65b9\u9762\u76f8\u95dc\u555f\u767c\u6027\u52d5\u529b\u5b78\u7d50\u679c\u51fa\u73fe\uff0c\u61f7\u7591\u8ad6\u8005\u8a8d\u70ba\u9084\u662f\u8a8d\u70ba\u4ed6\u5011\u662f\u4e00\u7fa4\u53e4\u602a\u3001\u7279\u7570\u7684\u50a2\u4f19\u7684\u884c\u70ba\uff0c\u9019\u4e3b\u8981\u6e90\u81ea\u65bc\u4f7f\u7528\u8cea\u8b5c\u5075\u6e2c(mass spectrometric detection)\u6642\uff0c\u7576\u6642\u7684\u6280\u8853\u5c1a\u7121\u6cd5\u5b8c\u5168\u514b\u670d\u96fb\u5b50\u649e\u64ca\u5340(electron bombardment region)\u7684\u80cc\u666f\u5e72\u64fe\u3002\u6709\u597d\u5e7e\u500b\u6708\u7684\u6642\u9593\u88e1\uff0c\u674e\u9060\u54f2\u5e38\u548c\u4ed6\u7684\u5de5\u4f5c\u5925\u4f34\u9ad8\u767b\u5229\u7528\u5348\u9910\u524d\u53ca\u665a\u9910\u5f8c\u7684\u6642\u9593\u9032\u884c\u547d\u540d\u70ba\u300c\u5e0c\u671b(Hope)\u300d\u65b0\u5100\u5668\u7684\u8a2d\u8a08\u8a08\u7b97\u548c\u8349\u5716\u7e6a\u88fd\u3002\u96a8\u5f8c\uff0c\u6709\u5169\u500b\u65b0\u7814\u7a76\u751f\uff0c\u76ae\u57c3\u723e\u02d9\u52d2\u5e03\u96f7\u9813(Pierre LeBreton)\u548c\u9053\u683c\u02d9\u9ea5\u7576\u52de(Doug McDonald)\u9678\u7e8c\u52a0\u5165\uff0c\u4ed6\u5011\u5169\u4eba\u90fd\u6709\u984d\u5916\u7684\u7814\u7a76\u8a08\u5283\u5728\u9032\u884c\u3002\u6b64\u5916\uff0cGeorge Pisiello \u548c\u7cfb\u4e0a\u5c0f\u800c\u7f8e\u6a5f\u68b0\u5de5\u5834\u7684\u6a5f\u68b0\u5e2b\u7236\u5011\u4e5f\u9069\u6642\u52a0\u5165\u5354\u52a9\u8a2d\u8a08\u8207\u5efa\u9020\uff0c\u4ed6\u5011\u7b2c\u4e00\u6b21\u88ab\u4ea4\u4ed8\u6b64\u7b49\u91cd\u4efb\uff0c\u4e5f\u78ba\u80fd\u53ca\u6642\u914d\u5408\uff0c\u4e0d\u8ca0\u6240\u8a17\u3002<\/p>\n<p>\u8a2d\u8a08\u7684\u5b8c\u6210\u5f8c\u7684\u5100\u5668\u5404\u500b\u5143\u4ef6\u7d44\u88dd\u7f6e\u5de5\u4f5c\uff0c\u90fd\u80fd\u6309\u6642\u9032\u884c\uff0c\u674e\u9060\u54f2\u5411\u4f86\u6703\u4ed4\u7d30\u6aa2\u8996\u5404\u500b\u9805\u76ee\uff0c\u60f3\u8fa6\u6cd5\u4f7f\u7528\u5176\u4ed6\u5143\u4ef6\u4f86\u514b\u670d\u88fd\u4f5c\u4e0a\u5076\u6709\u7684\u932f\u8aa4(\u4f8b\u5982\u87ba\u5b54\u932f\u4f4d)\u3002\u5718\u968a\u6210\u54e1\u4e5f\u57fa\u65bc\u4e00\u7a2e\u4f7f\u547d\u5fc5\u9054\u7684\u8cac\u4efb\u611f\uff0c\u53ca\u5c0d\u674e\u9060\u54f2\u80fd\u529b\u3001\u5224\u65b7\u529b\u7684\u4fe1\u4efb\uff0c\u6eff\u61f7\u5e79\u52c1\u5730\u4e00\u5fc3\u70ba\u9019\u9805\u4efb\u52d9\u52aa\u529b\u3002\u7576\u554f\u984c\u4e00\u4e00\u5730\u89e3\u6c7a\uff0c\u6bcf\u500b\u4eba\u8a8d\u540c\u674e\u9060\u54f2\u7684\u65b7\u8a9e\uff1a\u300c\u61c9\u8a72\u6c92\u554f\u984c\u7684(Should be all right)\uff01\u300d<\/p>\n<p>\u5728\u9019\u4e9b\u4e8b\u4e0a\uff0c\u674e\u9060\u54f2\u7684\u65b7\u8a9e---\u300c\u61c9\u8a72\u6c92\u554f\u984c\u7684\uff01\u300d\uff0c\u96d6\u7136\u5728\u6587\u6cd5\u4e0a\u4e0d\u662f\u500b\u5b8c\u6574\u53e5\u5b50\uff0c\u537b\u7e3d\u662f\u88ab\u8b49\u660e\u662f\u5c0d\u7684\u3002\u771f\u7684\uff0c\u5728\u674e\u9060\u54f2\u96e2\u958b\u9019\u88cf\u5f8c\u7684\u5e7e\u5e74\u88e1\uff0c\u6211\u5011\u7279\u5730\u5728\u300c\u5e0c\u671b\u300d\u6846\u4e0a\u4e00\u5e45\u4ed6\u7684\u7167\u7247\uff0c\u6a19\u4e0a\u4ed6\u5e38\u8aaa\u7684\u9019\u53e5\u65b7\u8a9e\u3002<\/p>\n<p>\u300c\u5e0c\u671b\u300d\u5f9e\u6700\u65e9\u7684\u8a08\u5283\u69cb\u60f3\u5230\u6e2c\u8a66\uff0c\u53ea\u7528\u4e86\u77ed\u77ed9\u500b\u6708\u7684\u6642\u9593\uff0c\u57281967\u5e74\u8056\u8a95\u524d\u5915\uff0c\u300c\u5e0c\u671b\u300d\u9032\u884c\u7b2c\u4e00\u6b21\u6e2c\u8a66\u3002\u6b64\u6b21\u5be6\u9a57\u662f\u7814\u7a76 <span class='MathJax_Preview'><img src='https:\/\/case.ntu.edu.tw\/blog\/wp-content\/plugins\/latex\/cache\/tex_a4f1fc4f7a763d6d147a5377e1b55de0.gif' style='vertical-align: middle; border: none; padding-bottom:2px;' class='tex' alt=\"\" \/><\/span><script type='math\/tex'><\/script> \u7684\u78b0\u649e\u53cd\u61c9\uff0c\u4e0d\u4e45\u7372\u5f97\u4ee4\u4eba\u6eff\u610f\u6578\u64da\u7d50\u679c\u53ca\u4ee4\u4eba\u6ce8\u76ee\u7684\u76f8\u95dc\u52d5\u529b\u5b78\u4e0a\u610f\u7fa9\u3002\u9019\u500b\u5be6\u9a57\u4e5f\u662f\u8b93\u540c\u884c\u5011\u8208\u596e\u7684\u9996\u4f8b\u7814\u7a76\uff0c\u56e0\u70ba\uff0c\u900f\u904e\u300c\u5e0c\u671b\u300d\u9019\u90e8\u65b0\u5100\u5668\u6216\u8005\u5728\u5176\u4ed6\u5be6\u9a57\u5ba4\u7531\u674e\u9060\u54f2\u5354\u52a9\u88dd\u7f6e\u6216\u5225\u4eba\u4eff\u88fd\u7684\u985e\u4f3c\u5100\u5668\uff0c\u6709\u8a31\u591a\u9019\u65b9\u9762\u7814\u7a76\u9678\u7e8c\u5c55\u958b\u3002\u5716\u4e00\u662f\u201dall right\u201d\u5100\u5668\u300c\u5e0c\u671b\u300d\u80fd\u5920\u5728\u77ed\u6642\u9593\u5167\u5b55\u80b2\u7814\u88fd\u800c\u6210\uff0c\u662f\u6211\u610f\u60f3\u4e0d\u5230\u7684\uff0c\u9019\u8981\u6b78\u529f\u65bc\u9019\u4e9b\u5177\u6709\u7279\u6b8a\u624d\u83ef\u3001\u80af\u52aa\u529b\u8ce3\u547d\u53ca\u6709\u6c23\u9b44\u7684\u7814\u7a76\u5718\u968a\u3002\u4f46\u662f\uff0c\u5728\u9019\u5152\uff0c\u6211\u8981\u63d0\u53ca\u4e00\u4ef6\u76f8\u7576\u95dc\u9375\u7684\u4e8b\uff0c\u5c31\u662f\u7576\u6642\u6211\u96d6\u591a\u65b9\u52aa\u529b\uff0c\u537b\u4e00\u76f4\u82e6\u65bc\u627e\u4e0d\u51fa\u8db3\u5920\u7d93\u8cbb\u4f86\u6253\u9020\u9019\u6a23\u8cb4\u91cd\u7684\u5be6\u9a57\u5100\u5668\u3002\u5373\u4f7f\u662f\u73fe\u5728\uff0c\u4e00\u822c\u7cfb\u4e0a\u7684\u5100\u5668\u7d93\u8cbb\u4e5f\u7528\u65bc\u7cfb\u4e0a\u76f4\u63a5\u8cfc\u8cb7\u8a31\u591a\u7814\u7a76\u5718\u968a\u53ef\u516c\u7528\u8a2d\u5099\uff0c\u800c\u975e\u7528\u65bc\u6559\u6388\u81ea\u884c\u7814\u9020\u7279\u6b8a\u8a2d\u5099\u88dd\u7f6e\u3002\u5e78\u597d\uff0c\u7576\u6642\u7684\u5316\u5b78\u5be6\u9a57\u5ba4\u4e3b\u4efb\u7f85\u6069\u02d9\u74e6\u5167\u5229(Ron Vanelli)\u5c0d\u6211\u5011\u9019\u500b\u5e74\u8f15\u7684\u5718\u968a\u6df1\u5177\u4fe1\u5fc3\uff0c\u5141\u8a31\u6211\u7e7c\u7e8c\u5f9e\u6211\u7528\u8d64\u5b57\u9810\u7b97\u65b9\u5f0f\u5f9e\u6211\u7684\u7814\u7a76\u5e33\u6236\u5148\u501f\u63d0\u8cc7\u91d1(\u65bc1967 \u5e74\u6642\uff0c\u517180,000\u7f8e\u91d1)\uff0c\u4ee5\u7528\u4f86\u6253\u9020\u300c\u5e0c\u671b\u300d\u3002\u9019\u6a23\u7684\u4e8b\uff0c\u5373\u4f7f\u5728\u4eca\u5929\u6839\u672c\u4e0d\u53ef\u80fd\u767c\u751f\uff0c\u5c31\u7b97\u6709\uff0c\u4e5f\u7d55\u5c0d\u4e0d\u5408\u6cd5\u3002\u674e\u9060\u54f2\u56de\u61b6\u5230\uff0c\u7576\u6642\uff0c\u74e6\u5167\u5229\u5c31\u5e38\u4e0d\u6642\u5230\u5be6\u9a57\u5ba4\u5bdf\u770b\u9032\u5ea6\uff0c\u9084\u534a\u5a01\u8105\u7684\u8aaa\uff1a\u300c\u5982\u679c\u4e8b\u60c5\u4e0d\u6210\uff0c\u4f60\u5011\u5c31\u5f97\u5230\u5ba4\u5916\u5277\u96ea\uff01\u300d<\/p>\n<p><span style=\"color: #008080;\"><strong>\u829d\u5927\u5091\u51fa\u7814\u7a76\u6df1\u7372\u80af\u5b9a<\/strong><\/span><\/p>\n<p>1968\u5e746\u6708\uff0c\u674e\u9060\u54f2\u65bc\u9ad8\u767b\u7814\u8a0e\u6703(Gordon Conference)\u4e0a\u767c\u8868\u4ed6\u5011\u5718\u968a\u5f9e\u300c\u5e0c\u671b\u300d\u6240\u5f97\u5230\u7684\u7814\u7a76\u6210\u679c\uff0c\u8b93\u8207\u6703\u4eba\u58eb\u5370\u8c61\u6975\u70ba\u6df1\u523b\uff0c\u4e0d\u4e45\u4e4b\u5f8c\uff0c\u674e\u9060\u54f2\u61c9\u829d\u52a0\u54e5\u5927\u5b78\u4e4b\u9080\uff0c\u65bc\u7576\u5e74\u5341\u6708\u5230\u5316\u5b78\u7cfb\u4efb\u6559\u3002\u5728\u9019\u5152\uff0c\u674e\u9060\u54f2\u4e5f\u5f88\u5e78\u904b\u5730\u7372\u5f97\u6821\u65b9\u6975\u4f73\u652f\u6301\u53ca\u6709\u6975\u70ba\u512a\u79c0\u5b78\u751f\u6155\u540d\u52a0\u5165\u7814\u7a76\u5718\u968a\uff0c\u5982\u4ed6\u7684\u7b2c\u4e00\u500b\u78a9\u58eb\u7814\u7a76\u751f\u7d04\u7ff0\u02d9\u5e15\u68ee(John Parson)\uff0c\u7b2c\u4e00\u500b\u535a\u58eb\u5f8c\u7814\u7a76\u751fPeter Siska\uff0c\u5169\u4eba\u90fd\u662f\u54c8\u4f5b\u7562\u696d\u3002\u5f88\u5feb\u5730\uff0c\u674e\u9060\u54f2\u7684\u65b0\u5718\u968a\u5c31\u5b8c\u6210\u65b0\u5100\u5668\u7684\u5efa\u7f6e\u53ca\u5be6\u9a57\u9032\u884c\uff0c\u4e26\u958b\u59cb\u767c\u8868\u5ee3\u5ea6\u8207\u6df1\u5ea6\u90fd\u4ee4\u4eba\u6ce8\u76ee\u7684\u51fa\u8272\u7814\u7a76\u6210\u679c\u3002\u9019\u5305\u62ec\u63a1\u7528\u900f\u904e\u5b8c\u6574\u89e3\u6790\u7684\u91cf\u5b50\u5e72\u6d89\u7d50\u69cb\uff0c\u6b63\u78ba\u5730\u63cf\u8ff0\u60f0\u6027\u6c23\u9ad4\u539f\u5b50\u5c0d\u5f48\u6027\u6563\u5c04\u884c\u70ba( definitive studies of the elastic scattering of pairs of noble gas atoms, with fully resolved quantum interference structure)\u3002\u9019\u9805\u6210\u679c\u4f7f\u5f97\u5206\u5b50\u9593\u4f4d\u80fd(intermolecular potentials)\u7684\u6e2c\u5b9a\u80fd\u9054\u5230\u7a7a\u524d\u7684\u7cbe\u6e96\u5ea6\uff0c\u73fe\u5df2\u6210\u70ba\u8a55\u4f30\u5176\u4ed6\u5be6\u9a57\u3001\u7406\u8ad6\u7d50\u679c\u7684\u57fa\u6e96\u3002\u9084\u6709\u5176\u4ed6\u8a31\u591a\u5091\u51fa\u7684\u5be6\u9a57\u53ca\u7814\u7a76\u6210\u679c\uff0c\u5305\u62ec\u9e7c\u91d1\u5c6c\u9e75\u5316\u7269\u7684\u78b0\u649e\u8a98\u767c\u5206\u89e3\u7814\u7a76(collision-induced dissociation of alkali halides)\uff0c\u4e0d\u7a69\u5b9a\u7a00\u6709\u6c23\u9ad4\u539f\u5b50\u7684\u6563\u5c04(scattering of metastable rare gas atoms)\u53ca\u4f7f\u7528\u4ea4\u53c9\u5206\u5b50\u675f\u63a2\u8a0e\u6c1f\u539f\u5b50\u8207\u6c2b\u5206\u5b50\u53ca\u4e0d\u98fd\u548c\u78b3\u6c2b\u5316\u5408\u7269\u9593\u53cd\u61c9\u7684\u9996\u4f8b\u7814\u7a76 (the first crossed beam studies of reaction of fluorine atoms with hydrogen molecules and with unsaturated hydrocarbons)\u7b49\u7b49\u3002\u9019\u4e9b\u7814\u7a76\u6210\u679c\u4e0d\u50c5\u6311\u6230\u4e5f\u5e38\u5c0e\u81f4\u7406\u8ad6\u5206\u6790\u7d50\u8ad6\u7684\u4fee\u6b63\u7684\u4f9d\u64da\u3002<\/p>\n<p><span style=\"color: #008080;\"><strong>\u518d\u56de\u67cf\u514b\u840a\u5927\u653e\u7570\u5f69<\/strong><\/span><\/p>\n<p>1974\u5e74\uff0c\u674e\u9060\u54f2\u56de\u5230\u67cf\u514b\u840a\uff0c\u5728\u5f88\u77ed\u7684\u6642\u9593\u5167\u5c31\u5c07\u7814\u7a76\u9818\u57df\u64f4\u5927\u5230\u8a31\u591a\u65b9\u9762\uff0c\u9019\u5305\u62ec\u96e2\u5b50\u8207\u5206\u5b50\u7c07\u7684\u521d\u59cb\u5149\u5316\u5b78\u7a0b\u5e8f\u7684\u5149\u8b5c\u5b78\u7814\u7a76(primary photochemical processes spectroscopy of ionic and molecular clusters)\u53ca\u8a31\u591a\u4ea4\u53c9\u5206\u5b50\u675f\u53cd\u61c9\u52d5\u529b\u5b78\u7684\u6df1\u5165\u63a2\u8a0e\u3002\u5728\u7576\u6642\uff0c\u674e\u9060\u54f2\u7684\u5be6\u9a57\u5ba4\u53ef\u8aaa\u662f\u5316\u5b78\u7269\u7406\u754c\u540d\u7b26\u5176\u5be6\u7684\u7814\u7a76\u91cd\u93ae\uff0c\u5efa\u7acb\u8a31\u591a\u4ee4\u4eba\u5606\u70ba\u89c0\u6b62\u7684\u65b0\u5be6\u9a57\u65b9\u6cd5\u53ca\u5f71\u97ff\u6df1\u9060\u7684\u5283\u6642\u4ee3\u6027\u65b0\u767c\u73fe\u548c\u97ad\u8f9f\u5165\u88e1\u7684\u89c0\u5ff5\u5efa\u7acb\u3002<\/p>\n<p>\u674e\u9060\u54f2\u958b\u5275\u7684\u79d1\u5b78\u5148\u4f8b\u4e4b\u591a\uff0c\u53ef\u898b\u4ee5\u4e0b\u6982\u8ff0\uff1a(1) <span class='MathJax_Preview'><img src='https:\/\/case.ntu.edu.tw\/blog\/wp-content\/plugins\/latex\/cache\/tex_f2f61470582b42a3b445878d8b4cdfed.gif' style='vertical-align: middle; border: none; padding-bottom:2px;' class='tex' alt=\"\" \/><\/span><script type='math\/tex'><\/script> \u53cd\u61c9\u7684\u5b8c\u6574\u7684\u614b\u8207\u614b\u9593\u7522\u7269\u5206\u4f48\u8207\u52d5\u614b\u5171\u632f\u89e3\u6790(resolution of the complete state-to-state product\u00a0distributions and dynamical resonances in the  <span class='MathJax_Preview'><img src='https:\/\/case.ntu.edu.tw\/blog\/wp-content\/plugins\/latex\/cache\/tex_f2f61470582b42a3b445878d8b4cdfed.gif' style='vertical-align: middle; border: none; padding-bottom:2px;' class='tex' alt=\"\" \/><\/span><script type='math\/tex'><\/script>  reaction) (2) \u81ea\u7531\u57fa\u8207\u4e0d\u98fd\u548c\u78b3\u6c2b\u5316\u5408\u7269\u53cd\u61c9\u521d\u59cb\u6b65\u9a5f\u7684\u78ba\u8a8d(identification of primary steps in reactions of\u00a0radicals with unsaturated hydrocarbons) (3)\u5438\u71b1\u6027\u53d6\u4ee3\u53cd\u61c9\u7684\u52d5\u529b\u5b78\u7814\u7a76( the dynamics of endothermic substitution reactions) (4) \u65bc\u6fc0\u767c\u8ecc\u9053\u6b63\u4f4d\u6642\u96fb\u5b50\u6fc0\u767c\u539f\u5b50\u7684\u5316\u5b78\u53cd\u61c9\u6d3b\u6027\u76f8\u95dc\u6027\u63a2\u8a0e(the dependence of chemical reactivity of electronically excited atoms on the alignment of excited orbitals) (5)\u591a\u539f\u5b50\u5206\u5b50\u9593\u5149\u88c2\u53cd\u61c9\u52d5\u529b\u5b78\u7814\u7a76(dynamics of photofragmentation of many polyatomic molecules)(6) \u5316\u5b78\u6d3b\u5316\u6216\u5c40\u90e8\u6fc0\u767c\u5206\u5b50\u5167\u80fd\u91cf\u50b3\u905e\u7814\u7a76(intramolecular energy transfer in chemically activated or locally excited molecules) (7) \u71c3\u71d2\u7a0b\u5e8f\u4e2d\u5c45\u95dc\u9375\u89d2\u8272\u7684\u81ea\u7531\u57fa\u52d5\u80fd\u5b78\u7814\u7a76(the energetics of free radicals important in combustion processes)(8) \u78b3\u6b63\u96e2\u5b50\u8207\u6c34\u5316\u6c2b\u96e2\u5b50\u7684\u7d05\u5916\u7dda\u5438\u6536\u5149\u8b5c\u7814\u7a76(infrared absorption spectra of carbonium ions and hydrated hydronium ions) (9) \u7279\u5b9a\u96fb\u5b50\u6fc0\u767c\u7684\u9078\u64c7\u6027\u5149\u9375\u89e3\u7814\u7a76(bond-selective photodissociation governed by specific electronic excitation; (10)\u96e2\u5b50\u5316\u5206\u5b50\u7684\u7d50\u5408\u80fd\u7814\u7a76 (binding energies of molecular ions) (11) \u9e75\u5316\u6c2b\u5316\u5408\u7269\u3001\u6c34\u53ca\u6c28\u7684\u9ad8\u7cbe\u5ea6\u8cea\u5b50\u89aa\u5408\u529b\u7814\u7a76(highly accurate proton affinities of hydrogen halides, water, and ammonia) \u53ca(12) \u78b3\u539f\u5b50\u8207\u4e00\u4e9b\u4e0d\u98fd\u548c\u78b3\u6c2b\u5316\u5408\u7269\u9593\u53cd\u61c9\u5206\u6790\u65bc\u4e00\u4e9b\u62f1\u661f\u5305\u5c64\u5f62\u6210\u7684\u91cd\u8981\u6027\u63a2\u6790(analysis of facile reactions of carbon atoms with unsaturated hydrocarbons, developing evidence for the importance of such reactions in some circumstellar envelopes)\u3002\u82e5\u8981\u4e00\u4e00\u7d30\u6578\u9060\u54f2\u6210\u5c31\uff0c\u53ef\u9084\u9700\u66f4\u9577\u7684\u6e05\u55ae\uff0c\u800c\u4e0a\u8ff0\u9019\u4e9b\u6210\u5c31\u5df2\u7d93\u542b\u62ec\u5730\u7403\u3001\u6d77\u6d0b\u3001\u5927\u6c23\u53ca\u5929\u9ad4\u7269\u7406\u5316\u5b78\u4e86\uff01\u5149\u9019\u5341\u4e8c\u9805\u5dee\u4e8b\uff0c\u4fbf\u8db3\u4ee5\u4ee4\u5e0c\u81d8\u795e\u8a71\u4e2d\u7684\u5927\u529b\u58eb\u8d6b\u4e18\u529b\u58eb(Hercules)\u4e5f\u75b2\u65bc\u5954\u547d\u5462\uff01<\/p>\n<p>1994\u5e74\uff0c\u674e\u9060\u54f2\u4ee5\u6559\u6388\u8eab\u5206\uff0c\u5f9e\u67cf\u514b\u840a\u9000\u4f11\uff0c\u96a8\u5f8c\uff0c\u56de\u53f0\u7063\u64d4\u4efb\u4e2d\u7814\u9662\u9662\u9577\u8077\u52d9\uff0c\u4e26\u5949\u737b\u5f88\u591a\u5fc3\u529b\u65bc\u5e6b\u52a9\u6559\u80b2\u6539\u9769\u7684\u63a8\u52d5\u9019\u4ef6\u4e8b\u4e0a\uff0c\u6b64\u671f\u9593\uff0c\u9084\u8eab\u8ca0\u7763\u5c0e22\u500b\u4ee5\u4e0a\u7814\u7a76\u6a5f\u69cb\u7684\u91cd\u8cac\uff0c\u5176\u4e2d\u4e4b\u4e00\u662f\u4e2d\u592e\u7814\u7a76\u9662\u539f\u5b50\u8207\u5206\u5b50\u79d1\u5b78\u7814\u7a76\u6240\u3002\u8a72\u7814\u7a76\u6240\u65bc1983\u5e74\u6210\u7acb\uff0c\u674e\u9060\u54f2\u662f\u6b64\u7814\u7a76\u6240\u7684\u50ac\u751f\u8005\uff0c\u4ed6\u4e5f\u5728\u6b64\u6240\u8a2d\u7acb\u4e86\u81ea\u5df1\u7684\u5be6\u9a57\u5ba4\u3002\u53e6\u5916\uff0c\u4ed6\u4e5f\u7e7c\u7e8c\u5728\u67cf\u514b\u840a\u64d4\u4efb\u7814\u7a76\u751f\u6307\u5c0e\u6559\u6388\uff0c\u7814\u7a76\u5718\u968a\u5011\u4e5f\u59cb\u7d42\u5145\u6eff\u6d3b\u529b\u53ca\u9ad8\u6210\u679c\u7522\u51fa\u3002<\/p>\n<p>\u674e\u9060\u54f2\u5718\u968a\u7684\u51fa\u8272\u7684\u7814\u7a76\u6210\u679c\u5728\u4e00\u7bc7\u8a55\u8ad6\u6587\u7ae0\u4e2d\u6709\u8a73\u7d30\u63cf\u8ff0\uff0c\u5728\u6b64\u6211\u60f3\u8981\u5f37\u8abf\u7684\u662f\u674e\u9060\u54f2\u7684\u5091\u51fa\u500b\u4eba\u7279\u8cea\u9762\u5411\uff0c\u9664\u4e86\u5177\u6709\u975e\u51e1\u80fd\u529b\u8207\u5949\u737b\u7cbe\u795e\u5916\uff0c\u4ed6\u7684\u79d1\u5b78\u76f4\u89ba\u53ca\u7279\u6b8a\u54c1\u5473\uff0c\u8b93\u4ed6\u65bc\u9078\u64c7\u7814\u7a76\u984c\u76ee\u3001\u89e3\u6c7a\u65b9\u5f0f\u53ca\u8a2d\u8a08\u5100\u5668\u6642\uff0c\u4e0d\u50c5\u660e\u667a\u4e14\u7cbe\u6e96\uff0c\u4ed6\u6240\u8a2d\u8a08\u7684\u5be6\u9a57\u5e38\u6703\u5f15\u8d77\u7406\u8ad6\u5316\u5b78\u5bb6\u7684\u8208\u8da3\uff0c\u751a\u81f3\u53ef\u80fd\u7522\u751f\u65b0\u7684\u8a0e\u8ad6\u8b70\u984c\u3002\u7576\u674e\u9060\u54f2\u9078\u5b9a\u4e86\u4e00\u500b\u503c\u5f97\u6df1\u5165\u7814\u7a76\u7684\u984c\u76ee\u6216\u7cfb\u7d71\u5f8c\uff0c\u4e5f\u8a31\u4e00\u958b\u59cb\u770b\u4f3c\u4e0d\u53ef\u80fd\u7684\u4efb\u52d9\uff0c\u4f46\u4ed6\u7684\u7814\u7a76\u5925\u4f34\u5011\u90fd\u77e5\u9053\uff0c\u6700\u5f8c\u7684\u7d50\u679c\u90fd\u662f\u300c\u61c9\u8a72\u6c92\u554f\u984c\u7684\u300d\u3002\u674e\u9060\u54f2\u6703\u5148\u4ed4\u7d30\u5be9\u8996\u7814\u7a76\u4e3b\u984c\u7684\u5404\u76f8\u95dc\u5c64\u9762\u3001\u9810\u6e2c\u53ef\u80fd\u906d\u9047\u5230\u7684\u4e3b\u8981\u56f0\u96e3\u9ede\uff0c\u9032\u800c\u627e\u51fa\u907f\u514d\u6216\u514b\u670d\u7684\u65b9\u6cd5\u3002\u4ed6\u7684\u5316\u5b78\u7cfb\u540c\u50da\u5011\u90fd\u77e5\u9053\u4ed6\u7684\u5be6\u9a57\u6210\u679c\u5e38\u5c0d\u65bc\u5316\u5b78\u7684\u57fa\u790e\u7406\u8ad6\u7684\u4fee\u6b63\u6709\u5de8\u5927\u8ca2\u737b\u3002<\/p>\n<p>\u674e\u9060\u54f2\u773e\u591a\u7684\u512a\u79c0\u5b50\u5f1f\u548c\u5171\u4e8b\u8005\uff0c\u9664\u4e86\u5c0d\u4ed6\u7684\u500b\u4eba\u5929\u8ce6\u8207\u5c0d\u79d1\u5b78\u7684\u57f7\u8457\u6298\u670d\u5916\uff0c\u66f4\u6b3d\u4f69\u4ed6\u7684\u54c1\u5fb7\u8207\u4eba\u683c\u3002\u5728\u6559\u5b78\u8207\u7814\u7a76\u6307\u5c0e\u4e0a\uff0c\u674e\u9060\u54f2\u7e3d\u80fd\u6070\u5982\u5176\u5206\u626e\u597d\u89d2\u8272\uff0c\u80fd\u654f\u92b3\u611f\u53d7\u53ca\u56de\u61c9\u5230\u5b78\u751f\u7684\u9700\u6c42\u3002\u4ed6\u5e7d\u9ed8\u611f\u5341\u8db3\uff0c\u8655\u4e8b\u900f\u660e\u516c\u6b63\uff0c\u96d6\u7136\u8a00\u8a9e\u8209\u6b62\u59cb\u7d42\u6eab\u548c\uff0c\u4f46\u4e00\u8aaa\u8d77\u81ea\u5df1\u7684\u5be6\u9a57\u5ba4\u548c\u5f92\u5b50\u5f92\u5b6b\u5011\u7684\u6210\u5c31\uff0c\u7e3d\u662f\u70af\u70af\u6709\u795e\u3001\u6b23\u559c\uff0c\u5f15\u4ee5\u70ba\u50b2\u7684\u5fc3\u60c5\u6ea2\u65bc\u8a00\u8868\u3002\u53e6\u5916\uff0c\u674e\u9060\u54f2\u7684\u9ad4\u529b\u8207\u8010\u529b\u4e0a\u7684\u7279\u8cea\u8b93\u4ed6\u8db3\u4ee5\u61c9\u4ed8\u6578\u4e0d\u5b8c\u7684\u6709\u95dc\u7814\u7a76\u6210\u679c\u9080\u7d04\u6f14\u8b1b\uff0c\u4e5f\u61c9\u9080\u7576\u5b78\u8853\u671f\u520a\u4e3b\u7de8\u6216\u7576\u8aee\u8a62\u59d4\u54e1\u7b49\u7b49\uff0c\u800c\u4ed6\u7e3d\u80fd\u5f88\u8ca0\u8cac\u5730\u5b8c\u6210\u9019\u4e9b\u4e8b\u3002<\/p>\n<p>\u6211\u9664\u4e86\u80fd\u611f\u540c\u8eab\u53d7\u4ed6\u7684\u5de5\u4f5c\u7684\u6a02\u8da3\u5916\uff0c\u904e\u53bb\u7684\u5e7e\u5e74\uff0c\u6211\u66fe\u6709\u6a5f\u6703\u807d\u904e\u5e7e\u6b21\u674e\u9060\u54f2\u751f\u52d5\u6d3b\u6f51\u7684\u6f14\u8b1b\uff0c\u6211\u7279\u5225\u559c\u6b61\u4ed6\u7528\u68d2\u7403\u6216\u5176\u4ed6\u904b\u52d5\u7684\u6bd4\u8cfd\u904e\u7a0b\u4f86\u8aaa\u660e\u5316\u5b78\u52d5\u529b\u5b78\u5169\u8005\u9593\u7684\u76f8\u4f3c\u6027\u3002\u53e6\u5916\uff0c\u4ed6\u8a31\u591a\u5171\u4e8b\u7684\u540c\u50da\u544a\u8a34\u6211\uff0c\u8ac7\u5230\u4eba\u969b\u95dc\u4fc2\u6642\uff0c\u674e\u9060\u54f2\u6703\u7fd2\u6163\u5730\u7528\u5316\u5b78\u8853\u8a9e\u4f86\u63cf\u8ff0\uff0c\u4f8b\u5982\uff0c\u4ed6\u88ab\u544a\u77e5\u5718\u968a\u7684\u5de5\u4f5c\u540c\u4ec1\u7684\u6fc0\u60c5\u53cd\u61c9\u6642\uff0c\u4ed6\u53ef\u80fd\u5c31\u6703\u8aaa\u300c\u6211\u5e0c\u671b\u9019\u5c31\u5982\u540c\u300e\u653e\u71b1\u53cd\u61c9\u300f\u5427\uff01\u300d\u3002<\/p>\n<p>\u5728\u53f0\u7063\uff0c\u70ba\u6176\u795d\u674e\u9060\u54f260\u6b72\u751f\u65e5\uff0c\u800c\u8209\u8fa6\u7684\u53cd\u61c9\u52d5\u529b\u5b78\u5b78\u8853\u7814\u8a0e\u6703\uff0c\u8207\u767c\u751f\u5728\u65af\u5fb7\u54e5\u723e\u6469\u4ee4\u6211\u5011\u96e3\u5fd8\u7684\u8afe\u8c9d\u723e\u9812\u734e\u5178\u79ae\uff0c\u525b\u597d\u76f8\u969410\u5e74\u3002\u96d6\u7136\uff0c\u8afe\u8c9d\u723e\u734e\u9812\u734e\u5178\u79ae\u7684\u76f8\u95dc\u6176\u795d\u6d3b\u52d5\u7684\u6392\u5834\u70ba\u5927\u5bb6\u6240\u77e5\uff0c\u4f46\u662f\uff0c\u4e00\u4e9b\u5f88\u71b1\u70c8\u8207\u6d3b\u529b\u7684\u7bc0\u76ee\u5247\u4e0d\u7136\u3002\u8209\u4f8b\u4f86\u8aaa\uff0c\u5728\u5c07\u8fd1\u4e00\u661f\u671f\u6d3b\u52d5\u7684\u5f8c\u671f\u6642\uff0c\u5728\u5b78\u751f\u806f\u5408\u6703\u8209\u8fa6\u7684\u6d3e\u5c0d\u88e1\uff0c\u7372\u734e\u8005\u5fd7\u9858\u6216\u534a\u5f37\u8feb\u5730\u8981\u53c3\u52a0\u4e00\u500b\u7a31\u4f5c\u300c\u6c38\u5e36\u5fae\u7b11\u53ca\u8df3\u86d9\u7684\u8056\u5e8f\u6d3b\u52d5\u300d(Sacred Order of the Ever-Smiling and Jumping Frog)\uff0c\u53c3\u52a0\u8005\u9700\u5b78\u86d9\u53eb\u3001\u8df3\u6301\u7e8c\u4e00\u6bb5\u6642\u9593\u3002\u6211\u5011\u4e4b\u9593\uff0c\u7d04\u7ff0\u02d9\u6ce2\u862d\u5c3c(John Polanyi)\u6709\u98a8\u5ea6\u5730\u8df3\u5b8c\uff0c\u6211\u5247\u56e0\u7b28\u62d9\u800c\u5ba3\u544a\u5931\u6557\uff0c\u7136\u800c\uff0c\u674e\u9060\u54f2\u537b\u80fd\u4ee5\u76f8\u7576\u654f\u6377\u8eab\u624b\u5b8c\u6210\u8868\u6f14\u3002\u9019\u4e8b\u8b93\u6211\u60f3\u8acb\u674e\u9060\u54f2\u65bc60 \u5927\u58fd\u6642\uff0c\u80fd\u5426\u6a21\u4eff\u4ed6\u7684\u751f\u8096\u8001\u9f20\u8868\u6f14\uff0c\u4e0d\u50c5\u8981\u6a6b\u885d\u76f4\u649e\u4e82\u8df3\uff0c\u4e5f\u8981\u5431\u5431\u53eb\u500b\u4e0d\u505c\uff0c\u4ee5\u6b61\u8fce\u5c6c\u65bc\u4ed6\u7684\u8096\u9f20\u8005\u65b0\u4e00\u8f2a\u7684\u958b\u59cb\uff0c\u53ef\u60dc\u9019\u4e00\u6b21\u4ed6\u6c92\u7b54\u61c9\u3002<\/p>\n<p>\u58fd\u5bb4\u548c\u8afe\u8c9d\u723e\u9812\u734e\u5178\u79ae\u7684\u6f5b\u5728\u610f\u7fa9\uff0c\u662f\u5c0d\u674e\u9060\u54f2\u5bb6\u65cf\u6c38\u6046\u50f9\u503c\u7684\u80af\u5b9a\u3002\u5728\u9019\u5152\u6240\u8b02\u7684\u5bb6\u65cf\uff0c\u4e0d\u53ea\u662f\u6709\u8840\u7de3\u95dc\u4fc2\u7684\u89aa\u4eba\uff0c\u9084\u5305\u62ec\u79d1\u5b78\u7814\u7a76\u4e0a\u4e0d\u5206\u5e74\u9f61\u4e16\u4ee3\u8207\u5730\u5340\u7684\u5fd7\u540c\u9053\u5408\u5925\u4f34\u5011\u3002\u674e\u9060\u54f2\u548c\u4ed6\u7684\u592a\u592a\u2014\u5433\u9326\u9e97\uff0c\u5728\u570b\u5c0f\u5538\u66f8\u6642\u8a8d\u8b58\uff0c\u6709\u4e09\u500b\u5b50\u5973---Ted\u3001Sidney 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Sklodowsky \u5973\u5b69\u6240\u5beb\uff0c\u9019\u4f4d\u66fe\u4f4f\u5728\u5df4\u9ece\u516d\u5c64\u6a13\u516c\u5bd3\u4e2d\u5c0f\u5c4b\u4e2d\u7684\u4e00\u500b\u8a8d\u771f\u7684\u5e74\u8f15\u5b78\u751f\uff0c\u800c\u5f8c\u6539\u540dMarie Curie \u800c\u70ba\u5927\u5bb6\u6240\u77e5\uff0c\u8a69\u4f5c\u5982\u4e0b\uff1a<\/p>\n<p>\u662f\u4eab\u53d7\u77e5\u8b58\u7684\u559c\u6085<br \/>\n\u662f\u56e0\u767c\u73fe\u7a84\u5ba4\u7684\u7368\u8655\u53ef\u5f97\u5230\u5fc3\u9748\u6eff\u6eff\u6210\u9577<br \/>\n\u662f\u8a31\u591a\u654f\u92b3\u7684\u601d\u7dad\u9f13\u821e\u8457<br \/>\n\u8b93\u7406\u60f3\u6eff\u6ea2\u8457\u9019\u5c0f\u5ba4<br \/>\n\u9019\u4e9b\u90fd\u652f\u6490\u8457\u5979\u4f86\u5230\u6b64\u7570\u9109<br \/>\n\u4e5f\u6566\u4fc3\u8457\u5979\u53bb\u8ffd\u6c42\u771f\u7406<br \/>\n\u800c\u8fd1\u5728\u54ab\u5c3a\u7684\u4eae\u5149<br \/>\n\u662f\u5979\u4e00\u751f\u6240\u8ffd\u5c0b\u771f\u7406\u4e4b\u5149<br \/>\n\u5979\u66f4\u52a0\u52e4\u52f5\u5b78\u7fd2<br \/>\n\u8a8d\u70ba\u5979\u7684\u4e16\u754c\u53ea\u6709\u66f4\u591a\u5b78\u7fd2<br \/>\n\u624d\u80fd\u9054\u6210\u9019\u547d\u4e2d\u6ce8\u5b9a\u4e4b\u4e8b<\/p>\n<p>\u737b\u4e0a\u746a\u8389\uff0e\u5c45\u79ae\u7684\u9019\u9996\u8a69\u4e5f\u662f\u5c0d\u674e\u9060\u54f2\u7684\u81f4\u656c\uff0c\u56e0\u5979\u7684\u6545\u4e8b\u555f\u767c\u534a\u4e16\u7d00\u5f8c\u7684\u4ed6\u52aa\u529b\u8ffd\u6c42\u5b8c\u6210\u4ed6\u79d1\u5b78\u4e0a\u4f7f\u547d\u3002<\/p>\n<p><strong>\u00a0<\/strong><\/p>\n<p><strong>\u53c3\u8003\u8cc7\u6599<\/strong><\/p>\n<p>(1) Lee, Y. T. Les Prix Nobel en 1986; Nobel Foundation: Stockholm, 1987; pp<\/p>\n<p>166-206.<\/p>\n<p>(2) This paper is mostly based on recent conversations with Yuan and on my speech at the Y. T. Lee Banquet held on December 10, 1996, in the Grand Formosa Regent Hotel in Taipei. The scene included a giant ice sculpture featuring the number 60, an orchestra playing traditional instruments, and 350 guests who had enjoyed an 18-course dinner. Also worthy of mention was a timely front-page photo in the day\u2019s newspaper; the accompanying story described an argument between two taxicab drivers that culminated in a dramatic head-on collision between their vehicles.<\/p>\n<p>(3) At the Y. T. Lee Banquet, I gave Yuan two birthday presents: a softball (made in China) autographed by more than 100 colleagues, and a copy of the new biography by Susan Quinn, Marie Curie; Addison-Wesley: New York, 1995.<\/p>\n<p>(4) References to the research literature are omitted; they may be readily found from the complete listing of Lee group papers included in this issue.<\/p>\n<p>(5) The poem, originally in Polish, was versified in English by Jan Schreiber; it is reprinted with permission of Simon &amp; Schuster from Quinn, S. Marie Curie, A Life; Addison-Wesley: New York, 1995; p 92. 6344 J. Phys. Chem. A, Vol. 101, No. 36, 1997<\/p>\n<p>&nbsp;<\/p>\n<p><a href=\"https:\/\/line.me\/R\/ti\/p\/%40fcx6182w\" target=\"_blank\" rel=\"noopener noreferrer\"><img decoding=\"async\" class=\"alignnone\" src=\"https:\/\/scdn.line-apps.com\/n\/line_add_friends\/btn\/zh-Hant.png\" alt=\"\u52a0\u5165\u597d\u53cb\" width=\"212\" height=\"36\" border=\"0\"><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u539f\u6587\u4f5c\u8005\uff5cDudley Herschba<\/p>\n","protected":false},"author":20,"featured_media":25754,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[32,3293,1042],"tags":[2854,695,2853,2148],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2016\/10\/Q5.jpg","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/25753"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=25753"}],"version-history":[{"count":6,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/25753\/revisions"}],"predecessor-version":[{"id":32667,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/25753\/revisions\/32667"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/25754"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=25753"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=25753"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=25753"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}