{"id":19367,"date":"2014-10-07T13:46:27","date_gmt":"2014-10-07T05:46:27","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=19367"},"modified":"2017-07-29T15:13:32","modified_gmt":"2017-07-29T07:13:32","slug":"%e3%80%90%e8%ab%be%e8%b2%9d%e7%88%be%e5%8c%96%e5%ad%b8%e7%8d%8e%e9%a0%90%e6%b8%ac%e3%80%91%e4%bd%95%e8%ac%82%e5%8f%af%e9%80%86%e5%8a%a0%e6%88%90-%e6%96%b7%e8%a3%82%e9%8f%88%e8%bd%89%e7%a7%bb%ef%bc%88r","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=19367","title":{"rendered":"\u30102014\u8afe\u8c9d\u723e\u5316\u5b78\u734e\u9810\u6e2c\u3011\u4f55\u8b02\u53ef\u9006\u52a0\u6210-\u65b7\u88c2\u93c8\u8f49\u79fb\uff08Reversible Addition-Fragmentation chain Transfer\uff1bRAFT\uff09\u805a\u5408\u53cd\u61c9"},"content":{"rendered":"<p><strong><img fetchpriority=\"high\" decoding=\"async\" class=\"aligncenter size-full wp-image-19382\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2014\/10\/563.png\" alt=\"563\" width=\"670\" height=\"239\" srcset=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2014\/10\/563.png 670w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2014\/10\/563-300x107.png 300w\" sizes=\"(max-width: 670px) 100vw, 670px\" \/>\u7de8\u8b6f\uff5c<\/strong>\u5de5\u696d\u79d1\u6280\u7814\u7a76\u9662\u3000<span style=\"color: #222222;\">\u6d2a\u9298\u8070\u535a\u58eb<\/span><\/p>\n<p>\u5728\u6211\u5011\u6bcf\u5929\u7684\u65e5\u5e38\u751f\u6d3b\u4e2d\u90fd\u6703\u63a5\u89f8\u5230\u8a31\u591a\u7531\u805a\u5408\u7269\u6240\u88fd\u6210\u7684\u7522\u54c1\uff0c\u9019\u4e9b\u805a\u5408\u7269\u6709\u805a\u4e19\u70ef\u9178\u916f\u3001\u805a\u4e19\u70ef\u8148\u3001\u805a\u82ef\u4e59\u70ef\u4ee5\u53ca\u805a\u4e59\u70ef\u9187\u3002\u5b83\u5011\u90fd\u662f\u900f\u904e\u81ea\u7531\u57fa\u805a\u5408\u53cd\u61c9\u7684\u65b9\u5f0f\u6240\u88fd\u9020\u51fa\u4f86\uff0c\u800c\u53cd\u61c9\u7684\u904e\u7a0b\u5305\u542b\u4e86\u55ae\u9ad4\u5206\u5b50\u5f9e\u81ea\u7531\u57fa\u63a5\u6536\u4e86\u4e00\u500b\u96fb\u5b50\u7136\u5f8c\u518d\u8207\u4e0b\u4e00\u500b\u55ae\u9ad4\u9032\u884c\u53cd\u61c9\uff0c\u63a5\u8457\u4e00\u76f4\u91cd\u8907\u9019\u500b\u6b65\u9a5f\uff0c\u56e0\u6b64\u5206\u5b50\u93c8\u6703\u4e0d\u65b7\u5730\u589e\u9577\u76f4\u5230\u9047\u5230\u53ef\u4ee5\u7d42\u6b62\u53cd\u61c9\u7684\u55ae\u4f4d\uff0c\u4f8b\u5982\u53e6\u4e00\u500b\u81ea\u7531\u57fa\u3002\u6240\u4ee5\u9019\u985e\u578b\u53cd\u61c9\u6240\u7522\u751f\u7684\u5206\u5b50\u93c8\u9577\u5ea6\u53ef\u4ee5\u975e\u5e38\u5927\u4e26\u4e0d\u4ee4\u4eba\u8a1d\u7570\u3002<!--more--><\/p>\n<p>\u96d6\u7136\u9019\u4e9b\u805a\u5408\u7269\u5df2\u7d93\u767c\u5c55\u8d85\u904e70\u5e74\u7684\u6b77\u53f2\uff0c\u4f46\u662f\u771f\u6b63\u5728\u5316\u5b78\u4e0a\u5411\u524d\u9081\u9032\u4e00\u5927\u6b65\u5247\u662f\u57281990\u5e74\u4ee3\uff0c\u9019\u90fd\u8981\u6b78\u529f\u65bc\u5728\u6fb3\u6d32\u806f\u90a6\u79d1\u5b78\u8207\u5de5\u696d\u7814\u7a76\u7d44\u7e54\uff08CSIRO\uff09\u4e2d\u5fc3\u5de5\u4f5c\u4e09\u500b\u79d1\u5b78\u5bb6\uff1a\u83ab\u5fb7(Graeme Moad)\u3001\u6851\u2027\u5510(San Thang)\u548c\u91cc\u624e\u591a(Ezio Rizzardo)\u3002\u4ed6\u5011\u57281998\u5e74 Macromolecules \u671f\u520a\u4e0a\u6240\u767c\u8868\u7684\u8ad6\u6587\u63d0\u51fa\u4e86\u53ef\u9006\u52a0\u6210-\u65b7\u88c2\u93c8\u8f49\u79fb\u81ea\u7531\u57fa\u805a\u5408\u6cd5\uff0c\u5f15\u8d77\u4e86\u76f8\u7576\u5927\u7684\u95dc\u6ce8\uff0c\u81f3\u4eca\u5df2\u7d93\u88ab\u5f15\u7528\u8d85\u904e2700\u6b21\u3002\u8a72\u8ad6\u6587\u4e2d\u6307\u51fa\u53ef\u4ee5\u5229\u7528\u4e00\u7a2e\u5177\u6709ZC(=S)S<sub>2<\/sub>R\u4e4b\u7d50\u69cb\u7684\u4e8c\u786b\u916f\uff08dithio ester\uff09\u93c8\u8f49\u79fb\u5291\u4f86\u9032\u884c\u81ea\u7531\u57fa\u805a\u5408\u3002\u53cd\u61c9\u6a5f\u5236\u5982\u4e0b\u5716\u6240\u793a\uff1a\u5176\u4e2dZ\u57fa\u5718\u80fd\u5920\u6d3b\u5316\u78b3\u786b\u96d9\u9375\uff08C=S bond\uff09\u4e26\u4e14\u627f\u53d7\u7acb\u5373\u6210\u70ba\u81ea\u7531\u57fa\u7684\u529f\u80fd\uff0cR\u57fa\u5718\u5247\u662f\u597d\u7684\u81ea\u7531\u57fa\u96e2\u53bb\u57fa\u3002<\/p>\n<figure id=\"attachment_19368\" aria-describedby=\"caption-attachment-19368\" style=\"width: 550px\" class=\"wp-caption aligncenter\"><img decoding=\"async\" class=\"wp-image-19368 size-full\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2014\/10\/\u672a\u547d\u540d1.png\" alt=\"\u672a\u547d\u540d\" width=\"550\" height=\"110\" srcset=\"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2014\/10\/\u672a\u547d\u540d1.png 550w, https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2014\/10\/\u672a\u547d\u540d1-300x59.png 300w\" sizes=\"(max-width: 550px) 100vw, 550px\" \/><figcaption id=\"caption-attachment-19368\" class=\"wp-caption-text\">RAFT\u805a\u5408\u53cd\u61c9\u53cd\u61c9\u6a5f\u5236<\/figcaption><\/figure>\n<p>\u5316\u5b78\u5bb6\u7a31\u9019\u500b\u904e\u7a0b\u53eb\u505a\u201c\u53ef\u9006\u52a0\u6210-\u65b7\u88c2\u93c8\u8f49\u79fb\u201d\u7c21\u7a31\u7e2e\u5beb\u70baRAFT\u3002RAFT\u805a\u5408\u5177\u6709\u81ea\u7531\u57fa\u53cd\u61c9\u7684\u5316\u5b78\u7279\u6027\uff0c\u5728\u5f15\u767c\u7684\u968e\u6bb5\u5fc5\u9808\u8981\u5f15\u5165\u81ea\u7531\u57fa\u624d\u80fd\u7522\u751f\u55ae\u9ad4\u81ea\u7531\u57fa\u4e26\u4e14\u9032\u884c\u93c8\u8f49\u79fb\u548c\u589e\u9577\u3002<\/p>\n<p>\u4ee5\u5408\u6210\u65b9\u6cd5\u4f86\u8aaa\uff0cRAFT\u5177\u6709\u8a31\u591a\u512a\u9ede\uff0c\u9664\u4e86\u4e0d\u5fc5\u4f7f\u7528\u91d1\u5c6c\u89f8\u5a92\uff0c\u800c\u4e14\u53cd\u61c9\u53ef\u4ee5\u5728\u8f03\u6eab\u548c\u7684\u689d\u4ef6\u4e0b\u9032\u884c\uff0c\u61c9\u7528\u65bc\u66f4\u5ee3\u6cdb\u7684\u5404\u7a2e\u805a\u5408\u55ae\u9ad4 (monomer)\uff0c\u5176\u4e2d\u5305\u62ec\u542b\u6709\u9178\u6216\u6709\u6c28\u57fa\u7b49\u5b98\u80fd\u57fa\u7684\u55ae\u9ad4\u3002\u53e6\u4e00\u65b9\u9762\u7531\u65bcRAFT\u6cd5\u5c0d\u6eb6\u5291\u8207\u53cd\u61c9\u6eab\u5ea6\u4e5f\u6c92\u6709\u7279\u5225\u7684\u9650\u5236\uff0c\u9069\u7528\u65bc\u50b3\u7d71\u81ea\u7531\u57fa\u805a\u5408\u7684\u5be6\u9a57\u689d\u4ef6\uff0c\u5728\u6c34\u4e2d\u3001\u6eb6\u6db2\u3001\u4e73\u5316\u6216\u61f8\u6d6e\u72c0\u614b\u4e0b\u90fd\u80fd\u9032\u884c\u805a\u5408\u53cd\u61c9\u3002\u5229\u7528\u9019\u7a2e\u6709\u6548\u4e14\u4fbf\u5229\u7684\u805a\u5408\u6cd5\u9084\u53ef\u4ee5\u5408\u6210\u51fa\u8a31\u591a\u4e0d\u540c\u5f62\u72c0\u985e\u578b\u7684\u805a\u5408\u7269\uff0c\u4f8b\u5982\uff1a\u5237\u5b50\u72c0\u3001\u68b3\u72c0\u3001\u661f\u72c0\u3001\u555e\u9234\u72c0\uff1b\u4e5f\u53ef\u7528\u65bc\u5718\u806f\u5f0f\u5171\u805a\u7269\u6216\u5176\u5b83\u66f4\u8907\u96dc\u7d50\u69cb\u805a\u5408\u7269\u7684\u5408\u6210\u3002<\/p>\n<p>\u7e3d\u548c\u4f86\u8aaa\uff0cRAFT\u7684\u5546\u696d\u50f9\u503c\u5c07\u5f88\u5feb\u5730\u88ab\u610f\u8b58\u5230\uff0c\u4e26\u4e14\u5feb\u901f\u7684\u5c07\u7814\u7a76\u5f9e\u5be6\u9a57\u5ba4\u8f49\u79fb\u5230\u5de5\u5ee0\u662f\u53ef\u4ee5\u9810\u671f\u7684\u3002<\/p>\n<p>--<strong>\u7814\u7a76\u51fa\u8655\uff1a<a href=\"http:\/\/sciencewatch.com\/nobel\/2014-predictions\/chemistry-laureates\" target=\"_blank\" rel=\"noopener noreferrer\">FOR DESIGN OF FUNCTIONAL MESOPOROUS MATERIALS<\/a><\/strong><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u7de8\u8b6f\uff5c\u5de5\u696d\u79d1\u6280\u7814\u7a76\u9662\u3000\u6d2a\u9298\u8070\u535a\u58eb \u5728\u6211\u5011<\/p>\n","protected":false},"author":20,"featured_media":29025,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[32,3293],"tags":[1639,1456,2249,1457,177],"aioseo_notices":[],"jetpack_featured_media_url":"https:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2014\/10\/563-1.png","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/19367"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/20"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=19367"}],"version-history":[{"count":7,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/19367\/revisions"}],"predecessor-version":[{"id":29026,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/19367\/revisions\/29026"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/media\/29025"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=19367"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=19367"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=19367"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}