{"id":25746,"date":"2016-10-11T13:23:36","date_gmt":"2016-10-11T05:23:36","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=25746"},"modified":"2018-08-03T15:17:40","modified_gmt":"2018-08-03T07:17:40","slug":"%e3%80%90%e6%9d%8e%e9%81%a0%e5%93%b2%e7%8d%b2%e9%a0%92%e8%ab%be%e8%b2%9d%e7%88%be%e5%8c%96%e5%ad%b8%e7%8d%8e30%e9%80%b1%e5%b9%b4%e3%80%911986%e5%b9%b4%e5%8c%96%e5%ad%b8%e7%8d%8e%e5%ae%98%e6%96%b9","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=25746","title":{"rendered":"\u3010\u674e\u9060\u54f2\u7372\u9812\u8afe\u8c9d\u723e\u5316\u5b78\u734e30\u9031\u5e74\u30111986\u5e74\u5316\u5b78\u734e\u5b98\u65b9\u65b0\u805e\u7a3f"},"content":{"rendered":"
\"q8\"
\u5716\u7247\u51fa\u81ea\u8afe\u8c9d\u723e\u5b98\u7db2<\/figcaption><\/figure>\n

\u64b0\u6587\uff5c<\/strong>\u4e2d\u592e\u7814\u7a76\u9662\u539f\u5b50\u8207\u5206\u5b50\u79d1\u5b78\u7814\u7a76\u6240\u7814\u7a76\u54e1\u66a8\u53f0\u5927\u5316\u5b78\u7cfb\u5408\u8058\u6559\u6388 \u6797\u5fd7\u6c11<\/p>\n

\u70ba\u4e86\u8868\u5f70\u4ed6\u5011\u5728\u5316\u5b78\u57fa\u672c\u904e\u7a0b\u7684\u52d5\u614b\u7814\u7a76\u4e0a\u7684\u8ca2\u737b\uff0c\u745e\u5178\u7687\u5bb6\u79d1\u5b78\u9662\u5df2\u6c7a\u5b9a\u5c071986\u5e74\u8afe\u8c9d\u723e\u5316\u5b78\u734e\u6388\u4e88<\/p>\n

Professor Dudley R. Herschbach, Harvard University, Cambridge, USA,Professor Yuan T. Lee, University of California, Berkeley, USA and\u00a0Professor John C. Polanyi, University of Toronto, Toronto, Canada<\/p>\n

\u7e3d\u7d50<\/strong><\/span><\/p>\n

\u70ba\u4e86\u8868\u5f70\u4ed6\u5011\u5728\u5316\u5b78\u57fa\u672c\u904e\u7a0b\u7684\u52d5\u614b\u7814\u7a76\u4e0a\u7684\u8ca2\u737b\uff0c\u4eca\u5e74\u7684\u8afe\u8c9d\u723e\u5316\u5b78\u734e\u7531Herschbach\u3001\u674e\u9060\u54f2\u548cPolanyi\u4e09\u4eba\u5171\u4eab\u3002\u5316\u5b78\u53cd\u61c9\u52d5\u614b\u5b78\u662f\u5316\u5b78\u7814\u7a76\u7684\u4e00\u500b\u65b0\u9818\u57df\uff0c\u4ed6\u5011\u7684\u7814\u7a76\u5c0d\u6b64\u9818\u57df\u7684\u767c\u5c55\u5341\u5206\u91cd\u8981\uff0c\u5c0d\u65bc\u5316\u5b78\u53cd\u61c9\u662f\u5982\u4f55\u767c\u751f\u7684\u63d0\u4f9b\u4e86\u66f4\u70ba\u8a73\u7d30\u7684\u7406\u89e3\u3002<\/p>\n

Herschbach \u767c\u5c55\u4ea4\u53c9\u5206\u5b50\u675f\u65b9\u6cd5\uff0c\u4f7f\u5316\u5b78\u53cd\u61c9\u7684\u8a73\u7d30\u7814\u7a76\u6210\u70ba\u53ef\u80fd\uff0c\u4e26\u95e1\u660e\u4e86\u57fa\u672c\u53cd\u61c9\u7684\u52d5\u614b\u5b78\u3002\u674e\u9060\u54f2\u8d77\u521d\u8207Herschbach \u5408\u4f5c\uff0c\u958b\u767c\u4ea4\u53c9\u5206\u5b50\u675f\u65b9\u6cd5\uff0c\u5f8c\u4f86\u674e\u9060\u54f2\u5c07\u5176\u9032\u4e00\u6b65\u61c9\u7528\u65bc\u66f4\u666e\u904d\u7684\u53cd\u61c9\u4e0a\u3002\u503c\u5f97\u4e00\u63d0\u7684\u662f\uff0c\u4ed6\u5c07\u9019\u7a2e\u65b9\u6cd5\u61c9\u7528\u65bc\u7814\u7a76\u8f03\u5927\u5206\u5b50\u7684\u91cd\u8981\u53cd\u61c9\u3002Polanyi \u958b\u767c\u4e86\u7d05\u5916\u6ce2\u6bb5\u7684\u5316\u5b78\u767c\u5149\u65b9\u6cd5\uff0c\u85c9\u7531\u6e2c\u91cf\u8207\u5206\u6790\u5f9e\u4e00\u500b\u65b0\u5f62\u6210\u7684\u5206\u5b50\u6240\u767c\u51fa\u7684\u6975\u5f31\u7d05\u5916\u5149\uff0c\u95e1\u660e\u5316\u5b78\u53cd\u61c9\u4e2d\u8a73\u7d30\u7684\u80fd\u91cf\u5206\u5e03\u3002<\/p>\n

\u80cc\u666f<\/strong><\/span><\/p>\n

\u7269\u8cea\u4e2d\u7684\u539f\u5b50\u548c\u5206\u5b50\u90fd\u4e0d\u66fe\u771f\u6b63\u975c\u6b62\uff0c\u5728\u6c23\u9ad4\u6216\u6db2\u9ad4\u4e2d\uff0c\u5206\u5b50\u9593\u7684\u78b0\u649e\u4e0d\u65b7\u5730\u767c\u751f\u3002\u7576\u5206\u5b50\u5f7c\u6b64\u9760\u5f97\u8db3\u5920\u8fd1\u6642\uff0c\u539f\u5b50\u53ef\u80fd\u5728\u5206\u5b50\u9593\u6216\u5206\u5b50\u5167\u767c\u751f\u91cd\u65b0\u6392\u5217\uff0c\u5f62\u6210\u6240\u8b02\u7684\u7522\u7269\u5206\u5b50\uff0c\u4ee3\u8868\u5316\u5b78\u53cd\u61c9\u7684\u767c\u751f\u3002\u8981\u8b93\u4e00\u500b\u5316\u5b78\u53cd\u61c9\u767c\u751f\uff0c\u78b0\u649e\u7684\u5206\u5b50\u5f80\u5f80\u8981\u6709\u4e00\u4e9b\u7279\u6b8a\u7684\u6027\u8cea\uff0c\u5982\u9ad8\u901f\u6216\u5177\u6709\u5927\u91cf\u7684\u5167\u80fd\u3002<\/p>\n

\u95dc\u65bc\u5316\u5b78\u53cd\u61c9\u5982\u4f55\u767c\u751f\u3001\u5176\u53cd\u61c9\u901f\u7387\u5982\u4f55\u6e2c\u91cf\u7684\u50b3\u7d71\u63cf\u8ff0\uff0c\u5c6c\u65bc\u5316\u5b78\u53cd\u61c9\u52d5\u529b\u5b78\u7684\u9818\u57df\u3002\u904e\u53bb\u7684\u5e7e\u5341\u5e74\u4e2d\uff0c\u9019\u500b\u9818\u57df\u767c\u5c55\u8fc5\u901f\uff0c\u53c8\u4ee5\u5176\u5be6\u9a57\u65b9\u6cd5\u70ba\u751a\u30021967\u5e74\u8afe\u8c9d\u723e\u5316\u5b78\u734e\u7531\u5fb7\u570b\u7684Eigen\u3001\u82f1\u570b\u7684Norrish\u548cPorter\u5171\u540c\u7372\u5f97\uff0c\u70ba\u4e86\u8868\u5f70\u4ed6\u5011\u5728\u6975\u70ba\u5feb\u901f\u4e4b\u5316\u5b78\u53cd\u61c9\u4e0a\u7684\u7814\u7a76\u3002\u7136\u800c\uff0c\u5728\u8a31\u591a\u65b9\u9762\uff0c\u4ec0\u9ebc\u5206\u5b50\u7279\u5fb5\u6703\u5f71\u97ff\u5316\u5b78\u53cd\u61c9\u901f\u7387\u7684\u57fa\u672c\u7406\u89e3\uff0c\u537b\u53ea\u6709\u7de9\u6162\u7684\u9032\u5c55\u3002<\/p>\n

\u5728\u6c23\u9ad4\u6216\u6db2\u9ad4\u4e2d\uff0c\u5206\u5b50\u904b\u52d5\u7684\u901f\u5ea6\u548c\u65b9\u5411\u4e3b\u8981\u662f\u96a8\u6a5f\u7684\u3002\u56e0\u6b64\uff0c\u5206\u5b50\u4e4b\u9593\u7684\u78b0\u649e\u53ca\u80fd\u91cf\u662f\u4e0d\u660e\u78ba\u7684\uff1b\u8a72\u5206\u5b50\u9593\u53cd\u61c9\u7684\u7d30\u7bc0\u56e0\u800c\u8b8a\u5f97\u6a21\u7cca\uff0c\u4e0d\u80fd\u9032\u884c\u8db3\u5920\u7cbe\u78ba\u7684\u89c0\u6e2c\u3002\u5728\u5206\u5b50\u675f\u7684\u767c\u5c55\u4e4b\u524d\uff0c\u9019\u500b\u554f\u984c\u4e26\u6c92\u6709\u5f97\u5230\u4ee4\u4eba\u6eff\u610f\u7684\u89e3\u6c7a\u3002<\/p>\n

\u7d42\u65bc\uff0c\u901a\u904e\u4f7f\u7528\u5206\u5b50\u675f(\u4f4e\u5bc6\u5ea6\u7684\u5206\u5b50\u5c04\u7dda\uff0c\u5177\u660e\u78ba\u5b9a\u7fa9\u7684\u65b9\u5411\uff0c\u5f80\u5f80\u9084\u5177\u6709\u826f\u597d\u9650\u5b9a\u7684\u901f\u5ea6)\u9019\u500b\u554f\u984c\u5f97\u4ee5\u89e3\u6c7a\u3002\u7576\u5169\u500b\u5206\u5b50\u675f\u76f8\u4e92\u4ea4\u53c9\uff0c\u5206\u5b50\u4e4b\u9593\u53cd\u61c9\u7684\u7d30\u7bc0\u5f97\u4ee5\u7814\u7a76\u3002\u4ea4\u53c9\u5206\u5b50\u675f\u6280\u8853\u662f\u53cd\u61c9\u52d5\u614b\u5b78\u9818\u57df\u4e2d\uff0c\u6700\u91cd\u8981\u7684\u9032\u5c55\u4e4b\u4e00\u3002<\/p>\n

Herschbach \u5728\u8349\u5275\u671f\u5c31\u53c3\u8207\u4e86\u9019\u7a2e\u6280\u8853\u7684\u767c\u5c55\u3002\u4ed6\u6975\u91cd\u8981\u7684\u6210\u5c31\uff0c\u662f\u95dc\u65bc\u77ed\u58fd\u547d\u7684\u76f4\u63a5\u53cd\u61c9\u7684\u5be6\u4f8b\u7814\u7a76\uff0c\u7279\u5225\u662f\u5c0d\u65bc\u201c\u53cd\u5f48\u201d\u548c\u201c\u812b\u53bb\u201d\u9019\u5169\u7a2e\u985e\u578b\u7684\u53cd\u61c9\u3002\u4ed6\u6539\u826f\u4e86\u4e00\u822c\u6240\u7528\u7684\u5075\u6e2c\u65b9\u6cd5\uff0c\u514b\u670d\u4e86\u65e9\u671f\u5be6\u9a57\u4e2d\u7684\u4e00\u4e9b\u554f\u984c\u3002\u518d\u8005\uff0c\u5728\u4ea4\u53c9\u5206\u5b50\u675f\u5be6\u9a57\u4e2d\u767c\u73fe\u7684\u9577\u58fd\u547d\u53cd\u61c9\u8907\u5408\u7269\uff0c\u5176\u5f62\u6210\u8207\u8870\u8b8a\uff0c\u4e0d\u4e45\u4e4b\u5f8c\u4e5f\u53ef\u7528\u7406\u8ad6\u4f86\u63cf\u8ff0\u3002\u5728\u9019\u4e9b\u53cd\u61c9\u4e2d\uff0c\u9996\u6b21\u89c0\u5bdf\u5230\u89d2\u52d5\u91cf\u7684\u91cd\u8981\u6027\u3002\u96a8\u5f8c\uff0c\u674e\u9060\u54f2\u548c\u4ed6\u4eba\u7684\u7814\u7a76\uff0c\u90fd\u6e05\u695a\u5730\u986f\u793a\uff0c\u9019\u7a2e\u985e\u578b\u7684\u9577\u58fd\u547d\u53cd\u61c9\u5177\u6709\u666e\u904d\u7684\u91cd\u8981\u6027\u3002<\/p>\n

\u5728\u4ea4\u53c9\u5206\u5b50\u675f\u9818\u57df\u767c\u5c55\u7684\u7b2c\u4e00\u968e\u6bb5\uff0c\u53d7\u9650\u65bc\u7576\u6642\u7684\u5075\u6e2c\u65b9\u6cd5\uff0c\u53ea\u80fd\u7814\u7a76\u9e7c\u91d1\u5c6c\u539f\u5b50\u548c\u5176\u5b83\u5206\u5b50\u4e4b\u9593\u7684\u53cd\u61c9\u3002\u5e7e\u500b\u7814\u7a76\u5718\u968a\u958b\u767c\u4e86\u4ea4\u53c9\u5206\u5b50\u675f\u5100\u5668\uff0c\u4ee5\u7814\u7a76\u66f4\u666e\u904d\u7684\u53cd\u61c9\u3002\u5176\u4e2d\u6700\u7cbe\u5de7\u8907\u96dc\u7684\u5100\u5668\uff0c\u662f\u7531\u674e\u9060\u54f2\u9996\u5148\u5728Herschbach\u5be6\u9a57\u5ba4\u6240\u958b\u767c\u7684\u3002\u9019\u500b\u6240\u8b02\u7684\u300c\u8d85\u7d1a\u6a5f\u5668\u300d\u4f7f\u7528\u5169\u9053\u660e\u78ba\u5b9a\u7fa9\u7684\u4ea4\u53c9\u5206\u5b50\u675f\u548c\u4e00\u500b\u53ef\u79fb\u52d5\u7684\u8cea\u8b5c\u5075\u6e2c\u5668\uff0c\u5075\u6e2c\u5668\u88dd\u6709\u96fb\u5b50\u8f5f\u64ca\u96fb\u96e2\u548c\u6578\u6bb5\u7684\u5dee\u52d5\u62bd\u6c23\u3002<\/p>\n

\u674e\u9060\u54f2\u3001Herschbach\u4ee5\u53ca\u5176\u4ed6\u7814\u7a76\u4eba\u54e1\uff0c\u5df2\u7d93\u4f7f\u7528\u9019\u7a2e\u985e\u578b\u7684\u5206\u5b50\u675f\u88dd\u7f6e\u5c0d\u5927\u91cf\u7684\u5316\u5b78\u53cd\u61c9\u9032\u884c\u4e86\u8a73\u7d30\u7684\u7814\u7a76\u3002\u674e\u9060\u54f2\u900f\u904e\u7814\u7a76\u6709\u6a5f\u5206\u5b50\u548c\u6c1f\u6216\u6c27\u539f\u5b50\u4e4b\u9593\u7684\u53cd\u61c9\uff0c\u671d\u5411\u5316\u5b78\u4e2d\u91cd\u8981\u53cd\u61c9\u7cfb\u7d71\u7684\u958b\u767c\u3002\u5728\u9019\u6a23\u7684\u8f03\u5927\u5206\u5b50\u7cfb\u7d71\u4e2d\uff0c\u7121\u8ad6\u77ed\u58fd\u547d\u76f4\u63a5\u53cd\u61c9\u6216\u662f\u9577\u58fd\u547d\u7684\u53cd\u61c9\u90fd\u88ab\u89c0\u5bdf\u5230\u3002\u9019\u8b49\u5be6\u4e86\uff0c\u542b\u9e7c\u91d1\u5c6c\u539f\u5b50\u53cd\u61c9\u9ad4\u7cfb\u7684\u65e9\u671f\u7814\u7a76\u7d50\u679c\uff0c\u5177\u666e\u904d\u7684\u6709\u6548\u6027\u3002\u8fd1\u5e74\u4f86\uff0c\u674e\u9060\u54f2\u4e5f\u7814\u7a76\u4e86\u5c0d\u71c3\u71d2\u5316\u5b78\u548c\u5927\u6c23\u5316\u5b78\u5177\u7acb\u5373\u610f\u7fa9\u7684\u91cd\u8981\u53cd\u61c9\u3002<\/p>\n

Polanyi\u958b\u767c\u4e86\u53e6\u4e00\u500b\u53ef\u8a73\u7d30\u7814\u7a76\u5316\u5b78\u53cd\u61c9\u7684\u91cd\u8981\u65b9\u6cd5 \u2014 \u7d05\u5916\u7dda\u5316\u5b78\u767c\u5149\u6cd5\u3002\u9019\u500b\u767c\u5c55\u8207\u4ea4\u53c9\u5206\u5b50\u675f\u7684\u9818\u57df\u540c\u6642\u5f62\u6210\u3002\u9019\u7a2e\u4e92\u88dc\u7684\u65b9\u6cd5\uff0c\u5728\u8a31\u591a\u65b9\u9762\uff0c\u985e\u4f3c\u65bc\u4ea4\u53c9\u5206\u5b50\u675f\u6cd5\uff0c\u4f46\u6d89\u53ca\u5f9e\u67d0\u4e9b\u5316\u5b78\u53cd\u61c9\u7684\u7522\u7269\u5206\u5b50\uff0c\u6e2c\u91cf\u548c\u5206\u6790\u6975\u5f31\u7684\u7d05\u5916\u7dda\u767c\u5149\u3002\u5316\u5b78\u53cd\u61c9\u904e\u5269\u7684\u80fd\u91cf\uff0c\u53ef\u5132\u5b58\u65bc\u7522\u7269\u5206\u5b50\u7684\u5167\u80fd\uff0c\u7d93\u904e\u4e00\u4e9b\u6642\u9593\u5f8c\uff0c\u9019\u4e9b\u80fd\u91cf\u53ef\u7528\u7d05\u5916\u5149\u7684\u5f62\u5f0f\u767c\u5c04\u51fa\u4f86\u3002\u900f\u904e\u5206\u6790\u9019\u7a2e\u7d05\u5916\u5149\u7684\u5149\u8b5c\uff0c\u53ef\u76f4\u63a5\u986f\u793a\u8a72\u7522\u7269\u5206\u5b50\u7684\u91cf\u5b50\u72c0\u614b\u3002\u9019\u9593\u63a5\u5730\u7d66\u51fa\u975e\u5e38\u91cd\u8981\u7684\u8cc7\u8a0a\uff0c\u662f\u95dc\u65bc\u63cf\u8ff0\u7cfb\u7d71\u4e2d(\u4f5c\u7528\u529b)\u4f4d\u80fd\u7684\u591a\u7dad\u8868\u9762\u3002\u5728\u5927\u591a\u6578\u60c5\u6cc1\u4e0b\uff0c\u4f4d\u80fd\u9762\u662f\u672a\u77e5\u7684\uff0c\u4f46\u5b83\u6839\u672c\u5730\u6c7a\u5b9a\u4e86\u5316\u5b78\u53cd\u61c9\u7684\u8a73\u7d30\u884c\u70ba\u3002<\/p>\n

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--
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 <\/p>\n

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