{"id":21142,"date":"2015-04-24T00:30:11","date_gmt":"2015-04-23T16:30:11","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=21142"},"modified":"2018-08-01T15:36:00","modified_gmt":"2018-08-01T07:36:00","slug":"%e3%80%90%e6%b8%9b%e7%a2%b3%e5%a4%a7%e4%bd%9c%e6%88%b0%e3%80%91%e6%b8%9b%e4%bd%8e%e4%ba%8c%e6%b0%a7%e5%8c%96%e7%a2%b3%e5%8d%bb%e6%b6%88%e8%80%97%e6%9b%b4%e5%a4%9a%e8%83%bd%e9%87%8f%ef%bc%9f%e9%80%99","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=21142","title":{"rendered":"\u3010\u6e1b\u78b3\u5927\u4f5c\u6230\u3011\u6e1b\u4f4e\u4e8c\u6c27\u5316\u78b3\u537b\u6d88\u8017\u66f4\u591a\u80fd\u91cf\uff1f\u9019\u4e0d\u5408\u7406\u554a\uff01"},"content":{"rendered":"<p><span style=\"color: #333399;\"><strong>\u25a0\u74b0\u4fdd\u610f\u8b58\u9ad8\u6f32\uff0c\u6709\u6c92\u6709\u66f4\u7bc0\u80fd\u7684\u65b9\u6cd5\u6355\u6349\u4e8c\u6c27\u5316\u78b3\u4e26\u5c07\u5176\u5c01\u5b58\u5462\uff1f<\/strong><\/span><\/p>\n<figure id=\"attachment_21143\" aria-describedby=\"caption-attachment-21143\" style=\"width: 380px\" class=\"wp-caption alignleft\"><img fetchpriority=\"high\" decoding=\"async\" class=\"wp-image-21143\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2015\/03\/153113.jpg\" alt=\"\u5716\u7247\u4f86\u6e90\uff1ahttp:\/\/ppt.cc\/XxBS\" width=\"380\" height=\"278\" srcset=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2015\/03\/153113.jpg 361w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2015\/03\/153113-300x219.jpg 300w\" sizes=\"(max-width: 380px) 100vw, 380px\" \/><figcaption id=\"caption-attachment-21143\" class=\"wp-caption-text\">\u5716\u7247\u4f86\u6e90\uff1ahttp:\/\/ppt.cc\/XxBS<\/figcaption><\/figure>\n<p><strong>\u64b0\u6587\uff5c<\/strong>\u65b9\u7a0b\u6bc5<\/p>\n<p>\u4eba\u985e\u6587\u660e\u7684\u9032\u6b65\u4f34\u96a8\u5927\u91cf\u4e8c\u6c27\u5316\u78b3\u6392\u653e\u4e26\u5c0e\u81f4\u6eab\u5ba4\u6548\u61c9\u60e1\u5316\uff0c\u9019\u61c9\u8a72\u662f\u5927\u5bb6\u518d\u719f\u6089\u4e0d\u904e\u7684\u6545\u4e8b\u4e86\u3002\u806f\u5408\u570b\u6c23\u5019\u8b8a\u5316\u6846\u67b6\u516c\u7d04\u3001\u4eac\u90fd\u8b70\u5b9a\u66f8\u6216\u78b3\u4ea4\u6613\u7b49\u7b49\u7684\u51fa\u73fe\u90fd\u662f\u70ba\u4e86\u89e3\u6c7a\u9019\u9805\u5927\u96e3\u984c\uff0c\u5118\u7ba1\u653f\u6cbb\u4e0a\u7d1b\u7d1b\u64fe\u64fe\u722d\u8ad6\u4e0d\u4f11\uff0c\u81f3\u4eca\u90fd\u7121\u6cd5\u51dd\u805a\u5404\u570b\u5171\u8b58\uff0c\u4f46\u662f\u79d1\u5b78\u4e0a\u91dd\u5c0d\u5982\u4f55\u6e1b\u4f4e\u78b3\u6392\u653e\u91cf\u7684\u7814\u7a76\u537b\u662f\u4e0d\u66fe\u505c\u6b47\u3002\u96d6\u7136\u5927\u5bb6\u90fd\u77e5\u9053\u8981\u6e1b\u78b3\uff0c\u4f46\u8b93\u4e8c\u6c27\u5316\u78b3\u6392\u653e\u91cf\u6e1b\u5c11\uff0c\u53ef\u4e0d\u662f\u8aaa\u8aaa\u5c31\u80fd\u505a\u5230\uff0c\u767c\u96fb\u5ee0\u6216\u5de5\u5ee0\u4e5f\u4e0d\u662f\u8aaa\u6e1b\u6392\u5c31\u80fd\u6e1b\u6392\uff0c\u56e0\u6b64\u5982\u679c\u6211\u5011\u80fd\u628a\u5de5\u5ee0\u6216\u767c\u96fb\u5ee0\u7522\u751f\u7684\u4e8c\u6c27\u5316\u78b3\u5c01\u5b58\u8d77\u4f86\uff0c\u4e0d\u8b93\u4ed6\u5011\u6392\u5230\u7a7a\u6c23\u4e2d\uff0c\u4e5f\u4e0d\u5931\u70ba\u4e00\u500b\u597d\u8fa6\u6cd5\uff0c\u65e2\u4e0d\u6703\u56e0\u70ba\u6e1b\u6392\u8b93\u5de5\u5ee0\u6216\u767c\u96fb\u5ee0\u7684\u6548\u80fd\u964d\u4f4e\uff0c\u53c8\u80fd\u9632\u6b62\u4e8c\u6c27\u5316\u78b3\u5728\u7a7a\u6c23\u4e2d\u7684\u6fc3\u5ea6\u7e7c\u7e8c\u589e\u9ad8\u3002<!--more--><\/p>\n<p>\u78b3\u6536\u96c6\u53ca\u5132\u5b58(Carbon capture and storage\uff0c\u53c8\u8b6f\u70ba\u78b3\u5c01\u5b58)\u5c31\u662f\u9019\u6a23\u7684\u89c0\u5ff5\uff0c\u5c07\u4e8c\u6c27\u5316\u78b3\u672c\u8eab\u6216\u662f\u5c07\u5176\u8f49\u6210\u78b3\u9178\u9e7d\u985e\u7684\u5f62\u5f0f\u5c01\u5b58\u5728\u6d77\u6d0b\u6216\u5730\u4e0b\u5ca9\u5c64\u4e2d\uff0c\u4ee5\u907f\u514d\u9032\u5165\u5927\u6c23\u5c64\u3002\u4f46\u662f\u9019\u7a2e\u65b9\u6cd5\u6709\u8a31\u591a\u96e3\u4ee5\u514b\u670d\u7684\u969c\u7919\uff0c\u9664\u4e86\u8981\u9078\u64c7\u9069\u7576\u7684\u5132\u5b58\u5730\u9ede\u4e4b\u5916\uff0c\u53e6\u4e00\u5927\u96e3\u984c\u5c31\u662f\u5982\u4f55\u628a\u9019\u4e9b\u4e8c\u6c27\u5316\u78b3\u300c\u6355\u6349\u300d\u8d77\u4f86\u4e26\u904b\u9001\u5230\u5176\u4ed6\u5730\u65b9\u3002\u6349\u4e8c\u6c27\u5316\u78b3\u53ef\u4e0d\u50cf\u8c93\u6349\u8001\u9f20\u4e00\u6a23\u7c21\u55ae\uff0c\u88dc\u6349\u4e8c\u6c27\u5316\u78b3\u5fc5\u9808\u8981\u8b93\u4e8c\u6c27\u5316\u78b3\u5206\u5b50\u80fd\u5920\u5438\u9644(adsorb)\u5728\u67d0\u7a2e\u5206\u5b50\u4e0a\uff0c\u7d93\u904e\u904b\u9001\uff0c\u518d\u812b\u9644(desorb)\u5230\u76ee\u7684\u5730\u6216\u9032\u884c\u4e0b\u4e00\u968e\u6bb5\u7684\u8655\u7406\uff0c\u56e0\u6b64\u4e0d\u50c5\u5438\u9644\u662f\u500b\u554f\u984c\uff0c\u812b\u9644\u4e5f\u662f\u500b\u554f\u984c\u3002<\/p>\n<p>\u53ef\u60f3\u800c\u77e5\uff0c\u5bb9\u6613\u5438\u9644\u4e8c\u6c27\u5316\u78b3\u7684\u5206\u5b50\u4e00\u5b9a\u4e0d\u5bb9\u6613\u812b\u9644\u4e8c\u6c27\u5316\u78b3\u3002\u76ee\u524d\u7814\u7a76\u4e0a\u4e3b\u8981\u7528\u4f86\u5438\u812b\u9644\u4e8c\u6c27\u5316\u78b3\u7684\u5206\u5b50\u70ba\u80fa\u985e(Amine)\u6709\u6a5f\u7269\u3002\u4ee5\u80fa\u985e\u70ba\u4e3b\u7684\u5438\u812b\u9644\u6a5f\u5236\u662f\u4f4e\u6eab\u5438\u9644\u3001\u9ad8\u6eab\u812b\u9644\uff0c\u4e5f\u5c31\u662f\u8aaa\u5728\u812b\u9644\u4e8c\u6c27\u5316\u78b3\u7684\u904e\u7a0b\u4e2d\u5fc5\u9808\u52a0\u71b1\uff0c\u901a\u5e38\u8981\u5230120-150\u00b0C\uff0c\u4f46\u662f\u52a0\u71b1\u5c31\u9700\u8981\u80fd\u91cf\uff0c\u70ba\u4e86\u74b0\u4fdd\uff0c\u5c01\u5b58\u4e8c\u6c27\u5316\u78b3\u537b\u9700\u8981\u7528\u6389\u66f4\u591a\u80fd\u91cf\uff0c\u600e\u9ebc\u8aaa\u90fd\u4e0d\u5408\u7406\u3002\u56e0\u6b64\u964d\u4f4e\u812b\u9644\u4e8c\u6c27\u5316\u78b3\u6642\u7684\u6eab\u5ea6\uff0c\u540c\u6642\u4fdd\u6301\u9019\u500b\u5206\u5b50\u5438\u9644\u4e8c\u6c27\u5316\u78b3\u7684\u80fd\u529b\u5c31\u986f\u5f97\u975e\u5e38\u91cd\u8981\u3002\u67cf\u514b\u840a\u5927\u5b78(UC Berkeley)\u5316\u5b78\u7cfbJeffrey Long\u6559\u6388\u4fbf\u7814\u767c\u51fa\u4e00\u7a2e\u5206\u5b50\uff0c\u53ef\u8b93\u986f\u8457\u964d\u4f4e\u812b\u9644\u6eab\u5ea6\uff0c\u5927\u5927\u6e1b\u5c11\u78b3\u6355\u6349\u6240\u6d88\u8017\u7684\u80fd\u91cf\uff0c\u9019\u9805\u7814\u7a76\u4e5f\u88ab\u767c\u8868\u57282015\u5e74\u81ea\u7136\u300aNature\u300b\u671f\u520a\u4e0a\u3002<\/p>\n<p>Jeffrey Long\u6559\u6388\u4f7f\u7528\u7684\u5206\u5b50\u662f\u4e8c\u80fa\u985e(diamines)\uff0c\u4e3b\u9ad4\u70ba\u91d1\u5c6c\u6709\u6a5f\u7269\u518d\u4ee5\u542b\u6c2e\u7684\u5316\u5408\u7269\u9032\u884c\u4fee\u98fe\uff0c\u9019\u985e\u5316\u5408\u7269\u76f8\u5c0d\u6bd4\u8f03\u7a69\u5b9a\uff0c\u85c9\u7531\u4e0d\u540c\u7684\u5408\u6210\u65b9\u5f0f\u53ef\u4ee5\u5728\u4e0d\u540c\u6eab\u5ea6\u4e0b\u5438\u9644\u4e8c\u6c27\u5316\u78b3\uff0c\u800c\u812b\u9644\u7684\u6eab\u5ea6\u53ea\u9700\u8981\u6bd4\u5438\u9644\u6eab\u5ea6\u9ad850\u00b0C\u5373\u53ef\u3002\u80fd\u5728\u4e0d\u540c\u6eab\u5ea6\u4e0b\u5438\u9644\u4e8c\u6c27\u5316\u78b3\u662f\u4e00\u9805\u5f88\u91cd\u8981\u7684\u529f\u80fd\uff0c\u56e0\u70ba\u4e0d\u540c\u5de5\u5ee0\u6216\u767c\u96fb\u5ee0\u7522\u751f\u4e8c\u6c27\u5316\u78b3\u6642\u7684\u6eab\u5ea6\u90fd\u6709\u6240\u4e0d\u540c\uff0c\u5982\u679c\u53ea\u80fd\u5728\u67d0\u4e9b\u6eab\u5ea6\u4e0b\u5438\u9644\u4e8c\u6c27\u5316\u78b3\uff0c\u5c31\u5fc5\u9808\u8981\u518d\u591a\u4e00\u9053\u6b65\u9a5f\uff0c\u5c07\u4e8c\u6c27\u5316\u78b3\u5347\u6eab\u6216\u964d\u6eab\u81f3\u8a72\u6eab\u5ea6\u624d\u80fd\u9032\u884c\u5438\u9644\uff0c\u7121\u7591\u53c8\u662f\u589e\u52a0\u80fd\u6e90\u6d88\u8017\u3002<\/p>\n<p>\u9664\u4e86\u6eab\u5ea6\uff0c\u53cd\u61c9\u6642\u7684\u58d3\u529b\u4e5f\u540c\u6a23\u91cd\u8981\uff0c\u56e0\u70ba\u6c23\u9ad4\u7684\u58d3\u529b\u4e5f\u4ee3\u8868\u6c23\u9ad4\u7684\u5bc6\u5ea6(\u6216\u6fc3\u5ea6)\uff0c\u5982\u679c\u80fd\u5728\u4e8c\u6c27\u5316\u78b3\u58d3\u529b\u5f88\u4f4e\u7684\u72c0\u6cc1\u4e0b\u884c\u5438\u9644\u53cd\u61c9\uff0c\u5c31\u80fd\u5c07\u4e8c\u6c27\u5316\u78b3\u6fc3\u5ea6\u964d\u5f97\u66f4\u4f4e\uff0cJeffrey Long\u6559\u6388\u4e5f\u8003\u616e\u5230\u9019\u9805\u56e0\u7d20\u4e86\uff0c\u85c9\u7531\u66ff\u63db\u4e0d\u540c\u7684\u91d1\u5c6c\uff0c\u4fbf\u53ef\u5728\u4e0d\u540c\u7684\u58d3\u529b\u4e0b\u5438\u9644\u4e8c\u6c27\u5316\u78b3\uff0c\u7814\u7a76\u986f\u793a\u4e8c\u80fa\u985e\u53ef\u5438\u9644\u4e8c\u6c27\u5316\u78b3\u7684\u6700\u4f4e\u6fc3\u5ea6\u70ba300ppm\uff0c\u7a7a\u6c23\u4e2d\u4e8c\u6c27\u5316\u78b3\u6fc3\u5ea6\u5927\u7d04\u662f400ppm\uff0c\u800c\u8a31\u591a\u570b\u5bb6\u5e0c\u671b\u53ef\u4ee5\u5c07\u5927\u6c23\u4e2d\u4e8c\u6c27\u5316\u78b3\u6fc3\u5ea6\u964d\u4f4e\u81f3350ppm\u4ee5\u9632\u6b62\u4e0d\u53ef\u9006\u7684\u5168\u7403\u6696\u5316\u3002<\/p>\n<p>\u4e0d\u50c5\u5982\u6b64\uff0c\u9019\u7a2e\u4e8c\u80fa\u5206\u5b50\u9084\u6709\u4e00\u9805\u5927\u512a\u9ede\uff0c\u7576\u4e00\u500b\u4e8c\u6c27\u5316\u78b3\u5206\u5b50\u5438\u9644\u4e0a\u53bb\u4e4b\u5f8c\uff0c\u6703\u52a0\u901f\u63a5\u4e0b\u4f86\u7684\u5438\u9644\u901f\u7387\u5f62\u6210\u4e00\u93c8\u9396\u6548\u61c9\uff0c\u8b93\u53cd\u61c9\u6642\u9593\u5927\u5e45\u7e2e\u77ed\uff0c\u540c\u6a23\u7684\u73fe\u8c61\u4e5f\u767c\u751f\u5728\u812b\u9644\u7684\u6642\u5019\uff0c\u4e00\u500b\u4e8c\u6c27\u5316\u78b3\u5206\u5b50\u96e2\u958b\u6703\u52a0\u901f\u9130\u8fd1\u7684\u4e8c\u6c27\u5316\u78b3\u5206\u5b50\u812b\u9644\u3002<\/p>\n<p>Jeffrey Long\u751a\u81f3\u6307\u51fa\u4ed6\u5011\u7814\u767c\u51fa\u542b\u9382(Mg)\u7684\u91d1\u5c6c\u4e8c\u80fa\u985e\u7684\u7d50\u69cb\u8207\u81ea\u7136\u754c\u5149\u5408\u4f5c\u7528\u4e2d\u56fa\u78b3\u7684\u9175\u7d20RuBisCO\u975e\u5e38\u985e\u4f3c\uff0c\u9019\u4e5f\u662f\u4e00\u500b\u9081\u5411\u4f4e\u8017\u80fd\u78b3\u6536\u96c6\u53ca\u5132\u5b58\u7684\u597d\u6d88\u606f\u3002<\/p>\n<p><strong>\u539f\u59cb\u8ad6\u6587\uff1a<\/strong>Thomas M. McDonald, Jarad A. Mason, Xueqian Kong, Eric D. Bloch, David Gygi, Alessandro Dani, Valentina Crocell\u00e0, Filippo Giordanino, Samuel O. Odoh, Walter S. Drisdell, Bess Vlaisavljevich, Allison L. Dzubak, Roberta Poloni, Sondre K. Schnell, Nora Planas, Kyuho Lee, Tod Pascal, Liwen F. Wan, David Prendergast, Jeffrey B. Neaton, Berend Smit, Jeffrey B. Kortright, Laura Gagliardi, Silvia Bordiga, Jeffrey A. Reimer, Jeffrey R. Long.\u00a0<strong>Cooperative insertion of CO<sub>2<\/sub> in diamine-appended metal-organic frameworks<\/strong>.\u00a0<em>Nature<\/em>, 2015; DOI:\u00a0<a href=\"http:\/\/dx.doi.org\/10.1038\/nature14327\" target=\"_blank\" rel=\"noopener noreferrer\">10.1038\/nature14327<\/a><\/p>\n<p><strong>\u53c3\u8003\u8cc7\u6599\uff1a<\/strong><\/p>\n<ol>\n<li><a href=\"http:\/\/newscenter.berkeley.edu\/2015\/03\/11\/new-material-captures-carbon-at-half-the-energy-cost\/\">New material captures carbon at half the energy cost<\/a><\/li>\n<li><a href=\"http:\/\/en.wikipedia.org\/wiki\/Carbon_capture_and_storage\">Carbon capture and storage<\/a><\/li>\n<\/ol>\n<p><span style=\"color: #333399;\"><strong>--<\/strong><\/span><br style=\"color: #000000;\" \/><span style=\"color: #333399;\"><strong>\u4f5c\u8005\uff1a\u65b9\u7a0b\u6bc5 \u79d1\u6559\u4e2d\u5fc3\u7279\u7d04\u5beb\u624b\uff0c\u5f9e\u4e8b\u79d1\u666e\u6587\u7ae0\u5beb\u4f5c\u3002<\/strong><\/span><\/p>\n<p>&nbsp;<\/p>\n<p><a href=\"https:\/\/line.me\/R\/ti\/p\/%40fcx6182w\" target=\"_blank\" rel=\"noopener noreferrer\"><img decoding=\"async\" class=\"alignnone\" src=\"https:\/\/scdn.line-apps.com\/n\/line_add_friends\/btn\/zh-Hant.png\" alt=\"\u52a0\u5165\u597d\u53cb\" width=\"212\" height=\"36\" border=\"0\"><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u25a0\u74b0\u4fdd\u610f\u8b58\u9ad8\u6f32\uff0c\u6709\u6c92\u6709\u66f4\u7bc0\u80fd\u7684\u65b9\u6cd5\u6355\u6349\u4e8c<\/p>\n","protected":false},"author":20,"featured_media":21143,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[191,1023,3293],"tags":[1558,1770,1136],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2015\/03\/153113.jpg","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/21142"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=21142"}],"version-history":[{"count":5,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/21142\/revisions"}],"predecessor-version":[{"id":32201,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/21142\/revisions\/32201"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/21143"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=21142"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=21142"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=21142"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}