{"id":10333,"date":"2011-12-12T15:34:55","date_gmt":"2011-12-12T07:34:55","guid":{"rendered":"https:\/\/case.ntu.edu.tw\/blog\/?p=10333"},"modified":"2017-03-31T23:20:35","modified_gmt":"2017-03-31T15:20:35","slug":"%e3%80%90%e5%8c%96%e5%ad%b8%e6%96%b0%e7%9f%a5%e3%80%91%e6%b0%ae%e8%ae%8a%e6%88%90%e6%b0%a8%ef%bc%9a%e7%99%be%e5%b9%b4%e5%93%88%e6%9f%8f%e6%b3%95%e7%9a%84%e5%8e%9f%e7%90%86%e7%b5%82%e6%8f%ad%e6%9b%89","status":"publish","type":"post","link":"https:\/\/case.ntu.edu.tw\/blog\/?p=10333","title":{"rendered":"\u3010\u5316\u5b78\u65b0\u77e5\u3011\u6c2e\u8b8a\u6210\u6c28\uff1a\u767e\u5e74\u54c8\u67cf\u6cd5\u7684\u539f\u7406\u7d42\u63ed\u66c9"},"content":{"rendered":"<p><span style=\"color: #333399;\"><strong>\u25a0<\/strong><strong>\u6700\u8fd1\u7f8e\u570b\u7f85\u5fb9\u65af\u7279\u5927\u5b78\uff08University of Rochester\uff09\u7684\u6d3e\u5d14\u514b\uff0e\u54c8\u862d\uff08Patrick Holland\uff09\u7387\u9818\u4e00\u7fa4\u5316\u5b78\u5b78\u8005\u9032\u884c\u7814\u7a76\uff0c\u7d42\u65bc\u7814\u7a76\u51fa\u6c28\u5728\u54c8\u67cf\u6cd5\u4e2d\u662f\u5982\u4f55\u5f62\u6210\u7684\u4e86\u3002\u9019\u9805\u7814\u7a76\u6210\u679c\u5df2\u65bc11\u670811\u65e5\u767c\u8868\u5728\u300a\u79d1\u5b78\u300b\uff08<em>Science<\/em>\uff09\u96dc\u8a8c\u4e0a\u3002<\/strong><\/span><\/p>\n<figure id=\"attachment_10334\" aria-describedby=\"caption-attachment-10334\" style=\"width: 506px\" class=\"wp-caption alignleft\"><a rel=\"attachment wp-att-10334\" href=\"http:\/\/case.ntu.edu.tw\/blog\/?attachment_id=10334\"><img fetchpriority=\"high\" decoding=\"async\" class=\"size-full wp-image-10334 \" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2011\/12\/89127718.jpg\" alt=\"\" width=\"506\" height=\"338\" \/><\/a><figcaption id=\"caption-attachment-10334\" class=\"wp-caption-text\">\u5716\u7247\u4f86\u6e90\uff1aJames French\u2502Getty Images <\/figcaption><\/figure>\n<p><strong>\u7de8\u8b6f<\/strong> | \u6c6a\u8283<\/p>\n<p>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;\u6c28\u662f\u88fd\u4f5c\u80a5\u6599\u7684\u91cd\u8981\u6210\u5206\uff0c\u800c\u904e\u53bb\u4e00\u767e\u5e74\u4ee5\u4f86\uff0c\u4e16\u4eba\u4e00\u76f4\u4f7f\u7528\u54c8\u67cf\u6cd5\uff08the Haber-Bosch process\uff09\u4f86\u5c07\u5927\u6c23\u4e2d\u7684\u6c2e\u6c23\u8f49\u63db\u6210\u6c28\u3002\u96d6\u7136\u9019\u500b\u88fd\u9020\u65b9\u6cd5\u4e00\u76f4\u5341\u5206\u53ef\u9760\uff0c\u7136\u800c\u79d1\u5b78\u5bb6\u5c0d\u54c8\u67cf\u6cd5\u7684\u78ba\u5207\u539f\u7406\u537b\u6240\u77e5\u751a\u5c11\u3002\u4f46\u6700\u8fd1\u7f8e\u570b\u7f85\u5fb9\u65af\u7279\u5927\u5b78\uff08University of Rochester\uff09\u7684\u6d3e\u5d14\u514b\uff0e\u54c8\u862d\uff08Patrick Holland\uff09\u7387\u9818\u4e00\u7fa4\u5316\u5b78\u5b78\u8005\u9032\u884c\u7814\u7a76\uff0c\u7d42\u65bc\u7814\u7a76\u51fa\u6c28\u5728\u54c8\u67cf\u6cd5\u4e2d\u662f\u5982\u4f55\u5f62\u6210\u7684\u4e86\u3002\u9019\u9805\u7814\u7a76\u6210\u679c\u5df2\u65bc11\u670811\u65e5\u767c\u8868\u5728\u300a\u79d1\u5b78\u300b\uff08<em>Science<\/em>\uff09\u96dc\u8a8c\u4e0a\u3002<\/p>\n<p><strong>\u4ee4\u4eba\u53c3\u4e0d\u900f\u7684\u54c8\u67cf\u6cd5<\/strong><\/p>\n<p>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;\u6309\u7167\u54c8\u862d\u7684\u8aaa\u6cd5\uff0c\u6c2e\u5206\u5b50\u975e\u5e38\u300c\u96e3\u7e8f\u300d\u3002\u96d6\u7136\u6211\u5011\u5468\u906d\u7684\u7a7a\u6c23\u4e2d\u5c31\u5b58\u5728\u5927\u91cf\u6c2e\u6c23\uff0c\u56e0\u6b64\u6211\u5011\u4e00\u76f4\u5f88\u559c\u6b61\u7528\u6c2e\u4f86\u7814\u7a76\u6216\u751f\u7522\u88fd\u9020\uff0c\u4f46\u9019\u7a2e\u6c23\u9ad4\u7684\u4e09\u9375\u93c8\u7d50\u975e\u5e38\u96e3\u7834\u58de\uff0c\u56e0\u6b64\u5e7e\u4e4e\u7121\u6cd5\u548c\u5176\u4ed6\u5143\u7d20\u7522\u751f\u4efb\u4f55\u53cd\u61c9\u3002<!--more-->\u904e\u53bb\u4e00\u4e16\u7d00\u4ee5\u4f86\uff0c\u6211\u5011\u4f7f\u7528\u7684\u662f\u54c8\u67cf\u6cd5\uff0c\u4e5f\u5c31\u662f\u4ee5\u9435\u4f5c\u70ba\u50ac\u5316\u5291\uff0c\u4e26\u65bd\u4ee5\u9ad8\u6eab\u53ca\u9ad8\u58d3\uff0c\u5982\u6b64\u624d\u80fd\u7834\u58de\u6c2e\u7684\u4e09\u9375\u7d50\u69cb\uff0c\u4e00\u9ede\u4e00\u9ede\u6162\u6162\u5730\u88fd\u6210\u6c28\uff0c\u5118\u7ba1\u5982\u6b64\uff0c\u54c8\u67cf\u6cd5\u80cc\u5f8c\u7684\u539f\u7406\u59cb\u7d42\u6c92\u4eba\u80fd\u6478\u900f\u3002<\/p>\n<p>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;\u54c8\u862d\u8aaa\uff1a\u300c\u54c8\u67cf\u6cd5\u6709\u6548\uff0c\u4f46\u8981\u4e86\u89e3\u80cc\u5f8c\u7684\u539f\u7406\u5f88\u96e3\uff0c\u56e0\u70ba\u9019\u500b\u5316\u5b78\u53cd\u61c9\u9760\u7684\u662f\u56fa\u614b\u7684\u50ac\u5316\u5291\uff0c\u56e0\u6b64\u4e0d\u5bb9\u6613\u89c0\u5bdf\u7814\u7a76\u3002\u6240\u4ee5\u6211\u5011\u624d\u6703\u8a66\u8457\u7528\u53ef\u6eb6\u7684\u9435\u4f86\u5206\u89e3\u6c2e\u5206\u5b50\u3002\u300d<\/p>\n<p><strong>\u6db2\u614b\u89e3\u8b0e\u5718<\/strong><\/p>\n<p>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;\u54c8\u862d\u6240\u7387\u9818\u7684\u7814\u7a76\u5718\u968a\uff0c\u6210\u54e1\u6709\u7f85\u5fb9\u65af\u7279\u5927\u5b78\u7684\u6885\u6839\uff0e\u7f85\u5fb7\u91cc\u683c\u65af\uff08Meghan Rodriguez\uff09\u548c\u5a01\u5ec9\uff0e\u5e03\u745e\u8afe\u7d22\uff08William Brennessel\uff09\uff0c\u9084\u6709\u5fb7\u570b\u99ac\u514b\u65af\u666e\u6717\u514b\u79d1\u5b78\u4fc3\u9032\u5354\u6703\u751f\u7269\u7121\u6a5f\u5316\u5b78\u7814\u7a76\u6240\uff08the Max Planck Institute for Bioinorganic Chemistry\uff09\u7684\u611b\u514b\u54c8\u5fb7\uff0e\u7562\u723e\uff08Eckhard Bill\uff09\uff0c\u4ed6\u5011\u7528\u6eb6\u6db2\u72c0\u614b\u6210\u529f\u6a21\u64ec\u4e86\u54c8\u67cf\u6cd5\u3002\u4ed6\u5011\u767c\u73fe\uff0c\u6709\u4e00\u7a2e\u7d50\u5408\u4e86\u9240\u7684\u542b\u9435\u932f\u5408\u7269\u80fd\u6253\u65b7\u6c2e\u539f\u5b50\u4e4b\u9593\u7684\u5f37\u97cc\u9375\u7d50\uff0c\u4e26\u5f62\u6210\u4e00\u7a2e\u4ee5\u6c2e\u5316\u4e9e\u9435\uff08Fe<sub>3<\/sub>N<sub>2<\/sub>\uff09\u70ba\u6838\u5fc3\u7684\u932f\u5408\u7269\uff0c\u7531\u6b64\u80fd\u770b\u51fa\uff0c\u6c2e\u539f\u5b50\u4e4b\u9593\u7684\u9375\u7d50\u80fd\u65b7\u958b\u4f86\uff0c\u9760\u7684\u4fbf\u662f\u9019\u4e09\u500b\u9435\uff08Fe\uff09\u539f\u5b50\u3002\u63a5\u8457\u9019\u7a2e\u6c2e\u5316\u4e9e\u9435\u932f\u5408\u7269\u4fbf\u6703\u8207\u6c2b\u6c23\uff08H<sub>2<\/sub>\uff09\u548c\u9178\u8d77\u53cd\u61c9\uff0c\u9032\u800c\u5f62\u6210\u6c28\uff08NH<sub>3<\/sub>\uff09\u3002\u5728\u6b64\u4e4b\u524d\uff0c\u5f9e\u4f86\u6c92\u6709\u4eba\u7528\u6db2\u9ad4\u4e2d\u7684\u9435\u6210\u529f\u88fd\u51fa\u6c28\u3002<\/p>\n<p>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;\u96d6\u7136\u9019\u662f\u4e00\u9805\u91cd\u5927\u7a81\u7834\uff0c\u4f46\u9019\u9805\u6280\u8853\u5728\u77ed\u6642\u9593\u5167\u4ecd\u7121\u6cd5\u53d6\u4ee3\u54c8\u67cf\u6cd5\u3002\u5118\u7ba1\u7528\u9ad8\u6eab\u9ad8\u58d3\u4f86\u88fd\u9020\u6c28\u6709\u5176\u98a8\u96aa\uff0c\u4f46\u54c8\u862d\u6307\u51fa\uff0c\u54c8\u67cf\u6cd5\u7528\u7684\u50ac\u5316\u5291\u7562\u7adf\u6bd4\u4ed6\u5011\u7528\u7684\u8981\u4fbf\u5b9c\u8a31\u591a\u3002\u4e0d\u904e\u54c8\u862d\u4e5f\u8868\u793a\uff0c\u672a\u4f86\u4ed6\u5011\u6709\u53ef\u80fd\u7814\u7a76\u51fa\u4e00\u7a2e\u66f4\u597d\u7684\u50ac\u5316\u5291\u4f9b\u54c8\u67cf\u6cd5\u4f7f\u7528\uff0c\u8b93\u54c8\u67cf\u6cd5\u4e0d\u9700\u8981\u90a3\u9ebc\u9ad8\u7684\u6eab\u5ea6\u53ca\u58d3\u529b\u5373\u53ef\u4f5c\u7528\u3002<\/p>\n<p>&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;&nbsp;\u6b64\u5916\uff0c\u9019\u9805\u7814\u7a76\u6210\u679c\u9084\u5e36\u4f86\u4e00\u500b\u8ddf\u6c28\u548c\u80a5\u6599\u516b\u7aff\u5b50\u6253\u4e0d\u8457\u7684\u597d\u8655\uff0c\u90a3\u5c31\u662f\u7576\u4e0a\u8ff0\u7684\u9435\u9240\u932f\u5408\u7269\u5206\u89e3\u6c2e\u5206\u5b50\u6642\uff0c\u540c\u6642\u6703\u5f62\u6210\u5e36\u8ca0\u96fb\u7684\u6c2e\u96e2\u5b50\uff0c\u7a31\u70ba\u6c2e\u5316\u7269\uff08nitrides\uff09\u3002\u54c8\u862d\u8aaa\uff0c\u6eb6\u6db2\u4e2d\u5f62\u6210\u7684\u9019\u4e9b\u6c2e\u5316\u7269\u53ef\u7528\u4f86\u88fd\u9020\u85e5\u54c1\u53ca\u5176\u4ed6\u7522\u54c1\u3002<br \/>\n--<\/p>\n<pre><span style=\"color: #333333;\"> \u5831\u5c0e\u51fa\u8655\uff1a<strong><a href=\"http:\/\/www.sciencedaily.com\/releases\/2011\/11\/111111152240.htm?utm_source=feedburner&amp;utm_medium=feed&amp;utm_campaign=Feed%3A+sciencedaily+%28ScienceDaily%3A+Latest+Science+News%29\">University of Rochester. \"Chemistry: New insight into 100-year-old Haber-Bbosch process of converting nitrogen to ammonia.\"ScienceDaily, 11 Nov. 2011. Web. 13 Nov. 2011.<\/a><\/strong><\/span><\/pre>\n<pre><span style=\"color: #333333;\"> \u7814\u7a76\u51fa\u8655\uff1a<strong>M. M. Rodriguez, E. Bill, W. W. Brennessel, P. L. Holland.N2 Reduction and Hydrogenation to Ammonia by a Molecular Iron-Potassium Complex. Science, 2011; 334 (6057): 780 DOI: 10.1126\/science.1211906<\/strong><\/span><\/pre>\n<p><span style=\"color: #333399;\"><strong><strong>\u8cac\u4efb\u7de8\u8f2f\uff1aNita  Hsu<\/strong><\/strong><\/span><\/p>\n<p><span style=\"color: #333399;\"><strong><strong><a rel=\"attachment wp-att-10500\" href=\"http:\/\/case.ntu.edu.tw\/blog\/?attachment_id=10500\"><img decoding=\"async\" class=\"alignleft size-full wp-image-10500\" title=\"\u6c2e\u8b8a\u6210\u6c28\u767e\u5e74\u54c8\u67cf\u6cd5\u7684\u539f\u7406\u7d42\u63ed\u66c9\" src=\"http:\/\/case.ntu.edu.tw\/blog\/wp-content\/uploads\/2011\/12\/\u6c2e\u8b8a\u6210\u6c28\u767e\u5e74\u54c8\u67cf\u6cd5\u7684\u539f\u7406\u7d42\u63ed\u66c9.png\" alt=\"\" width=\"140\" height=\"140\" \/><\/a><br \/>\n<\/strong><\/strong><\/span><\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u25a0\u6700\u8fd1\u7f8e\u570b\u7f85\u5fb9\u65af\u7279\u5927\u5b78\uff08Universi<\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[32,3293],"tags":[2249],"aioseo_notices":[],"jetpack_featured_media_url":"","_links":{"self":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/10333"}],"collection":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcomments&post=10333"}],"version-history":[{"count":13,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/10333\/revisions"}],"predecessor-version":[{"id":10502,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=\/wp\/v2\/posts\/10333\/revisions\/10502"}],"wp:attachment":[{"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fmedia&parent=10333"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Fcategories&post=10333"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/case.ntu.edu.tw\/blog\/index.php?rest_route=%2Fwp%2Fv2%2Ftags&post=10333"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}